Synchrotron-based X-ray study of iron oxide transformations in terraces from the Tinto-Odiel river system: Influence on arsenic mobility     

Rafael Pérez-López  Maria P. Asta  Gabriela Román-Ross  José Miguel Nieto  Carles Ayora  Rémi Tucoulou 《Chemical Geology》2011,280(3-4):336-343

Simultaneous analysis of micro-X-ray diffraction (μ-XRD) and micro-X-ray fluorescence (μ-XRF) based on synchrotron light sources, and electron microprobe (EMP) analyses, were performed on iron terrace samples taken from Tinto-Odiel river system from the Iberian Pyrite Belt (IBP, SW Iberian Peninsula). Iron terraces are formed during the oxidation and precipitation of dissolved iron along the riverbeds impacted by acid mine drainage (AMD). This paper includes the study of actively-forming current terraces and fossil terraces isolated from the stream courses due to the river migration over time. The results of the study of current terrace samples from AMD-affected streams of two IPB abandoned mines (Tinto Santa Rosa and Cueva de la Mora) showed that fresh precipitates at the surface are composed primarily of metastable schwertmannite, which is gradually transformed at depth over short-time scales into goethite. Sediments of ancient terraces are composed mainly of goethite, which most likely originated from the re-crystallization of a precursor schwertmannite. However, at century-time scale, goethite partially re-crystallizes to hematite due to diagenetic processes. The transformation rate of goethite into hematite is negatively correlated with grain size and the crystallinity of goethite. Moreover, this transformation is accompanied by an increase in grain size and a decrease in surface area of hematite, and a concomitant decrease in arsenic trapped in the solid. This increase in the arsenic mobility during the diagenetic maturation should be considered in the development of conceptual and analytical models describing long-term fate, transport and bioavailability of arsenic in environmental systems.  相似文献   

An Analytical Model for Hydraulic Fracturing in Shallow Bedrock Formations     

José Sérgio dos Santos  Thomas Paul Ballestero  Ernesto da Silva Pitombeira 《Ground water》2011,49(3):415-425

A theoretical method is proposed to estimate post‐fracturing fracture size and transmissivity, and as a test of the methodology, data collected from two wells were used for verification. This method can be employed before hydrofracturing in order to obtain estimates of the potential hydraulic benefits of hydraulic fracturing. Five different pumping test analysis methods were used to evaluate the well hydraulic data. The most effective methods were the Papadopulos‐Cooper model (1967), which includes wellbore storage effects, and the Gringarten‐Ramey model (1974), known as the single horizontal fracture model. The hydraulic parameters resulting from fitting these models to the field data revealed that as a result of hydraulic fracturing, the transmissivity increased more than 46 times in one well and increased 285 times in the other well. The model developed by dos Santos (2008) , which considers horizontal radial fracture propagation from the hydraulically fractured well, was used to estimate potential fracture geometry after hydrofracturing. For the two studied wells, their fractures could have propagated to distances of almost 175 m or more and developed maximum apertures of about 2.20 mm and hydraulic apertures close to 0.30 mm. Fracturing at this site appears to have expanded and propagated existing fractures and not created new fractures. Hydraulic apertures calculated from pumping test analyses closely matched the results obtained from the hydraulic fracturing model. As a result of this model, post‐fracturing geometry and resulting post‐fracturing well yield can be estimated before the actual hydrofracturing.  相似文献   

Coupled silicon–oxygen isotope fractionation traces Archaean silicification     

K. Abraham  A. Hofmann  S.F. Foley  D. Cardinal  C. Harris  M.G. Barth  L. André 《Earth and Planetary Science Letters》2011,301(1-2):222-230

Silica alteration zones and cherts are a conspicuous feature of Archaean greenstone belts worldwide and provide evidence of extensive mobilisation of silica in the marine environment of the early Earth. In order to understand the process(es) of silicification we measured the silicon and oxygen isotope composition of sections of variably silicified basalts and overlying bedded cherts from the Theespruit, Hooggenoeg and Kromberg Formations of the Barberton Greenstone Belt, South Africa.The δ³⁰Si and δ¹⁸O values of bulk rock increase with increasing amount of silicification from unsilicified basalts (?0.64‰ < δ³⁰Si < ?0.01‰ and + 8.6‰ < δ¹⁸O < + 11.9‰) to silicified basalts (δ³⁰Si and δ¹⁸O values as high as + 0.81‰ and + 15.6‰, respectively). Cherts generally have positive isotope ratios (+ 0.21‰ < δ³⁰Si < + 1.05‰ and + 10.9 < δ¹⁸O < + 17.1), except two cherts, which have negative δ³⁰Si values, but high δ¹⁸O (up to + 19.5‰).The pronounced positive correlations between δ³⁰Si, δ¹⁸O and SiO₂ imply that the isotope variation is driven by the silicification process which coevally introduced both ¹⁸O and ³⁰Si into the basalts. The oxygen isotope variation in the basalts from about 8.6‰ to 15.6‰ is likely to represent temperature-dependent isotope fractionation during alteration. Our proposed model for the observed silicon isotope variation relies on a temperature-controlled basalt dissolution vs. silica deposition process.  相似文献   

Coping with climate variability and climate change in La Ceiba,Honduras     

Joel B. Smith  Kenneth M. Strzepek  Julio Cardini  Mario Castaneda  Julie Holland  Carlos Quiroz  Tom M. L. Wigley  Jose Herrero  Peter Hearne  John Furlow 《Climatic change》2011,108(3):457-470

La Ceiba, Honduras, a city of about 200,000 people, lies along the Caribbean Sea, nestled against a mountain range and the Rio Cangrejal. The city faces three flooding risks: routine flooding of city streets due to the lack of a stormwater drainage system; occasional major flooding of the Rio Cangrejal, which flows through the city; and flooding from heavy rainfall events and storm surges associated with tropical cyclones. In this study, we applied a method developed for the U.S. Agency for International Development and then worked with stakeholders in La Ceiba to understand climate change risks and evaluate adaptation alternatives. We estimated the impacts of climate change on the current flooding risks and on efforts to mitigate the flooding problems. The climate change scenarios, which addressed sea level rise and flooding, were based on the Intergovernmental Panel on Climate Change estimates of sea level rise (Houghton et al. 2001) and published literature linking changes in temperature to more intense precipitation (Trenberth et al., Bull Am Meteorol Soc, 84:1205–1217, 2003) and hurricanes (Knutson and Tuleya, J Clim, 17:3477–3495, 2004). Using information from Trenberth et al., Bull Am Meteorol Soc, 84:1205–1217, (2003) and Knutson and Tuleya, J Clim, 17:3477–3495, 2004, we scaled intense precipitation and hurricane wind speed based on projected temperature increases. We estimated the volume of precipitation in intense events to increase by 2 to 4% in 2025 and by 6 to 14% by 2050. A 13% increase in intense precipitation, the high scenario for 2050, could increase peak 5-year flood flows by about 60%. Building an enhanced urban drainage system that could cope with the estimated increased flooding would cost one-third more than building a system to handle current climate conditions, but would avoid costlier reconstruction in the future. The flow of the Rio Cangrejal would increase by one-third from more intense hurricanes. The costs of raising levees to protect the population from increased risks from climate change would be about $1 million. The coast west of downtown La Ceiba is the most vulnerable to sea level rise and storm surges. It is relatively undeveloped, but is projected to have rapid development. Setbacks on coastal construction in that area may limit risks. The downtown coastline is also at risk and may need to be protected with groins and sand pumping. Stakeholders in La Ceiba concluded that addressing problems of urban drainage should be a top priority. They emphasized improved management of the Rio Cangrejal watershed and improved storm warnings to cope with risks from extreme precipitation and cyclones. Adoption of risk management principles and effective land use management could also help reduce risks from current climate and climate change.  相似文献   

Marine debris ingestion by Magellanic penguins, Spheniscus magellanicus (Aves: Sphenisciformes), from the Brazilian coastal zone     

Brandão ML  Braga KM  Luque JL 《Marine pollution bulletin》2011,62(10):2246-2249

Magellanic penguins (Spheniscus magellanicus) are non-breeding winter visitors to the Brazilian coast. In 2008 and 2010, plastic items and other marine debris were found in the stomachs and intestines of 15% of 175 dead penguins collected in the Lagos Region of the state of Rio de Janeiro. One bird had its stomach perforated by a plastic straw, which may have caused its death. There are few records of penguins ingesting plastic litter, but previous studies have found similar levels of debris ingestion among Magellanic penguins stranded on the Brazilian coast (35.8% of 397 birds). The high incidence of marine debris in this species in Brazil may result at least in part from the predominance of juveniles reaching these waters, as juvenile penguins may have a broader diet than adults. It is unclear to what extent plastic ingestion affects the mortality rate in this species and whether the incidence in stranded birds reflects that in the entire population. The present study addresses the increasing impact of plastic debris on marine life.  相似文献   

On the crystal structure and compressional behavior of talc: a mineral of interest in petrology and material science   总被引：1，自引：1，他引：0  

G. Diego Gatta  Marco Merlini  Giovanni Valdrè  Hanns-Peter Liermann  Gwilherm Nénert  André Rothkirch  Volker Kahlenberg  Alessandro Pavese 《Physics and Chemistry of Minerals》2013,40(2):145-156

The crystal structure of a natural triclinic talc (1Tc polytype) [with composition: (Mg_2.93Fe_0.06)_Σ2.99(Al_0.02Si_3.97)_Σ3.99O₁₀(OH)_2.10] has been investigated by single-crystal X-ray diffraction at 223 and 170 K and by single-crystal neutron diffraction at 20 K. Both the anisotropic X-ray refinements (i.e. at 223 and 170 K) show that the two independent tetrahedra are only slightly distorted. For the two independent Mg-octahedra, the bond distances between cation-hydroxyl groups are significantly shorter than the others. The ditrigonal rotation angle of the six-membered ring of tetrahedra is modest (α ~ 4°). The neutron structure refinement shows that the hydrogen-bonding scheme in talc consists of one donor site and three acceptors (i.e. trifurcated configuration), all the bonds having O···O ≤ 3.38 Å, H···O ~ 2.8 Å, and O–H···O ~ 111–116°. The three acceptors belong to the six-membered ring of tetrahedra juxtaposed to the octahedral sheet. The vibrational regime of the proton site appears being only slightly anisotropic. The elastic behavior of talc was investigated by means of in situ synchrotron single-crystal diffraction up to 16 GPa (at room temperature) using a diamond anvil cell. No evidence of phase transition has been observed within the pressure range investigated. P–V data fit, with an isothermal third-order Birch-Murnaghan equation of state, results as follows: V ₀ = 454.7(10) Å³, K _T0 = 56(3) GPa, and K′ = 5.4(7). The “Eulerian finite strain” versus “normalized stress” plot yields: Fe(0) = 56(2) GPa and K′ = 5.3(5). The compressional behavior of talc is strongly anisotropic, as reflected by the axial compressibilities (i.e. β(a):β(b):β(c) = 1.03:1:3.15) as well as by the magnitude and orientation of the unit-strain ellipsoid (with ε ₁:ε ₂:ε ₃ = 1:1.37:3.21). A comparison between the elastic parameters of talc obtained in this study with those previously reported is carried out.  相似文献   

Hydromechanical Analysis of Masonry Gravity Dams and their Foundations   总被引：1，自引：1，他引：0  

Eduardo M. Bretas  José V. Lemos  Paulo B. Lourenço 《Rock Mechanics and Rock Engineering》2013,46(2):327-339

A numerical model for the hydromechanical analysis of masonry dams based on the discrete element method is presented. The dam and the rock foundation are represented as block assemblies, and a coupled flow-stress analysis is performed in an integrated manner for the entire system. Complex block shapes may be obtained by assembling elementary blocks into macroblocks, allowing the application of the model to situations ranging from equivalent continuum to fully discontinuum analysis. A contact formulation was developed based on an accurate edge–edge approach, incorporating mechanical and hydraulic behavior. The main numerical aspects are described, with an emphasis in the flow analysis explicit algorithm. An application to an existing masonry dam is presented, analyzing its present condition, with excessive seepage, and the proposed rehabilitation intervention. An evaluation of sliding failure mechanisms was also performed, showing the expected improvement in the safety of the structure.  相似文献   

Debris-flow susceptibility of upland catchments     

Mélanie Bertrand  Frédéric Liébault  Hervé Piégay 《Natural Hazards》2013,67(2):497-511

Over the last three decades, many regional studies in mountain ranges under temperate climate revealed that it is possible to discriminate debris-flow and fluvial fans from morphometric indicators measured at the scale of the catchment and the fan itself. The most commonly used indicators are the Melton index (R), a normalized index of the gravitational energy of the catchment, and the fan slope (S). A wide range of thresholds have been proposed for discriminating purpose, but these are generally based on a small population of catchments and may be highly influenced by ambiguous fans included in the data set. A database of 620 upland catchments from several mountain ranges under temperate climate was compiled from the literature to propose robust discriminant morphometric thresholds for debris-flow versus fluvial responses. Linear discriminant analysis (LDA) and logistic regression (LR) were performed using the whole data set, and a leave-one-out cross-validation was used to evaluate performances of the models. Sensitivity and specificity scores obtained for LDA and LR were 0.96 and 0.73, and 0.95 and 0.75, respectively. It is also shown that the channel slope above which debris-flow is observed decreases with the gravitational energy of the catchment. Limitations of the morphometric discrimination are discussed.  相似文献   

Strutted Excavation in Soft Soil Incorporating a Jet-Grout Base Slab: Analysis Considering the Consolidation Effect     

José Leitão Borges  Ricardo Gomes Pinto 《Geotechnical and Geological Engineering》2013,31(2):593-615

The influence of the consolidation on a strutted excavation in soft soil is analysed using a computer code based on the finite element method. A base jet-grout slab is considered in order to improve stability against bottom heave failure and minimize wall displacements. The numerical model incorporates the Biot consolidation theory (coupled formulation of the flow and equilibrium equations) with soil constitutive relations simulated by the p–q–θ critical state model. Special emphasis is given to the analysis, during and after the construction period, of the pore pressures, shear stresses, stress levels and displacements in the ground, as well as strut compression loads, wall displacements and bending moments, earth pressures on the wall faces and compression loads and bending moments on the jet-grout slab. The safety factor against bottom heave is also evaluated from the finite element analysis considering formulations of the critical state soil mechanics, and also compared to values obtained with traditional methods that use limit equilibrium approach and bearing capacity fundamentals.  相似文献   

Les Montagnes Noires : cisaillement bordier méridional du bassin carbonifère de Châteaulin (Massif Armoricain,France). Caractéristiques structurales et métamorphiques     

Jean-René Darboux  Bernard Le Gall 《Geodinamica Acta》2013,26(3):121-133

Résumé

L’évolution structurale et métamorphique de la zone des Montagnes Noires, qui borde vers le sud le bassin carbonifère de Châteaulin, est contrôlée par le fonctionnement d’un cisaillement trans-current dextre. Le caractère unique, mais progressif et inhomogène, de la déformation régionale d’âge carbonifère supérieur conduit à remettre en cause le concept d’une structuration hercynienne polyphasée et celui de « phase bretonne ».  相似文献