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211.
Cryptomaria are mare basalt deposits hidden or obscured by superposed higher albedo material or variations in albedo. They represent a record of the earliest mare volcanism, and may be a significant volumetric contribution to the volcanic and magmatic history of the Moon. In order to assess their global distribution and significance, criteria for the identification of cryptomaria are developed and techniques for locating them are described. These criteria and techniques include the presence of dark halo craters, identification by spectral mixing analysis, identification by geochemical evidence, association with light plains units, location within basin topography, proximity to known mare, relation to mascons indicated by gravity anomalies, and identification of the source of an obscuring agent, such as crater ejecta. On the basis of these criteria and techniques, several types of cryptomare are recognized, depending on the nature of ejecta and mare materials. Cryptomaria may be formed when maria are obscured by coverings of proximal or distal basin ejecta, or by crater ejecta dusting, or when ejecta covers over basalts which lack a distinctive 1µm absorption band. Using these concepts we outline three case studies: 1) the Schiller-Schickard region adjacent to the Orientale basin, classified as a basin-ejecta cryptomare and grading from distal to proximal, with possible crater-ejecta covering occurring in the southwestern portion of the region, 2) the Balmer basin, classified as a crater-ejecta-dusting cryptomare, and 3) the Australe basin, in which two types of cryptomare were identified: a) crater-ejecta-dusting on old mare patches and b) possible distal-basin-ejecta covering even older mare material. These case studies provide criteria for the further global identification and classification of cryptomaria and stress the need for utilization of multiple criteria and data sets.  相似文献   
212.
Detailed compositional data for the sterols isolated from a surface, Unit I, sediment from the Black Sea are reported. A procedure based on digitonin precipitation has been used to separate the more abundant free sterols from those occurring in esterified forms. Saponification of the solvent extracted sediment residue liberated only a small quantity of residual bound sterols in contrast to studies of other sediments. 4-Methylsterols are much more abundant than 4-desmethylsterols in both the free and esterified sterol fractions which we attribute to a major dinoflagellate input, as in deeper Unit II sediment. The desmethylsterol fraction appears to derive from a variety of sources including dinoflagellates, coccolithophores, diatoms, terrigenous detritus and perhaps invertebrates. 5α(H)-Stanols are particularly abundant in the free sterol fraction. An analysis of the stanol/stenol ratios suggests that the 4-desmethyl-5α(H)-stanols are the result of specific microbial reductions of Δ5-sterols and/or the reflection of a contribution of stanol containing source organisms.  相似文献   
213.
Two limited series of alkan-1, 15-diols and alkan-15-one-1-ols with chain lengths of 30, 31 and 32 carbon atoms have been isolated from extracts of Unit I (0–3000 yr BP) and Unit II (3000–7000 yr BP) Black Sea sediments.  相似文献   
214.
The lithostratigraphic framework of Lake Van, eastern Turkey, has been systematically analysed to document the sedimentary evolution and the environmental history of the lake during the past ca 600 000 years. The lithostratigraphy and chemostratigraphy of a 219 m long drill core from Lake Van serve to separate global climate oscillations from local factors caused by tectonic and volcanic activity. An age model was established based on the climatostratigraphic alignment of chemical and lithological signatures, validated by 40Ar/39Ar ages. The drilled sequence consists of ca 76% lacustrine carbonaceous clayey silt, ca 2% fluvial deposits, ca 17% volcaniclastic deposits and 5% gaps. Six lacustrine lithotypes were separated from the fluvial and event deposits, such as volcaniclastics (ca 300 layers) and graded beds (ca 375 layers), and their depositional environments are documented. These lithotypes are: (i) graded beds frequently intercalated with varved clayey silts reflecting rising lake levels during the terminations; (ii) varved clayey silts reflecting strong seasonality and an intralake oxic–anoxic boundary, for example, lake‐level highstands during interglacials/interstadials; (iii) CaCO3‐rich banded sediments which are representative of a lowering of the oxic–anoxic boundary, for example, lake level decreases during glacial inceptions; (iv) CaCO3‐poor banded and mottled clayey silts reflecting an oxic–anoxic boundary close to the sediment–water interface, for example, lake‐level lowstands during glacials/stadials; (v) diatomaceous muds were deposited during the early beginning of the lake as a fresh water system; and (vi) fluvial sands and gravels indicating the initial flooding of the lake basin. The recurrence of lithologies (i) to (iv) follows the past five glacial/interglacial cycles. A 20 m thick disturbed unit reflects an interval of major tectonic activity in Lake Van at ca 414 ka bp . Although local environmental processes such as tectonic and volcanic activity influenced sedimentation, the lithostratigraphic pattern and organic matter content clearly reflect past global climate changes, making Lake Van an outstanding terrestrial archive of unprecedented sensitivity for the reconstruction of the regional climate over the last 600 000 years.  相似文献   
215.
Sulfide-rich tailings are a well-known environmental threat due to their production of acid drainage (AD) and release of potential toxic elements (PTE) to the local environment. The presence of heterogeneous materials produces complex environmental signatures and complicates the quantitative prediction of contamination. The present work provides a method of quantifying such heterogeneities, starting from mineral processing data of the Reps, Mirdita (Albania) site. A quantitative flow sheet (QF) method was applied to a selected dump site of the Mirdita copper mining district where secondary pyrite separation had been used in the past. The site is subject to long-lasting (103 years) AD processes with significant release of PTE into the local environment. The tailings at the Reps site are divided into two classes based on the sulfide S content, respectively, represented by high-sulfide-content (S > 10 wt%) materials (hS) and low-sulfide-content (S < 3 wt%) material (lS). The reconstruction of the QF allowed us to identify the hS tailings as the discharge of single-flotation processing lines. This material accounts for about 82% of the total potential H2SO4 production, even though it represents < 20% of the entire tailing discard. The QF is a useful tool for the evaluation of heterogeneity and consequently for the modeling of waste management within abandoned sites and in working plants. Given a good quantification, heterogeneity can in fact support the setting of pyrite separation lines or the separate management of pyrite-rich tailing dumps.  相似文献   
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