Sulfurous acid (H₂SO₃) on Io?     

Andreas F. Voegele  Christofer S. Tautermann  Andreas Hallbrucker  Erwin Mayer  Klaus R. Liedl 《Icarus》2004,169(1):242-249

Sulfurous acid (H₂SO₃) has never been characterized or isolated on Earth. This is caused by the unfavorable conditions for H₂SO₃ within Earth's atmosphere due to the high temperatures, the high water content and the oxidizing environment. Kinetic investigations by means of transition state theory showed that the half-life of H₂SO₃ at 300 K is 1 day but at 100 K it is increased to 2.7 billion years. Natural conditions to form H₂SO₃ presumably require cryogenic SO₂ or SO₂/H₂O mixtures and high energy proton irradiation at temperatures around 100 K. Such conditions can be found on the Jupiter moons Io and Europa. Therefore, we calculated IR-spectra of H₂SO₃ which we compared with Galileo's spectra of Io and Europa. From the available data we surmise that H₂SO₃ is present on Io and probably but to a smaller extent on Europa.  相似文献   

I Zwicky 1: Decomposition and dynamics of the nearby QSO host     

Julia Scharwächter  Andreas Eckart  Susanne Pfalzner  Johannes Staguhn  Eva Schinnerer 《Astrophysics and Space Science》2003,284(2):507-510

We address current theories of research on morphology, environment and evolution of active galaxies in the form of a detailed case study of the nearby QSO host I Zw 1. This study is based on sub-kpc resolution ¹²CO(1-0) observations with the BIMA mm-interferometer and on near-infrared imaging with ISAAC at the VLT. The ¹²CO(1-0) maps reveal a circumnuclear molecular gas ring with a radius of 0.9 kpc. The imaging data in the J-band are analyzed with respect to a disk-bulge decomposition. Together with a model of the gas rotation curve, the radial profile of the dynamical J-band mass-to-light ratio (M/L) is discussed. The J-band images give new evidence for an interaction between I Zw 1 and its nearby companion. First results from a sequence of N-body simulations for an extensive test of the parameter space of the interaction are presented. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   

Assessing the Vibrational Frequencies of the Holweide Hospital in the City of Cologne (Germany) by Means of Ambient Seismic Noise Analysis and FE modelling     

Stefano?ParolaiEmail author  Andreas?F?cke  Sandra?M.?Richwalski  Lothar?Stempniwski 《Natural Hazards》2005,34(2):217-230

Ambient seismic noise measurements were conducted inside the Holweide Hospital (Cologne) for checking whether its frequencies of vibration fall into the range where soil amplification is expected. If this is the case, damage might increase in case of an earthquake due to an amplified structural response of the building. Two different techniques were used: the ratio between the horizontal and vertical components of the spectra recorded at stations located inside the building and the ratio between the corresponding components of the spectra recorded simultaneously inside the building and at a reference station placed outside. While the former method might be preferred because of less equipment involved, the latter has the advantage of producing more stable results and deleting automatically the influence of the sedimentary cover, which might obscure some eigenfrequencies of vibration of the building. An independently performed finite-element analysis of the hospital showed a good correlation between measured and calculated eigenmodes.  相似文献   

Topography and morphodynamics in the German Bight using SAR and optical remote sensing data   总被引：3，自引：0，他引：3  

Andreas Niedermeier  Danielle Hoja  Susanne Lehner 《Ocean Dynamics》2005,55(2):100-109

Morphological changes in coastal areas, especially in river estuaries, are of high interest in many parts of the world. Satellite data from both optical and radar sensors can help to monitor and investigate these changes. Data from both kinds of sensors being available for up to 30 years now, allow examinations over large timescales, while high resolution sensors developed within the last decade allow increased accuracy. So the creation of digital elevation models (DEMs) of, for example, the wadden sea from a series of satellite images is already possible. ENVISAT, successfully launched on March 1, 2002, continues the line of higher resolution synthetic aperture radar (SAR) imaging sensors with its ASAR instrument and now also allows several polarization modes for better separation of land and water areas. This article gives an overview of sensors and algorithms for waterline determination as well as several applications. Both optical and SAR images are considered. Applications include morphodynamic monitoring studies and DEM generation.

Andreas NiedermeierEmail:

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Feeding Monsters – A Study of Active Galaxies     

Melanie Krips  Andreas Eckart  Roberto Neri  Joerg-Uwe Pott  Jens Zuther  Julia Scharwächter  Thomas Bertram 《Astrophysics and Space Science》2005,295(1-2):95-100

We present new interferometric observations of the molecular gas distribution and kinematics in the nuclei of different active galaxies at high angular resolution and high sensitivity carried out with the IRAM Plateau de Bure interferometer (PdBI). The observations cover galaxies in a redshift range of 0.03–1.4. We have so far observed five different active galaxies: NGC3718, NGC1068, HE1029–1831, 3C48 and Q0957+561. The first two objects belong to the NUGA (NUclei of GAlaxies) project – an international collaboration mainly between Spain, France and Germany – containing about 30 Seyfert and LINER galaxies. Both are at the same distance of 14Mpc and show a warped gas and dust disk. The new mosaic map of NGC3718 corrected for short-spacing effects with IRAM 30 m observations well demonstrates the existence of the warped gas disk with several secondary maxima in the projected gas distribution caused by orbit crowding effects. Based on these new data we have improved recent simulations of the warped disk in NGC3718. HE1029–1831 and 3C48 are nearby QSOs. HE1029–1831 is taken out of the Cologne nearby QSO sample. The maps of the integrated CO(1–0) and CO(2–1) emission clearly show that the molecular gas is mostly related to the central bulge with a non-negligible fraction distributed along the bar known from optical observations. Our new CO data of 3C48 unveil new information about the kinematics of its molecular gas complementing and improving further studies based on previous infrared observations and detailed multi-particle simulations. Finally, new measurements of the CO(1–0) line in Q0957+561 – a highly-red-shifted, gravitationally lensed quasar – will be presented as a link to earlier evolutionary stages of active galaxies and their hosts.  相似文献   

DDTs and other chlorinated organic pesticides and polychlorinated biphenyls pollution in the surface sediments of Keratsini harbour, Saronikos gulf, Greece   总被引：2，自引：0，他引：2  

Galanopoulou S  Vgenopoulos A  Conispoliatis N 《Marine pollution bulletin》2005,50(5):520-525

Sediment samples were collected from Keratsini harbour, Saronikos gulf, Greece and were analysed for chlorinated organic pesticides (DDTs, HCB, Lindane) and polychlorinated biphenyls (PCBs). High total DDTs values were detected in all the sediments samples ranging from 9.1 to 75.6 mug/g, dry weight. PCBs concentrations range from 47.8 to 351.8 ng/g. The results and especially the high concentrations of DDTs reflect the influence of the industrial and urban wastes in the pollution for the Keratsini harbour environment.  相似文献   

Reliability checking for GNSS baseline and network processing     

Andreas?WieserEmail author 《GPS Solutions》2004,8(2):55-66

Reliability analysis is inseparably connected with the formulation of failure scenarios, and common test statistics are based on specific assumptions. This is easily overlooked when processing observation differences. Poor failure identification performance and misleading pre-analysis results, mainly meaningless minimum detectable biases and external reliability measures, are the consequence. A reasonable failure scenario for use with differenced GNSS observations is formulated which takes into account that individual outliers in the original data affect more than one processed observation. The proper test statistics and reliability indicators are given for use with correlated observations and both batch processing and Kalman filtering. It is also shown that standardized residuals and redundancy numbers fail completely when used with double differenced observations.

Andreas WieserEmail: Phone: +43-316-8736323Fax: +43-316-8736820

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A kinetic model of metamorphism: an application to siliceous dolomites     

Andreas?LüttgeEmail author  Edward?W.?Bolton  Danny?M.?Rye 《Contributions to Mineralogy and Petrology》2004,146(5):546-565

We use a kinetic model of a metamorphic system to study the effect of competing rates of reaction, fluid injection, and heating on the evolution of the reaction pathway in temperature/composition space at constant pressure. We show that for rocks in contact with mixed volatile (e.g., CO₂-H₂O) fluids the reaction path may be quite different from what is expected from equilibrium-based petrologic models. Equilibrium-based models, used to understand the development of rock systems undergoing mineral reactions during a metamorphic event, rely on the Gibbs phase rule and only consider stable phases. For constant pressure, the temperature-composition paths follow univariant curves and significant reactions may occur at invariant points. By contrast, the more general kinetic treatment is not constrained by equilibrium, although with the proper competing rates equilibrium is a possible endmember of the kinetic approach. The deviation from equilibrium depends on the competing rates of reaction, heating, and fluid injection. A key element required by the kinetic approach is the inclusion of metastable reactions in the formulation, whereas such reactions are irrelevant for equilibrium-based models. Metastable reactions are often involved in a complex interplay with common prograde stable metamorphic reactions. We present model results for the well-studied CaO-MgO-SiO₂-CO₂-H₂O (CMS) system to show how the system evolves under kinetic control. Our simulations and discussion focus on the behavior of the CMS system under a number of closed and open system conditions. Special attention is paid to closed system behavior in the vicinity of the (first) isobaric invariant point (with Dol, Qtz, Tlc, Cal, and Tr). Also, for open systems with massive fluid infiltration we consider heating rates varying from contact to regional metamorphic conditions. For some geologically reasonable rates of reactions, heating, and fluid injection, our results demonstrate that equilibrium conditions may be significantly overstepped in metamorphic systems. We used overall mineral reactions in this model with rates based on experimental results. Future models could rely on more fundamental dissolution and precipitation reactions. Such an extension would require additional kinetic rate data, as well as mineral solubilities in mixed volatile fluids.Editorial responsibility: J. Hoefs  相似文献   

Melt extraction pathways and stagnation depths beneath the Madeira and Desertas rift zones (NE Atlantic) inferred from barometric studies     

Stefanie?SchwarzEmail author  Andreas?Klügel  Cora?Wohlgemuth-Ueberwasser 《Contributions to Mineralogy and Petrology》2004,147(2):228-240

The Madeira and Desertas Islands (eastern North Atlantic) show well-developed rift zones which intersect near the eastern tip of Madeira (São Lourenço peninsula). We applied fluid inclusion barometry and clinopyroxene-melt thermobarometry to reconstruct levels of magma stagnation beneath the two adjacent rifts and to examine a possible genetic relationship during their evolution. Densities of CO₂-dominated fluid inclusions in basanitic to basaltic samples from São Lourenço yielded frequency maxima at pressures of 0.57–0.87 GPa (23–29 km depth) and 0.25–0.32 GPa (8–10 km), whereas basanites, basalts and xenoliths from the Desertas indicate 0.3–0.72 GPa (10–24 km) and 0.07–0.12 GPa (2–3 km). Clinopyroxene-melt thermobarometry applied to Ti-augite phenocryst rim and glass/groundmass compositions indicates pressures of 0.45–1.06 GPa (15–35 km; São Lourenço) and 0.53–0.89 GPa (17–28 km; Desertas Islands) which partly overlap with pressures indicated by fluid inclusions. We interpret our data to suggest a multi-stage magma ascent beneath the Madeira Archipelago: main fractionation occurs at multiple levels within the mantle (>15 km depth) and is followed by temporary stagnation within the crust prior to eruption. Depths of crustal magma stagnation beneath São Lourenço and the Desertas differ significantly, and there is no evidence for a common shallow magma reservoir feeding both rift arms. We discuss two models to explain the relations between the two adjacent rift systems: Madeira and the Desertas may represent either a two-armed rift system or two volcanic centres with separate magma supply systems. For petrological and volcanological reasons, we favour the second model and suggest that Madeira and the Desertas root in distinct regions of melt extraction. Magma focusing into the Desertas system off the hotspot axis may result from lithospheric bending caused by the load of the Madeira and Porto Santo shields, combined with regional variations in melt production due to an irregularly shaped plume.Electronic Supplementary Material Supplementary material is available for this article if you access the article at . A link in the frame on the left on that page takes you directly to the supplementary material.Editorial responsibility: J. Hoefs  相似文献   

A late glacial Antarctic climate teleconnection and variable Holocene seasonality at Lake Pupuke, Auckland, New Zealand     

Thomas Stephens  Daniel Atkin  Paul Augustinus  Philip Shane  Andrew Lorrey  Alayne Street-Perrott  Andreas Nilsson  Ian Snowball 《Journal of Paleolimnology》2012,48(4):785-800

We present the first continuous paleolimnological reconstruction from the North Island of New Zealand (37°S) that spans the last 48.2?cal kyr. A tephra- and radiocarbon-based chronology was developed to infer the timing of marked paleolimnological changes in Lake Pupuke, Auckland, New Zealand, identified using sedimentology, magnetic susceptibility, grain size and geochemistry (carbon, nitrogen and sulphur concentrations and fluxes, carbon and nitrogen stable isotopes). Variable erosional influx, biomass and benthic REDOX conditions are linked to changing effective precipitation and seasonality within three inferred broad intervals of climatic change: (1) the Last Glacial Coldest Phase (LGCP) of reduced effective precipitation and cooler temperatures, from 28.8 to 18.0?cal kyr BP, (2) the Last Glacial Interglacial Transition (LGIT) of increasing effective precipitation and warmer conditions, from 18.0 to 10.2?cal?kyr?BP, and (3) a Holocene interval of high effective precipitation, beginning with a warm period of limited seasonality from 10.2?cal?kyr?BP and followed by increasing seasonality from 7.6?cal?kyr?BP. The LGCP and LGIT also contain millennial-scale climate events, including the coldest inferred glacial conditions during the LGCP from 27.8 to 26.0 and 22.0?C19.0?cal?kyr?BP, and a climate reversal in the LGIT associated with lower lake level, from 14.5 to 13.8?cal?kyr?BP, coeval with the Antarctic Cold Reversal. The onset of seasonal thermal stratification occurred at 5.7?cal?kyr?BP and was linked to natural eutrophication of Lake Pupuke, which produced enhanced organic sedimentation.  相似文献