Hydrogen bonding system in euchroite,Cu2(AsO4)(OH)(H2O)3: low-temperature crystal-structure refinement and solid-state density functional theory modeling     

Sergey V. Krivovichev  Andrey A. Zolotarev  Igor V. Pekov 《Mineralogy and Petrology》2016,110(6):877-883

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Biostratigraphy of the Upper Pleistocene (Upper Neopleistocene)–Holocene deposits of the Lemeza River valley of the Southern Urals region (Russia)     

Guzel Danukalova  Anatoly Yakovlev  Liliana Alimbekova  Tatyana Yakovleva  Evgenija Morozova  Andrey Eremeev  Pavel Kosintsev 《Quaternary International》2008,190(1):38

Numerous caves and terraces with late Late Pleistocene (Upper Neopleistocene according to the Russian stratigraphic scale)–Holocene deposits are located in the Lemeza River valley in the surroundings of the Atysh waterfall, the native reserve territory of the Bashkortostan Republic. Lemeza River runs in the southern part of the western slope of the Urals and belongs to the Belaya River valley system (Russian Federation). A summary of the biostratigraphical investigations between 1992 and 2007 in this area is given. Deposits of cave and fluvial origin are characterized in the framework of the regional stratigraphy. The results of mammalian investigations and radiocarbon dating provide the basis for the stratigraphical subdivision. Palynology, mollusca, fishes, amphibian and reptiles are used for the reconstruction the palaeoenvironments. The Southern Urals stratigraphic subdivisions are correlated with Western European (Weichselian-Holocene), Eastern European (Russia) (Leningrad–Ostashkov–Shuvalov) and Uralian (Nevyansk–Polar Urals–Gorbunovsky) stratigraphic schemes.  相似文献   

Air–Sea/Land Interaction in the Coastal Zone     

Andrey A. Grachev  Laura S. Leo  Harindra J. S. Fernando  Christopher W. Fairall  Edward Creegan  Byron W. Blomquist  Adam J. Christman  Christopher M. Hocut 《Boundary-Layer Meteorology》2018,167(2):181-210

Atmospheric turbulence measurements made at the U.S. Army Corps of Engineers Field Research Facility (FRF) located on the Atlantic coast near the town of Duck, North Carolina during the CASPER-East Program (October–November 2015) are used to study air–sea/land coupling in the FRF coastal zone. Turbulence and mean meteorological data were collected at multiple levels (up to four) on three towers deployed at different landward distances from the shoreline, with a fourth tower located at the end of a 560-m-long FRF pier. The data enable comparison of turbulent fluxes and other statistics, as well as investigations of surface-layer scaling for different footprints, including relatively smooth sea-surface conditions and aerodynamically rough dry inland areas. Both stable and unstable stratifications were observed. The drag coefficient and diurnal variation of the sensible heat flux are found to be indicators for disparate surface footprints. The drag coefficient over the land footprint is significantly greater, by as much as an order of magnitude, compared with that over the smooth sea-surface footprint. For onshore flow, the internal boundary layer in the coastal zone was either stable or (mostly) unstable, and varied dramatically at the land-surface discontinuity. The offshore flow of generally warm air over the cooler sea surface produced a stable internal boundary layer over the ocean surface downstream from the coast. While the coastal inhomogeneities violate the assumptions underlying Monin–Obukhov similarity theory (MOST), any deviations from MOST are less profound for the scaled standard deviations and the dissipation rate over both water and land, as well as for stable and unstable conditions. Observations, however, show a poor correspondence with MOST for the flux-profile relationships. Suitably-averaged, non-dimensional profiles of wind speed and temperature vary significantly among the different flux towers and observation levels, with high data scatter. Overall, the statistical dependence of the vertical gradients of scaled wind speed and temperature on the Monin–Obukhov stability parameter in the coastal area is weak, if not non-existent.  相似文献   

A GIS-based modeling of snow accumulation and melt processes in the Votkinsk reservoir basin     

Sergey V. Pyankov  Andrey N. Shikhov  Nikolay A. Kalinin  Eugene M. Sviyazov 《地理学报(英文版)》2018,28(2):221-237

Coupled hydrological and atmospheric modeling is an efficient method for snowmelt runoff forecast in large basins. We use short-range precipitation forecasts of mesoscale atmospheric Weather Research and Forecasting (WRF) model combining them with ground-based and satellite observations for modeling snow accumulation and snowmelt processes in the Votkinsk reservoir basin (184,319 km²). The method is tested during three winter seasons (2012–2015). The MODIS-based vegetation map and leaf area index data are used to calculate the snowmelt intensity and snow evaporation in the studied basin. The GIS-based snow accumulation and snowmelt modeling provides a reliable and highly detailed spatial distribution for snow water equivalent (SWE) and snow-covered areas (SCA). The modelling results are validated by comparing actual and estimated SWE and SCA data. The actual SCA results are derived from MODIS satellite data. The algorithm for assessing the SCA by MODIS data (ATBD-MOD 10) has been adapted to a forest zone. In general, the proposed method provides satisfactory results for maximum SWE calculations. The calculation accuracy is slightly degraded during snowmelt periods. The SCA data is simulated with a higher reliability than the SWE data. The differences between the simulated and actual SWE may be explained by the overestimation of the WRF-simulated total precipitation and the unrepresentativeness of the SWE measurements (snow survey).  相似文献   

Rainfall–runoff model parameter estimation and uncertainty evaluation on small plots          下载免费PDF全文

Keewook Kim  Gene Whelan  S. Thomas Purucker  Thomas F. Bohrmann  Michael J. Cyterski  Marirosa Molina  Yin Gu  Yakov Pachepsky  Andrey Guber  Dorcas H. Franklin 《水文研究》2014,28(20):5220-5235

Four seasonal rainfall simulations in 2009 and 2010 were applied to a field containing 36 plots (0.75 × 2 m each), resulting in 144 runoff events. In all simulations, a constant rate of rainfall was applied then halted 60 min after initiation of runoff, with plot‐scale monitoring of runoff every 5 min during that period. Runoff was simulated with the Kinematic Runoff and Erosion/Simulator of Transport with Infiltration and Runoff (KINEROS2/STWIR) field‐scale model, whose hydrodynamics are based on the kinematic wave equation. Because of the non‐linear nature of the model and a highly parameterized model with respect to the available data, several approaches were investigated to upscale nine runoff‐related parameters from a series of small monitored plots to the field scale. Inverse modeling was performed using the model‐independent Parameter ESTimation (PEST) algorithm to individually calibrate the nine KINEROS2/STWIR parameters on 36 plots. The parameters were averaged, and bootstrapping was used to assess uncertainty of the parameters via estimation of confidence intervals (CI). A Monte Carlo simulation using the bootstrap results showed reasonable field‐scale representation of flow rates. Median values of calibrated parameters were within the 95% CI obtained with bootstrapping. The simulated results for the median values associated with the 90% CI flow rates produced similar trends as those exhibited with the observed data, suggesting that median values of the calibrated parameters from the PEST inverse modeling could be used to represent the field scale. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Mammal fauna during the Late Pleistocene and Holocene in the far northeast of Europe     

Dmitry Ponomarev  Andrey Puzachenko  Olga Bachura  Pavel Kosintsev  Johannes van der Plicht 《Boreas: An International Journal of Quaternary Research》2013,42(3):779-797

The paper summarises materials on the mammal remains in northeastern Europe, dated by radiocarbon. Altogether, 23 local faunas of small mammals and 47 local faunas of large mammals were analysed. Multidimensional statistical analysis shows a strong correlation between changes in small mammal fauna composition and climate changes throughout time. The correlations with the spatial gradients, however, are less pronounced. The faunas are classified into three groups: (1) faunas of Holocene age; (2) Late Pleistocene ‘stadial’ assemblages; and (3) Late Pleistocene ‘interstadial’ assemblages. In some cases, changes in species abundance are better understood in terms of biotic interrelations rather than of climatic effects. The most pronounced change in small mammal fauna composition and structure occurred at the Preboreal/Boreal boundary, and a less conspicuous alteration took place at the LGM/Lateglacial transition. The most noticeable transformation in the large mammal fauna composition is dated to the early Holocene. Less significant changes are observed at the Middle Weichselian/LGM transition and at the LGM/Lateglacial transition. It is safely concluded that variations in the faunas of small and large mammals recorded in NE Europe during the last 35 000 years occurred synchronously and unidirectionally.  相似文献   

An invariant theory of the linearized shallow water equations with rotation and its application to a sphere and a plane     

Nathan Paldor  Andrey Sigalov 《Dynamics of Atmospheres and Oceans》2011,51(1-2):26-44

The system of linearized shallow water equations is formulated in this paper on any rotating and smooth surface M in terms of differential geometry. The system decouples into two separate equations: a scalar one for the height deviation and a vector one for the velocity field. For low and high frequencies these equations yield asymptotic equations whose solutions are the generalizations of the Poincare and Rossby waves to smooth surface. The application of these equations to the β-plane yields both new and previously known equations for the height deviation and for the velocity components. The application of the equations to the rotating spherical Earth shows that the meridional amplitudes of Poincare and Rossby waves are both described by the prolate angular spheroidal wave functions. The asymptotic and the power series expansions of the eigenvalues of these functions yield new approximations for the dispersion relations of these waves on a sphere. The new dispersion relations are very accurate in the physically relevant range of the single nondimensional model parameter – the square of the nondimensional gravity waves’ phase speed. The invariant formulation can also be applied to other surfaces that are of geophysical interest such as an oblate ellipsoid of revolution.  相似文献   

On the nature of lead–lag relationships during glacial–interglacial climate transitions     

Andrey Ganopolski  Didier M. Roche 《Quaternary Science Reviews》2009,28(27-28):3361-3378

Analysis of leads and lags between different paleoclimate records remains an important method in paleoclimatology, used to propose and test hypotheses about causal relationships between different processes in the climate system. The robust lead of Antarctic temperature over CO₂ concentration during several recent glacial–interglacial transitions inferred from the Antarctic ice cores apparently contradicts the concept of CO₂-driven climate change and still remains unexplained. Here, using an Earth system model of intermediate complexity and generic scenarios for the principal climatic forcings during glacial–interglacial transitions we performed a suite of experiments that shed some light on the complexity of phase relationships between climate forcing and climate system response. In particular, our results provide an explanation for the observed Antarctic temperature lead over CO₂ concentration. It is shown that the interhemispheric oceanic heat transport provides a crucial link between the two hemispheres. We demonstrate that temporal variations of the oceanic heat transport strongly contribute to the observed phase relationship between polar temperature records in both hemispheres. It is shown that the direct effect of orbital variations on the Antarctic temperature is also significant and explains the observed cooling trend during interglacials. In addition, an imbedded δ¹⁸O model is used to demonstrate that during glacial–interglacial transitions, the temporal evolution of deep calcite marine δ¹⁸O in different locations and at different depths can considerably deviate from that implied by the global ice volume change. This finding indicates that the synchronization of different marine records by means of foraminiferal calcite δ¹⁸O yield large additional uncertainties. Based on our results, we argue that the analysis of leads and lags alone, without a comprehensive understanding and an adequate model of all relevant climate processes, cannot provide direct information about causal relationships in the climate system.  相似文献   

Geochemistry of ultrahigh-pressure anatexis: fractionation of elements in the Kokchetav gneisses during melting at diamond-facies conditions     

Aleksandr S. Stepanov  Joerg Hermann  Andrey V. Korsakov  Daniela Rubatto 《Contributions to Mineralogy and Petrology》2014,167(5):1-25

The Kokchetav complex in Kazakhstan contains garnet-bearing gneisses that formed by partial melting of metasedimentary rocks at ultrahigh-pressure (UHP) conditions. Partial melting and melt extraction from these rocks is documented by a decrease in K₂O and an increase in FeO + MgO in the restites. The most characteristic trace element feature of the Kokchetav UHP restites is a strong depletion in light rare earth elements (LREE), Th and U. This is attributed to complete dissolution of monazite/allanite in the melt and variable degree of melt extraction. In contrast, Zr concentrations remain approximately constant in all gneisses. Using experimentally determined solubilities of LREE and Zr in high-pressure melts, these data constrain the temperature of melting to ~1,000 °C. Large ion lithophile elements (LILE) are only moderately depleted in the samples that have the lowest U, Th and LREE contents, indicating that phengite retains some LILE in the residue. Some restites display an increase in Nb/Ta with respect to the protolith. This further suggests the presence of phengite, which, in contrast to rutile, preferentially incorporates Nb over Ta. The trace element fractionation observed during UHP anatexis in the Kokchetav gneisses is significantly different from depletions reported in low-pressure restites, where generally no LREE and Th depletion occurs. Melting at UHP conditions resulted in an increase in the Sm/Nd ratio and a decoupling of the Sm–Nd and Lu–Hf systems in the restite. Further subduction of such restites and mixing with mantle rocks might thus lead to a distinct isotopic reservoir different from the bulk continental crust.  相似文献   

Diversity and Adaptations of Immature Diptera in Semiaquatic Habitats at Shorelines of Hypersaline Lakes in the Crimea,with a Brief Review of Diptera in Mineralized Bodies of Water     

Andrey PRZHIBORO 《《地质学报》英文版》2014,88(Z1):98-100

正The order Diptera(Insecta)is one of animal groups most successful in the colonization of mineralized shallow aquatic and semiaquatic environments.At the same time,the taxonomic composition of Diptera,their role in  相似文献