Extreme variations in strontium initial ratios in ore-related fluids     

Jean M. Richardson  John Blenkinsop  Keith Bell 《Contributions to Mineralogy and Petrology》1990,104(5):516-529

Magmato-hydrothermal cassiterite-topaz ore at the Carboniferous East Kemptville (EK) greisenhosted tin deposit (Nova Scotia, Canada) is cross-cut by veins containing apatite, triplite, vivianite and fluorite. Initial ⁸⁷Sr/⁸⁶Sr ratios of these minerals have an extreme range (0.7135 to 0.8284). The initial ratios of the host rocks, EK quartz-topaz rock and Davis Lake biotite monzogranite (0.729±0.001, 0.727±0.004), are also high. The adjacent Meguma Group metasedimentary rocks are more typical of crustal material (0.712–0.719 at 330 Ma). Rb and Sr contents of EK fluorite (max.: 13.0, 1420 ppm) and apatite (max.: 88.1, 6660 ppm) are unusually high and variable. Unexpectedly, high Sr contents correlate positively with the high initial ⁸⁷Sr/⁸⁶Sr ratios. Fluorite and phosphate minerals from the first set of post-greisen veins at East Kemptville reflect the unusual chemistry of a high ⁸⁷Sr/⁸⁶Sr fluid present in the deposit after ore formation. The most extreme composition of this fluid was characterized by ⁸⁷Sr/⁸⁶Sr>0.8284, high Rb/Sr, high P, Rb, Cu, Zn and Fe contents, but low abundances of Ca, Pb and Sn with respect to the Davis Lake monzogranite. Such a fluid could have been derived from the greisen fluid and modified by reaction with the overlying Meguma metawacke. A second alternative, which cannot be well constrained at present, is that an extremely radiogenic fluid entered the deposit after ore formation and mixed with the postore fluid. In either case, the modified fluid subsequently mixed with meteoric water and precipitated the minerals with much lower ⁸⁷Sr/⁸⁶Sr ratios and Rb and Sr contents.  相似文献   

Strontium isotopic geochemistry of Pan-African/Brasiliano rocks,Chapada copper deposit,Goiás,Brazil     

Stephen V. Richardson  Lois M. Jones  Stephen E. Kesler 《International Journal of Earth Sciences》1988,77(3):763-770

Whole rock and mineral Rb-Sr isochrons from the upper amphibolite grade metamorphic host rocks of the Chapada copper deposit in Goiás, Brazil, yield an age of 561±9 Ma, with a⁸⁷Sr/⁸⁶Sr initial (I) of 0.70414±0.00005, for the crystallization of pre-metamorphic volcanic and igneous rocks and 532 ±1 Ma for their metamorphism during the Pan-African/Brasiliano orogeny (700-450 Ma). A porphyritic diorite stock which intruded the host schists yields a mineral isochron age of 534±16 Ma (I=0.70415±0.00004). The low I values determined from these isochrons suggest that the host schists at Chapada were derived from upper mantle or lower crust material and are characteristic of magmatic products associated with island arcs. The Early Cambrian age of the host rocks at Chapada contradicts the previously assigned mid-Proterozoic age and suggests that Pan-African/Brasiliano magmatic activity may have been more extensive in central Brazil than previously thought.

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Zusammenfassung Das Trägergestein der Chapada Kupferlagerstätte in Goiás ist in metamorpher Hoch-Amphibolitfazies ausgebildet. Gesamtgesteins- und individuelle Mineral Rb-Sr-Isochronen mit einem⁸⁷Sr/⁸⁶Sr-Initialwert (I) von 0,70414±0.00005 ergeben für die Kristallisation der Vulkanite und Magmatite, die die Metamorphose vordatieren, ein Alter von 561±9 Mio Jahre. Die Datierung der Metamorphose während der panafrikanisch/brasilianischen Orogenese (700 bis 450 Mio Jahre) ergibt 532±1 Mio Jahre. Das Mineral-Isochronenalter eines Dioritkörpers porphyrischen Gefüges, der in die Schiefer intrudierte, beträgt 534±16 Mio Jahre (I=0,70415 ±0,00004). Das Ergebnis niedriger Initial-Werte dieser Isochronen ergibt für die Schiefer bei Chapada ein Ausgangs-Material im Bereich des oberen Mantels oder der tieferen Kruste; diese Ausgangswerte sind charakteristisch für magmatische Tätigkeit in Verbindung mit Inselbögen. Das unterkambrische Alter des Trägergesteins bei Chapada steht im Widerspruch zu dem bisher angenommenen mittelproterozoischen Alter und ist ein Hinweis auf eine mögliche Phase intensiverer pan-afrikanisch/brasilianischer magmatischer Aktivität in Zentral-Brasilien als ursprünglich angenommen wurde.

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Résumé Les roches qui contiennent le gisement de cuivre de Chapada (Goias, Brésil) sont des schistes cristallins appartenent au facies dupérieur des amphibolites. Dans des volcanites et des roches orthomagmatiques appartenant à cet ensemble, des isochrones Rb-Sr sur roches totales et sur minéraux donnent un âge de 561±9 Ma avec un rapport initial de 0,70414±0,00005 pour la cristallisation pré-métamorphique et un âge de 532±1 Ma pour le métamorphisme, lié à l'orogenèse pan-africaine / brésilienne. Un pluton de diorite porphyrique, qui intrude les schistes cristallins donne, par isochrone sur minéraux, un âge de 534±16 Ma (rapport initial de 0,70415±0,00004). Les valeurs basses des rapports initiaux de ces diverses roches suggèrent que les schistes de Chapada sont dérivés de matériaux mantelliques ou crustaux profonds et présentent les caractères des produits magmatiques associés aux arcs insulaires. Leur âge éo-cambrien, en contradiction avec l'âge mésoprotérozoïque admis jusqu'ici, permet de penser que l'activité magmatique pan-africaine/brésilienne dans le centre du Brésil a été plus intense que ce qu'on croyait jusqu'ici.

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Chapada Gois . 0,70414±0,00005, 561± 9 , 532±1 , . . - / 700 450 /. , , 534±16 / 1 = 0,70415 = 0,00004 /. , Chapada , . . - ; , . , - - , , , .

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A comparison of geographic datasets and field measurements to model soil carbon using random forests and stepwise regressions (British Columbia,Canada)     

Heather J. Richardson  David J. Hill  Dan R. Denesiuk  Lauchlan H. Fraser 《地理信息系统科学与遥感》2017,54(4):573-591

We used geographic datasets and field measurements to examine the mechanisms that affect soil carbon (SC) storage for 65 grazed and non-grazed pastures in southern interior grasslands of British Columbia, Canada. Stepwise linear regression (SR) modeling was compared with random forest (RF) modeling. Models produced with SR performed better than those produced using RF models (r² = 0.56–0.77 AIC = 0.16–0.30 for SR models; r² = 0.38–0.53 and AIC = 0.18–0.30 for RF models). The factors most significant when predicting SC were elevation, precipitation, and the normalized difference vegetation index (NDVI). NDVI was evaluated at two scales using: (1) the MOD 13Q1 (250 m/16-day resolution) NDVI data product from the moderate resolution imaging spectro-radiometer (MODIS) (NDVI_MODIS), and (2) a handheld multispectral radiometer (MSR, 1 m resolution) (NDVI_MSR) in order to understand the potential for increasing model accuracy by increasing the spatial resolution of the gridded geographic datasets. When NDVI_MSR data were used to predict SC, the percentage of the variance explained by the model was greater than for models that relied on NDVI_MODIS data (r² = 0.68 for SC for non-grazed systems, modeled with SR based on NDVI_MODIS data; r² = 0.77 for SC for non-grazed systems, modeled with SR based on NDVI_MSR data). The outcomes of this study provide the groundwork for effective monitoring of SC using geographic datasets to enable a carbon offset program for the ranching industry.  相似文献   

A Regional Measure of Neighborhood Multiple Environmental Deprivation: Relationships with Health and Health Inequalities     

Elizabeth A. Richardson  Jamie Pearce  Rich Mitchell  Niamh K. Shortt 《The Professional geographer》2013,65(1):153-170

The health impacts of simultaneous exposure to multiple adverse environmental factors are of concern in the United Kingdom. UK-wide indicators exist, but context-specific finer resolution measures are lacking. An environmental deprivation index was developed for 398 neighborhoods (average population = 760) in a Scottish council area, including measures of air pollution, noise pollution, traffic environment, undesirable land uses, and crime. Adverse environmental conditions were related to ill health in the region and implicated in wider socioeconomic health inequalities. The results suggest an independent role for environmental deprivation in explaining poor health and health inequalities.  相似文献   

Erratum to “formation of asteroid families by catastrophic disruption: simulations with fragmentation and gravitational reaccumulation”: [Icarus 160 (2002) 10-23],     

Patrick Michel  Willy Benz  Paolo Tanga  Derek C Richardson 《Icarus》2003,161(1):198

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Land use and water quality     

Andy Baker 《水文研究》2003,17(12):2499-2501

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Decomposition of litter in a dry sclerophyll eucalypt forest and a Pinus radiata plantation in southeastern Australia     

R. H. Crockford  D. P. Richardson 《水文研究》2002,16(17):3317-3327

This study of litter decomposition was part of an extensive project examining the partitioning of rainfall, the associated chemistry, and litterfall in a dry sclerophyll eucalypt forest and a Pinus radiata plantation in southeastern Australia. The eucalypt species studied were Eucalyptus rossii, E. mannifera and E. dives. The components tested were Pinus radiata needles, leaves of the three eucalypt species, and the bark of E. rossii and E. mannifera. During the first 16 weeks of the decomposition experiment there was a rapid decrease in the concentrations of potassium, magnesium, sodium and phosphorus; this was attributed to leaching. During this period, concentrations of nitrogen and calcium increased for most components. After this period, decomposition became the dominant process, during which the concentrations of most elements increased. By the end of the experiment there was, compared with the initial values, a marked reduction in concentrations of sodium, magnesium and potassium for all eucalypt and pine litter. Calcium concentrations increased through time, with eucalypt bark showing a mid‐period decline. Phosphorus concentrations decreased for the eucalypt leaves but increased substantially for the pine needles and the eucalypt bark. For all components of both the eucalypts and pines, total nitrogen concentrations rose consistently throughout the decomposition period. This was attributed to the formation of nitrogen‐substituted lignin, which was more resistant to decomposition than the other nitrogen‐containing compounds, as well as some nitrogen being stored in the micro‐organisms responsible for decomposition. Because of loss of fragmented litter from the litter bags after 16 weeks, the weight changes could not be confidently measured after this period. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

Crater clusters on Mars: Shedding light on martian ejecta launch conditions     

Olga P. Popova  William K. Hartmann  Derek C. Richardson 《Icarus》2007,190(1):50-73

We have identified two classes of crater clusters on Mars. One class is “small clusters” (crater diameter D∼ tens m, spread over few hundred m), fitting our earlier calculations for the breakup of weak stone meteoroids in the martian atmosphere [Popova, O.P., Nemtchinov, I.V., Hartmann, W.K., 2003. Meteorit. Planet. Sci. 38, 905-925]. The second class is “large clusters” (D∼ few hundred m, spread over 2 to 30 km), which do not fit any predictions for breakup of known meteoroid types. We consider a range of possible explanations. The best explanation relates to known, high-speed ejection of large, semi-coherent, fractured rock masses from the surface, as secondary debris from primary impacts. The clusters are probably due to breakup of partly fracture, few-hundred-meter scale weak blocks, especially during ascent (producing moderate lateral spreading velocities among the fragments during sub-orbital flight), and also during descent of the resulting swarm. These conclusions illuminate the launch conditions of martian meteorites, including fragmentation processes, although more work is needed on the lateral separation of fragments (during either atmosphere descent or ascent) due to the effects of volatiles in the projectiles. Martian meteorites probably come from smaller martian craters than the clusters' source craters. The latter probably have D?85 km, although we have not ruled out diameters as small as 15 km.  相似文献   

Protein‐like fluorescence intensity as a possible tool for determining river water quality     

Andy Baker  Roger Inverarity 《水文研究》2004,18(15):2927-2945

The results of a comparison between chemical water quality determinants and river water fluorescence on the River Tyne, NE England, demonstrate that tryptophan‐like fluorescence intensity shows statistically significant relationships between nitrate, phosphate, ammonia, biochemical oxygen demand (BOD) and dissolved oxygen. Tryptophan‐like fluorescence intensity at the 280 nm excitation/350 nm emission wavelength fluorescence centre correlates with both phosphate (r = 0·80) and nitrate (r = 0·87), whereas tryptophan‐like fluorescence intensity at the 220 nm excitation/350 nm emission wavelength centre correlates with BOD (r = 0·85), ammonia (r = 0·70) and dissolved oxygen (r = ?0·65). The strongest correlations are between tryptophan‐like fluorescence intensity and nitrate and phosphate, which in the Tyne catchment derive predominantly from point and diffuse source sewage inputs. The correlation between BOD and the tryptophan‐like fluorescence intensity suggests that this fluorescence centre is related to the bioavailable or labile dissolved organic matter pool. The weakest correlations are observed between tryptophan‐like fluorescence intensity and ammonia concentration and dissolved oxygen. The weaker correlation with ammonia is due to removal of the ammonia signal by wastewater treatment, and that with dissolved oxygen due to the natural aeration of the river such that this is not a good indicator of water quality. The observed correlations only hold true when treated sewage, sewerage overflows or cross connections, or agricultural organic pollutants dominate the water quality—this is not true for two sites where airport deicer (propylene glycol, which is non‐fluorescent) or landfill leachate (which contains high concentrations of humic and fulvic‐like fluorescent DOM) dominate the dissolved organic matter in the river. Mean annual tryptophan‐like fluorescence intensity agrees well with the General Water Quality Assessment as determined by the England and Wales environmental regulators, the Environment Agency. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

Correlation Dependences Determined by Simultaneous Multispacecraft Observations of Solar Wind and IMF Structures     

P.A. Dalin  G.N. Zastenker  K.I. Paularena  J.D. Richardson 《Astrophysics and Space Science》2001,277(1-2):323-324

Solar wind measurements on board several spacecraft were used to study the two-points correlations of the solar wind plasma structures. The factor shaving the most influence on the correlation level are the density variability and IMF cone angle. The characteristic length of large solar wind structures is estimated at 500–1000 R _E. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献