Removal of Pyridine from Aqueous Solution by Adsorption on an Activated Carbon Cloth     

Pedro Alonso‐Davila  Oliva L. Torres‐Rivera  Roberto Leyva‐Ramos  Raul Ocampo‐Perez 《洁净——土壤、空气、水》2012,40(1):45-53

Pyridine is a very toxic pollutant that has to be removed from wastewater. In this work, adsorption of pyridine on activated carbon cloth (ACC) is studied as a possible alternative for eliminating pyridine from aqueous solution. The ACC was produced from polyacrylonitrile. The adsorption equilibrium data of pyridine on ACC was obtained in a batch adsorber. The experimental data was interpreted with the isotherms of Langmuir, Freundlich, and Prausnitz‐Radke (PR), and the PR isotherm better represented the experimental data. The capacity of ACC for adsorbing pyridine was favored increasing the solution pH from 3 to 6, and this effect was due to the π–π dispersive and electrostatic interactions between the pyridine species in solution and the surface complexes of ACC. The modified Langmuir model fitted reasonably well the influence of pH on the adsorption capacity. In this model was assumed that both neutral pyridine and pyridinium were simultaneously adsorbed on ACC accordingly to the experimental results. The adsorption capacity was almost independent of temperature. The reversibility study revealed that 75% of the pyridine can be desorbed from ACC indicating that part of the pyridine was irreversibly adsorbed, and possibly chemisorbed.  相似文献   

Contrasting rainfall generated debris flows from adjacent watersheds at Forest Falls, southern California, USA   总被引：1，自引：0，他引：1  

Douglas M. Morton  Rachel M. Alvarez  Kelly R. Ruppert  Brett Goforth 《Geomorphology》2008,96(3-4):322

Debris flows are widespread and common in many steeply sloping areas of southern California. The San Bernardino Mountains community of Forest Falls is probably subject to the most frequently documented debris flows in southern California. Debris flows at Forest Falls are generated during short-duration high-intensity rains that mobilize surface material. Except for debris flows on two consecutive days in November 1965, all the documented historic debris flows have occurred during high-intensity summer rainfall, locally referred to as ‘monsoon’ or ‘cloudburst’ rains. Velocities of the moving debris range from about 5 km/h to about 90 km/h. Velocity of a moving flow appears to be essentially a function of the water content of the flow. Low velocity debris flows are characterized by steep snouts that, when stopped, have only small amounts of water draining from the flow. In marked contrast are high-velocity debris flows whose deposits more resemble fluvial deposits. In the Forest Falls area two adjacent drainage basins, Snow Creek and Rattlesnake Creek, have considerably different histories of debris flows. Snow Creek basin, with an area about three times as large as Rattlesnake Creek basin, has a well developed debris flow channel with broad levees. Most of the debris flows in Snow Creek have greater water content and attain higher velocities than those of Rattlesnake Creek. Most debris flows are in relative equilibrium with the geometry of the channel morphology. Exceptionally high-velocity flows, however, overshoot the channel walls at particularly tight channel curves. After overshooting the channel, the flows degrade the adjacent levee surface and remove trees and structures in the immediate path, before spreading out with decreasing velocity. As the velocity decreases the clasts in the debris flows pulverize the up-slope side of the trees and often imbed clasts in them. Debris flows in Rattlesnake Creek are relatively slow moving and commonly stop in the channel. After the channel is blocked, subsequent debris flows cut a new channel upstream from the blockage that results in the deposition of new debris-flow deposits on the lower part of the fan. Shifting the location of debris flows on the Rattlesnake Creek fan tends to prevent trees from becoming mature. Dense growths of conifer seedlings sprout in the spring on the late summer debris flow deposits. This repeated process results in stands of even-aged trees whose age records the age of the debris flows.  相似文献   

Multi‐Metal‐Substituted‐Goethite as an Effective Catalyst for Azo Dye Wastewater Oxidation          下载免费PDF全文

Sofía Schlichter  Alejandra S. Diez  María C. Zenobi  Mariana Dennehy  Mariana Alvarez 《洁净——土壤、空气、水》2016,44(12):1652-1660

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Robust Regulation of Alkalinity in Highly Uncertain Continuous Anaerobic Digestion Processes     

Víctor Alcaraz‐González  Fabián Azael Fregoso‐Sanchez  Hugo Oscar Mendez‐Acosta  Victor Gonzalez‐Alvarez 《洁净——土壤、空气、水》2013,41(12):1157-1164

In this paper, a multiple‐input multiple‐output (MIMO) model‐based robust control scheme is proposed for the indirect control of both total alkalinity and the ratio (intermediate alkalinity)/(total alkalinity) by regulating volatile fatty acid concentrations and strong ions concentration, while guaranteeing the so‐called operational stability in anaerobic digestion (AD) processes. The proposed MIMO regulator is an adaptive controller derived from an AD model which incorporates the physicochemical equilibrium of the system as well as the use of a robust interval observer to estimate key process bounds that are used in the computation of the control efforts. Numerical simulations were carried out for a number of operating conditions under the most uncertain scenarios. Results showed that the proposed multivariable control law is able to recover the system stability around a pre‐determined set point in the face of parameter uncertainty and load disturbances.  相似文献   

Distinguishing the Regional Atmospheric Controls on Precipitation Isotopic Variability in the Central-Southeast Portion of Brazil     

Vinícius dos SANTOS  Peter MARSHALL FLEMING  Luís HENRIQUE MANCINI  Stela DALVA SANTOS COTA  Graziele Beatriz de LIMA  Rafaela RODRIGUES GOMES  Roberto Eduardo KIRCHHEIM  Ricardo SANCHéZ-MURILLO  Didier GASTMANS 《大气科学进展》2022,39(10):1693-1708

Precipitation isotope ratios (O and H) record the history of water phase transitions and fractionation processes during moisture transport and rainfall formation. Here, we evaluated the isotopic composition of precipitation over the central-southeastern region of Brazil at different timescales. Monthly isotopic compositions were associated with classical effects (rainfall amount, seasonality, and continentality), demonstrating the importance of vapor recirculation processes and different regional atmospheric systems (South American Convergence Zone-SACZ and Cold Fronts-CF). While moisture recycling and regional atmospheric processes may also be observed on a daily timescale, classical effects such as the amount effect were not strongly correlated (δ¹⁸O-precipitation rate r ≤ –0.37). Daily variability revealed specific climatic features, such as δ¹⁸O depleted values (~ –6‰ to –8‰) during the wet season were associated with strong convective activity and large moisture availability. Daily isotopic analysis revealed the role of different moisture sources and transport effects. Isotope ratios combined with d-excess explain how atmospheric recirculation processes interact with convective activity during rainfall formation processes. Our findings provide a new understanding of rainfall sampling timescales and highlight the importance of water isotopes to decipher key hydrometeorological processes in a complex spatial and temporal context in central-southeastern Brazil.  相似文献   

A new approach to multiphase geochemical speciation modeling     

R.J. Perez  R.A. Heidemann  E.C. Perez 《Applied Geochemistry》2012

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Groundwater flow model, recharge estimation and sustainability in an arid region of Patagonia, Argentina   总被引：2，自引：2，他引：0  

María del Pilar Alvarez  María Marta Trovatto  Mario Alberto Hernández  Nilda González 《Environmental Earth Sciences》2012,66(7):2097-2108

The Península Valdés, in northeastern Patagonia, Argentina, is characterised by its arid climate and the lack of perennial watercourses; thus, all economic activities depend on the groundwater resources. Water demand is mainly associated with tourism, which is centralised in Puerto Pirámides and supplied by a water desalination plant, and to sheep farming, supplied by the local aquifer. Due to the exponential growth of tourism, the government is planning to exploit groundwater and convey it by aqueduct to the abovementioned locality. The objectives of this study were to corroborate the conceptual geohydrological model, to develop a mathematical model to simulate the response of the aquifer to different scenarios, and to assess the incidence of water input into the system as a variable—a function that poses difficulties in the models for arid regions. The Visual Modflow 4.1 code was used, calibrating it in trial-and-error mode, changing the recharge and hydraulic conductivity parameters with different variants in the recharge zone and in the inclusion or exclusion of the evapotranspiration module. Results indicate the importance of the recharge analysis by treating rainfall at daily time steps. The adjusted model was exposed to four scenarios with variations in water input and in output by pumping. It can be concluded that under different input conditions, but with a controlled extraction, the system responds in a sustainable manner.  相似文献   

Occurrence of perfluorinated compounds in water, sediment and mussels from the Cantabrian Sea (North Spain)   总被引：1，自引：0，他引：1  

Gómez C  Vicente J  Echavarri-Erasun B  Porte C  Lacorte S 《Marine pollution bulletin》2011,62(5):948-955

Perfluorinated compounds (PFCs) have emerged as significant global environmental pollutants with persistent, bioaccumulative and toxic properties. The aim of this study was to determine the occurrence of PFCs in water (wastewater, submarine emissaries and port-waters), sediment and transplanted mussels in estuarine areas of high urban and industrial impact from Northern Spain. Five PFCs of industrial use were studied: perfluorooctanesulfonate, perfluorohexanesulfonate, perfluorobutanesulfonate, perfluorooctanoate acid and perfluorononanoate acid. After selective extraction, samples were analyzed by Ultra Performance Liquid Chromatography coupled to tandem mass spectrometry. ΣPFCs ranged from 0.06 to 10.9 ng/L in water, with higher levels in wastewater treatment plants effluents and port waters than in submarine emissaries. Little accumulation was observed in sediments and mussels with ΣPFCs ranging from 0.01-0.13 ng/g dw and 0.01-0.06 ng/g ww, respectively. Most ubiquitous compounds were PFOS and PFOA. Mass fluxes of PFCs to the Cantabrian Sea are estimated and the impact to the coastal ecosystem is discussed.  相似文献   

Comparison of coral growth and survival under enclosed,semi-natural conditions and in the field     

Yap HT  Molina RA 《Marine pollution bulletin》2003,46(7):858-864

Two closely related scleractinian coral species, Porites cylindrica and Porites rus, were transplanted to two different locations: the natural environment on the reef flat, and culture tanks on land. The use of tanks enabled the regulation of certain environmental factors, and, hence, the evaluation of specific responses of the corals to these factors. For both species, growth and survival were much better in the field than in the land-based tanks most probably due to unrestricted water circulation. Since the two species were subjected to identical experimental treatments, it was possible to distinguish inherent differences between them in terms of responses to external variables. Porites cylindrica was more susceptible than P. rus to predation by corallivores. Predators, as well as grazers, occurred in significant numbers in the field, but not in the land-based tanks. Porites rus, on the other hand, succumbed more readily to overgrowth by macroalgae which thrived in the culture tanks presumably because of significantly higher nutrient levels and the conspicuous absence of grazers. These results have broader ecological implications because of accelerated environmental changes taking place in present-day reefs due to human impact. Major examples are eutrophication and alterations in water circulation which frequently result in sub-optimal conditions for coral survival and growth.  相似文献   

Modeling the onset of photosynthesis after the Chicxulub asteroid impact     

Noel Perez  Rolando Cardenas  Osmel Martin  Reinaldo Rojas 《Astrophysics and Space Science》2013,343(1):7-10

We do a preliminary modelling of the photosynthetic rates of phytoplankton at the very beginning of the Paleogene, just after the impact of the Chicxulub asteroid, which decisively contributed to the last known mass extinction of the Phanerozoic eon. We assume the worst possible scenario from the photobiological point of view: an already clear atmosphere with no ozone, as the timescale for soot and dust settling (years) is smaller than that of the full ozone regeneration (decades). Even in these conditions we show that most phytoplankton species would have had reasonable potential for photosynthesis in all the three main optical ocean water types. This modelling could help explain why the recovery of phytoplankton was relatively rapid after the huge environmental stress of that asteroid impact. In a more general scope, it also reminds us of the great resilience of the unicellular biosphere against huge environmental perturbations.  相似文献