Surface structure effects on direct reduction of iron oxides by Shewanella oneidensis     

Andrew L. Neal  Kevin M. Rosso  Yuri A. Gorby 《Geochimica et cosmochimica acta》2003,67(23):4489-4503

The atomic and electronic structure of mineral surfaces affects many environmentally important processes such as adsorption phenomena. They are however rarely considered relevant to dissimilatory bacterial reduction of iron and manganese minerals. In this regard, surface area and thermodynamics are more commonly considered. Here we take a first step towards understanding the nature of the influence of mineral surface structure upon the rate of electron transfer from Shewanella oneidensis strain MR-1 outer membrane proteins to the mineral surface and the subsequent effect upon cell “activity.” Cell accumulation has been used as a proxy for cell activity at three iron oxide single crystal faces; hematite (001), magnetite (111) and magnetite (100). Clear differences in cell accumulation at, and release from the surfaces are observed, with significantly more cells accumulating at hematite (001) compared to either magnetite face whilst relatively more cells are released into the overlying aqueous phase from the two magnetite faces than hematite. Modeling of the electron transfer process to the different mineral surfaces from a decaheme (protoporphyrin rings containing a central hexacoordinate iron atom), outer membrane-bound cytochrome of S. oneidensis has been accomplished by employing both Marcus and ab initio density functional theories. The resultant model of electron transfer to the three oxide faces predicts that over the entire range of expected electron transfer distances the highest electron transfer rates occur at the hematite (001) surface, mirroring the observed cell accumulation data. Electron transfer rates to either of the two magnetite surfaces are slower, with magnetite (111) slower than hematite (001) by approximately two orders of magnitude. A lack of knowledge regarding the structural details of the heme-mineral interface, especially in regards to atomic distances and relative orientations of hemes and surface iron atoms and the conformation of the protein envelope, precludes a more thorough analysis. However, the results of the modeling concur with the empirical observation that mineral surface structure has a clear influence on mineral surface-associated cell activity. Thus surface structure effects must be accounted for in future studies of cell-mineral interactions.  相似文献   

Formation of metal in Grosvenor Mountains 95551 and comparison to ordinary chondrites     

Andrew J. Campbell 《Geochimica et cosmochimica acta》2003,67(13):2481-2495

Siderophile element abundances in individual metal grains in the ungrouped chondrite Grosvenor Mountains (GRO) 95551 and in the ordinary chondrites Tieschitz H3.6, Soko-Banja LL4, and Allegan H5 were measured with laser ablation-inductively coupled plasma mass spectrometry. Matrix metal in GRO 95551 falls into two distinct compositional groups, a high-Ni group with 7.2 ± 0.4 wt% Ni and a low-Ni group with 3.7 ± 0.1 wt% Ni, indicating that kamacite/taenite equilibration at ∼1020 K was followed by rapid cooling. The nonrefractory siderophile elements P, Co, Cu, Ga, Ge, As, Pd, and Au also partition between the high-Ni and low-Ni metal in a manner consistent with kamacite/taenite fractionation, but the refractory siderophiles Ru, Re, Os, Ir, and Pt show correlated variations that are unrelated to kamacite/taenite partitioning and indicate that variations in refractory components of the metal were not completely erased during equilibration at ∼1020 K. The Ni-normalized bulk metal composition of GRO 95551 is refractory depleted and volatile rich relative to Bencubbin and related metal-rich chondrites but bears strong similarities to equilibrated ordinary chondrite metal. GRO 95551 represents a new chondrite type with chemical affinity to the ordinary chondrites. Individual metal grains in unequlibrated ordinary chondrites also have correlated variations in refractory siderophile contents that cannot be produced by redox processes alone; these variations span three orders of magnitude and diminish with increasing metamorphic grade of the ordinary chondrites.  相似文献   

Distribution of isomorphous cations within octahedral sheets in montmorillonite from Camp-Bertaux     

F. Muller  G. Besson  A. Manceau  V.-A. Drits 《Physics and Chemistry of Minerals》1997,24(3):159-166

 Ni-saturated montmorillonite from Camp-Bertaux heated at different temperatures has been studied by X-ray powder diffraction, X-ray absorption (EXAFS) and vibration IR spectroscopy. Analysis of the experimental data has shown that heating of samples at temperatures higher than 150° C was accompanied by migration of Ni cations into vacant cis-octahedra of 2:1 layers. In the octahedral sheet the Ni cation has two “heavy” (Fe) and four “light” (Al and Mg) nearest octahedral cations. A model for the octahedral cation distribution in Camp-Bertaux montmorillonite was proposed in which Fe and Mg octahedral cations are segregated in small clusters. Received July 7, 1996 / Revised, accepted August 23, 1996  相似文献   

Invariants in toroidal and tangentially geostrophic frozen-flux velocity fields     

Andrew Jackson  Raymond Hide 《Geophysical Journal International》1996,125(3):925-927

We derive two new types of invariant that must be obeyed by the radial magnetic field at the core-mantle boundary if the hypothesis of frozen flux is valid and the fluid motion is either toroidal or tangentially geostrophic there. These general invariants incorporate specific invariants that are already known and can, in principle, be tested using magnetic data that cover an interval of time.  相似文献   

A new form of the cokriging equations     

Andrew E. Long  Donald E. Myers 《Mathematical Geology》1997,29(5):685-703

Myers developed a matrix form of the cokriging equations, but one that entails the solution of a large system of linear equations. Large systems are troublesome because of memory requirements and a general increase in the matrix condition number. We transform Myers’s system into a set of smaller systems, whose solution gives the classical kriging results, and provides simultaneously a nested set of lower dimensional cokriging results. In the course of developing the new formulation we make an interesting link to the Cauchy-Schwarz condition for the invertibility of a system, and another to a simple situation of coregionalization. In addition, we proceed from these new equations to a linear approximation to the cokriging results in the event that the crossvariograms are small, allowing one to take advantage of a recent results of Xie and others which proceeds by diagonalizing the variogram matrix function over the lag classes.  相似文献   

Mitigating the Effects of Climate Change on the Water Resources of the Columbia River Basin   总被引：5，自引：3，他引：5  

Jeffrey T. Payne  Andrew W. Wood  Alan F. Hamlet  Richard N. Palmer  Dennis P. Lettenmaier 《Climatic change》2004,62(1-3):233-256

The potential effects of climate change on the hydrology and water resources of the Columbia River Basin (CRB) were evaluated using simulations from the U.S. Department of Energy and National Center for Atmospheric Research Parallel Climate Model (DOE/NCAR PCM). This study focuses on three climate projections for the 21st century based on a `business as usual' (BAU) global emissions scenario, evaluated with respect to a control climate scenario based on static 1995 emissions. Time-varying monthly PCM temperature and precipitation changes were statistically downscaled and temporally disaggregated to produce daily forcings that drove a macro-scale hydrologic simulation model of the Columbia River basin at 1/4-degree spatial resolution. For comparison with the direct statistical downscaling approach, a dynamical downscaling approach using a regional climate model (RCM) was also used to derive hydrologic model forcings for 20-year subsets from the PCM control climate (1995–2015) scenario and from the three BAU climate(2040–2060) projections. The statistically downscaled PCM scenario results were assessed for three analysis periods (denoted Periods 1–3: 2010–2039,2040–2069, 2070–2098) in which changes in annual average temperature were +0.5,+1.3 and +2.1 °C, respectively, while critical winter season precipitation changes were –3, +5 and +1 percent. For RCM, the predicted temperature change for the 2040–2060 period was +1.2 °C and the average winter precipitation change was –3 percent, relative to the RCM controlclimate. Due to the modest changes in winter precipitation, temperature changes dominated the simulated hydrologic effects by reducing winter snow accumulation, thus shifting summer streamflow to the winter. The hydrologic changes caused increased competition for reservoir storage between firm hydropower and instream flow targets developed pursuant to the Endangered Species Act listing of Columbia River salmonids. We examined several alternative reservoir operating policies designed to mitigate reservoir system performance losses. In general, the combination of earlier reservoir refill with greater storage allocations for instream flow targets mitigated some of the negative impacts to flow, but only with significant losses in firm hydropower production (ranging from –9 percent in Period1 to –35 percent for RCM). Simulated hydropower revenue changes were lessthan 5 percent for all scenarios, however, primarily due to small changes inannual runoff.  相似文献   

Comment on “Deconvolving the δO-seawater component from subseasonal coral δO and Sr/Ca at Rarotonga in the southwestern subtropical Pacific for the period 1726 to 1997,” by L. Ren, B. K. Linsley, G. M. Wellington, D. P. Schrag, and O Hoegh-Guldberg (2003)     

Amit Huppert  Andrew R Solow 《Geochimica et cosmochimica acta》2004,68(14):3137-3138

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Exploring the attractions of city centre living: evidence and policy implications in British cities   总被引：1，自引：0，他引：1  

Andrew R. Tallon  Rosemary D. F. Bromley   《Geoforum》2004,35(6):771-787

The British city centre has been the focus of dynamic housing development and repopulation strategies as a key dimension of the government's urban renaissance programme. Through large scale interview surveys in the provincial city centres of Bristol and Swansea, this paper explores the positive and negative features of city centre living, and how these vary amongst a range of social and physical characteristics. The findings suggest that the practical and mundane attractions of city centre living are more important than the more widely publicised lifestyle and cultural attractions of the city centre commonly emphasised in the gentrification literature. Moreover, the research points to differences in attitudes between age groups, with younger adults placing greater value on the range of social and cultural activities in the city centre, whilst older people express high levels of satisfaction with the attractiveness of the environment. A number of policy implications emerge to encourage inclusive marketing strategies within the continued urban renaissance, particularly to challenge the negative perceptions and promote the varied attractions of city centre living to a mix of social groups.  相似文献   

Geochemical Correlation Between Metasediments of the Mfongosi Group of the Natal Sector of the Namaqua-Natal Metamorphic Province, South Africa and the Ahlmannryggen Group of the Grunehogna Province, Antarctica     

Ian J. Basson  Samantha Perritt  Michael K. Watkeys  Andrew H. Menzies   《Gondwana Research》2004,7(1):57-73

The whole-rock geochemistry of metamorphosed greywackes, arenites and arkoses within the Mesoproterozoic Namaqua-Natal-Maudheim Province is interpreted with the aim of establishing geochemical correlations and defining common sediment source terrains. Metasediments of the Mfongosi Group of the Natal Sector of the Namaqua-Natal Metamorphic Province were sampled from their type area in the Mfongosi Valley. Metagreywackes from the northern limits of the Mfongosi Valley, directly adjacent to the Kaapvaal Craton, show ocean island arc signatures while metagreywackes from the southern limits of the Mfongosi Valley, near the contact with the Madidima Thrust of the Natal nappe zone, show mainly active continental margin signatures. Interleaved, geochemically distinct low-Ca+Na, high-K metamorphosed arkoses to lithic arkoses indicate a minor passive margin sediment component. Geochemical classification of low-grade Ahlmannryggen Group greywackes, arenites and arkoses of the Grunehogna Province, Antarctica, indicates both active and passive continental margin sediment sources. An oceanic island arc signature is not evident in Ahlmannryggen Group data. The active continental margin signature in both Natal Sector and Grunehogna Province metasediments potentially provides for a common link between these terranes. Discriminant Function Analysis, using three pre-defined provenance sub-sets within the Mfongosi Group and two pre-defined provenance sub-sets within the Ahlmannryggen Group, indicate that metasediments with active continental margin signatures from both groups are geochemically identical, implying that the active continental margin of the Grunehogna Province shed immature sediments westwards (African azimuths) into the developing, narrow or restricted Mesoproterozoic ‘Mfongosi Basin.’ This was accompanied by minor sediment influx from a stable continental platform, potentially the Kaapvaal Craton. Oblique and diachronous collision, initiated in the southwestern portions of the combined Natal Sector/Grunehogna Province system produced a laterally variable Mfongosi Group, which formed in the ‘Mfongosi Basin’. Coarse-grained sediments dominated in its eastern portions while basalts with thin sapropelite units dominated in its western portions.  相似文献   

Doing groups: Situating knowledge and creating stories     

Andrew McGregor 《The Australian geographer》2004,35(2):141-149

This paper presents group research as a potentially powerful research tool for cultural geographers interested in the ways knowledge is produced at the interpersonal level. I argue that groups can create unique research spaces that incorporate 'sociality', the everyday social norms, logics and languages that guide ordinary conversations, into the research agenda. By concentrating on these discursive norms, insights can be obtained into the ways that knowledge is negotiated, produced and constrained in different places. To demonstrate the value of group research, a case study involving Australian environmentalists is analysed, to show how forests are constructed, contested and naturalised within this particular subculture. The article concludes by emphasising the importance of group research to critical geographers interested in social empowerment and change.  相似文献