Effect of $$\hbox {CO}_2$$ solubility on dissolution rate of calcite in saline aquifers for temperature range of 50–100 $$^{\circ } \hbox {C}$$∘C and pressures up to 600 bar: alterations of fractures geometry in carbonate rocks by $$\hbox {CO}_2$$-acidified brines     

Mohammad A. Nomeli  Amir Riaz 《Environmental Earth Sciences》2017,76(9):352

An empirical model is developed to predict the dissolution rate of calcite in saline solutions that are saturated with respect to dissolved \(\hbox {CO}_2\) over a broad range of both subcritical and supercritical conditions. The focus is on determining the rate of calcite dissolution within a temperature range of 50–100 \(^\circ \hbox {C}\) and pressures up to 600 bar, relevant for \(\hbox {CO}_2\) sequestration in saline aquifers. A general reaction kinetic model is used that is based on the extension of the standard Arrhenius equation with an added, solubility-dependent, pH term to account for the saturated concentration of dissolved \(\hbox {CO}_2\). On the basis of this kinetic model, a new rate equation is obtained using multi-parameter, nonlinear regression of experimental data to determine the dissolution of calcite as a function of temperature, pressure and salinity. Different models for the activity coefficient of \(\hbox {CO}_2\) dissolved in saline solutions are accounted for. The new rate equation helps us obtain good agreement with experimental data, and it is applied to study the geochemically induced alterations of fracture geometry due to calcite dissolution.  相似文献   

Impact of tailings dam failure on spatial features of copper contamination (Mazraeh mine area,Iran)     

Amir Khamseh  Farzin Shahbazi  Shahin Oustan  Nosrattollah Najafi  Nasser Davatgar 《Arabian Journal of Geosciences》2017,10(11):244

Mining activities pose a potential risk of metal contamination around mining sites. On May 6, 2010, a tailings dam failure of the Mazraeh copper mine near Ahar in East Azerbaijan province, Iran, released vast amounts of mine wastes. To better understand the magnitude of copper contamination in the waste-affected soils, it is important to assess the spatial distribution of soil copper content at unsampled points. A total of 30 soil samples and their surficial sediments together with the 6 uncontaminated control samples (0–10 and 10–30 cm) were collected along the stream flow that joined Ahar-Chai River. Some of soil properties as well as total copper concentration were determined in all samples. The mean value of the latter in the surface contaminated soils was found to be approximately two times more than controls. Furthermore, the mean concentration of copper in the surface loaded material was 10 times more than the soils. High copper concentrations were observed in surficial sediments of the soils near the broken tailings dam. The Inverse Distance Weighting (IDW) method was employed in data analysis. The spherical and Gaussian semivariogram models were properly fitted to the data of copper contents in soils and surficial sediments.  相似文献   

Study on the improving method for gas production prediction in tight clastic reservoir     

Amir Maher Sayed Lala  Hany Maher Sayed Lala 《Arabian Journal of Geosciences》2017,10(3):70

Relative permeability and resistivity index are important parameters for the exploration and development in a tight sandstone gas field. In the splitting method which uses permeability (K), reservoir thickness (H), and relative permeability (K), briefly referred to as the KHK splitting method, the accuracy of the relative permeability is crucial. According to the relationship between resistivity index and relative permeability of the Mesozoic Lower Safa Formation at Obaiyed Field in the Western Desert of Egypt, we improved the split method and made it more in line with the real situation by adopting Pairoys’ model which is more suitable to our study area. In this paper, we use a radial basis function (RBF) to establish the relationship between logging data and the gas production split point to point in tight sandstone gas reservoirs. To compare with the result by support vector regression (SVR), our method is better as indicated by mean absolute error values. In order to solve the problem that the relative permeability is difficult to obtain in the well logging evaluation, we also provide a convenient method and application example.  相似文献   

Preservation of organic matter in soils of a climo-biosequence in the Main Range of Peninsular Malaysia     

Amir Hossein Jafarzadeh-Haghighi  Jusop Shamshuddin  Jol Hamdan  Norhazlin Zainuddin 《山地科学学报》2017,14(9):1763-1775

Limited information is available about factors of soil organic carbon(SOC) preservation in soils along a climo-biosequence. The objective of this study was to evaluate the role of soil texture and mineralogy on preservation of SOC in the topsoil and subsoil along a climo-biosequence in the Main Range of Peninsular Malaysia. Soil samples from the A and B-horizons of four representative soil profiles were subjected to particle-size fractionation and mineralogical analyses including X-ray diffraction and selective dissolution. The proportion of SOC in the 250-2000 μm fraction(SOC associated with coarse sand) decreased while the proportion of SOC in the 53 μm fraction(SOC associated with clay and silt)increased with depth. This reflected the importance of the fine mineral fractions of the soil matrix for SOC storage in the subsoil. Close relationships between the content of SOC in the 53 μm fraction and the content of poorly crystalline Fe oxides [oxalate-extractable Fe(Fe_o) – pyrophosphate-extractable Fe(Fe_p)] and poorly crystalline inorganic forms of Al [oxalateextractable Al(Al_o) – pyrophosphate-extractable Al(Al_p)] in the B-horizon indicated the importance of poorly crystalline Fe oxides and poorly crystalline aluminosilicates for the preservation of SOC in the Bhorizon. The increasing trend of Fe_o-Fe_p and Al_o-Al_p over elevation suggest that the importance of poorly crystalline Fe oxides and poorly crystalline aluminosilicates for the preservation of SOC in the Bhorizon increased with increasing elevation. This study demonstrates that regardless of differences in climate and vegetation along the studied climobiosequence, preservation of SOC in the subsoil depends on clay mineralogy.  相似文献