Extreme variations in strontium initial ratios in ore-related fluids     

Jean M. Richardson  John Blenkinsop  Keith Bell 《Contributions to Mineralogy and Petrology》1990,104(5):516-529

Magmato-hydrothermal cassiterite-topaz ore at the Carboniferous East Kemptville (EK) greisenhosted tin deposit (Nova Scotia, Canada) is cross-cut by veins containing apatite, triplite, vivianite and fluorite. Initial ⁸⁷Sr/⁸⁶Sr ratios of these minerals have an extreme range (0.7135 to 0.8284). The initial ratios of the host rocks, EK quartz-topaz rock and Davis Lake biotite monzogranite (0.729±0.001, 0.727±0.004), are also high. The adjacent Meguma Group metasedimentary rocks are more typical of crustal material (0.712–0.719 at 330 Ma). Rb and Sr contents of EK fluorite (max.: 13.0, 1420 ppm) and apatite (max.: 88.1, 6660 ppm) are unusually high and variable. Unexpectedly, high Sr contents correlate positively with the high initial ⁸⁷Sr/⁸⁶Sr ratios. Fluorite and phosphate minerals from the first set of post-greisen veins at East Kemptville reflect the unusual chemistry of a high ⁸⁷Sr/⁸⁶Sr fluid present in the deposit after ore formation. The most extreme composition of this fluid was characterized by ⁸⁷Sr/⁸⁶Sr>0.8284, high Rb/Sr, high P, Rb, Cu, Zn and Fe contents, but low abundances of Ca, Pb and Sn with respect to the Davis Lake monzogranite. Such a fluid could have been derived from the greisen fluid and modified by reaction with the overlying Meguma metawacke. A second alternative, which cannot be well constrained at present, is that an extremely radiogenic fluid entered the deposit after ore formation and mixed with the postore fluid. In either case, the modified fluid subsequently mixed with meteoric water and precipitated the minerals with much lower ⁸⁷Sr/⁸⁶Sr ratios and Rb and Sr contents.  相似文献   

Strontium isotopic geochemistry of Pan-African/Brasiliano rocks,Chapada copper deposit,Goiás,Brazil     

Stephen V. Richardson  Lois M. Jones  Stephen E. Kesler 《International Journal of Earth Sciences》1988,77(3):763-770

Whole rock and mineral Rb-Sr isochrons from the upper amphibolite grade metamorphic host rocks of the Chapada copper deposit in Goiás, Brazil, yield an age of 561±9 Ma, with a⁸⁷Sr/⁸⁶Sr initial (I) of 0.70414±0.00005, for the crystallization of pre-metamorphic volcanic and igneous rocks and 532 ±1 Ma for their metamorphism during the Pan-African/Brasiliano orogeny (700-450 Ma). A porphyritic diorite stock which intruded the host schists yields a mineral isochron age of 534±16 Ma (I=0.70415±0.00004). The low I values determined from these isochrons suggest that the host schists at Chapada were derived from upper mantle or lower crust material and are characteristic of magmatic products associated with island arcs. The Early Cambrian age of the host rocks at Chapada contradicts the previously assigned mid-Proterozoic age and suggests that Pan-African/Brasiliano magmatic activity may have been more extensive in central Brazil than previously thought.

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Zusammenfassung Das Trägergestein der Chapada Kupferlagerstätte in Goiás ist in metamorpher Hoch-Amphibolitfazies ausgebildet. Gesamtgesteins- und individuelle Mineral Rb-Sr-Isochronen mit einem⁸⁷Sr/⁸⁶Sr-Initialwert (I) von 0,70414±0.00005 ergeben für die Kristallisation der Vulkanite und Magmatite, die die Metamorphose vordatieren, ein Alter von 561±9 Mio Jahre. Die Datierung der Metamorphose während der panafrikanisch/brasilianischen Orogenese (700 bis 450 Mio Jahre) ergibt 532±1 Mio Jahre. Das Mineral-Isochronenalter eines Dioritkörpers porphyrischen Gefüges, der in die Schiefer intrudierte, beträgt 534±16 Mio Jahre (I=0,70415 ±0,00004). Das Ergebnis niedriger Initial-Werte dieser Isochronen ergibt für die Schiefer bei Chapada ein Ausgangs-Material im Bereich des oberen Mantels oder der tieferen Kruste; diese Ausgangswerte sind charakteristisch für magmatische Tätigkeit in Verbindung mit Inselbögen. Das unterkambrische Alter des Trägergesteins bei Chapada steht im Widerspruch zu dem bisher angenommenen mittelproterozoischen Alter und ist ein Hinweis auf eine mögliche Phase intensiverer pan-afrikanisch/brasilianischer magmatischer Aktivität in Zentral-Brasilien als ursprünglich angenommen wurde.

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Résumé Les roches qui contiennent le gisement de cuivre de Chapada (Goias, Brésil) sont des schistes cristallins appartenent au facies dupérieur des amphibolites. Dans des volcanites et des roches orthomagmatiques appartenant à cet ensemble, des isochrones Rb-Sr sur roches totales et sur minéraux donnent un âge de 561±9 Ma avec un rapport initial de 0,70414±0,00005 pour la cristallisation pré-métamorphique et un âge de 532±1 Ma pour le métamorphisme, lié à l'orogenèse pan-africaine / brésilienne. Un pluton de diorite porphyrique, qui intrude les schistes cristallins donne, par isochrone sur minéraux, un âge de 534±16 Ma (rapport initial de 0,70415±0,00004). Les valeurs basses des rapports initiaux de ces diverses roches suggèrent que les schistes de Chapada sont dérivés de matériaux mantelliques ou crustaux profonds et présentent les caractères des produits magmatiques associés aux arcs insulaires. Leur âge éo-cambrien, en contradiction avec l'âge mésoprotérozoïque admis jusqu'ici, permet de penser que l'activité magmatique pan-africaine/brésilienne dans le centre du Brésil a été plus intense que ce qu'on croyait jusqu'ici.

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Chapada Gois . 0,70414±0,00005, 561± 9 , 532±1 , . . - / 700 450 /. , , 534±16 / 1 = 0,70415 = 0,00004 /. , Chapada , . . - ; , . , - - , , , .

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On a visit to the Scilly Isles     

C.T. Richardson 《Proceedings of the Geologists' Association. Geologists' Association》1871,2(2):37-38

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Chert formation in the Bargate Beds of the Churt Neighbourhood,Surrey     

J.A. Richardson 《Proceedings of the Geologists' Association. Geologists' Association》1947,58(3):161-177

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An overview of SAX99: acoustic measurements   总被引：5，自引：0，他引：5  

Thorsos  E.I. Williams  K.L. Chotiros  N.P. Christoff  J.T. Commander  K.W. Greenlaw  C.F. Holliday  D.V. Jackson  D.R. Lopes  J.L. McGehee  D.E. Piper  J.E. Richardson  M.D. Dajun Tang 《Oceanic Engineering, IEEE Journal of》2001,26(1):4-25

A high-frequency acoustic experiment was performed at a site 2 km from shore on the Florida Panhandle near Fort Walton Beach in water of 18-19 m depth. The goal of the experiment was, for high-frequency acoustic fields (mostly In the 10-300-kHz range), to quantify backscattering from the seafloor sediment, penetration into the sediment, and propagation within the sediment. In addition, spheres and other objects were used to gather data on acoustic detection of buried objects. The high-frequency acoustic interaction with the medium sand sediment was investigated at grazing angles both above and below the critical angle of about 30°. Detailed characterizations of the upper seafloor physical properties were made to aid in quantifying the acoustic interaction with the seafloor. Biological processes within the seabed and the water column were also investigated with the goal of understanding their impact on acoustic properties. This paper summarizes the topics that motivated the experiment, outlines the scope of the measurements done, and presents preliminary acoustics results  相似文献   

The drying up of Britain? A national estimate of changes in seasonal river flows from 11 Regional Climate Model simulations     

Christel Prudhomme  Andy Young  Glenn Watts  Tracey Haxton  Sue Crooks  Jennifer Williamson  Helen Davies  Simon Dadson  Stuart Allen 《水文研究》2012,26(7):1115-1118

As climate change may modify the hydrological cycle significantly, understanding the impact on river flow is important because it affects long‐term water resources planning. Here, we describe a high‐resolution British assessment of changes in river flows in the 2050s under 11 different realisations of HadRM3. In winter, river flows may either increase or decrease, with a wide range of possible decreases in summer flow. These results should encourage adaptation that copes with a broad range of future hydrological conditions. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

A fission-track and (U–Th)/He thermochronometric study of the northern margin of the South China Sea: An example of a complex passive margin     

Yan Yi  Andy Carter  Bin Xia  Lin Ge  Stephanie Brichau  Hu Xiaoqiong 《Tectonophysics》2009,474(3-4):584-594

Zircon fission track (ZFT), apatite fission track (AFT) and (U–Th)/He thermochronometric data are used to reconstruct the Cenozoic exhumation history of the South China continental margin. A south to north sample transect from coast to continental interior yielded ZFT ages between 116.6 ± 4.7 Ma and 87.3 ± 4.0, indicating that by the Late Cretaceous samples were at depths of 5–6 km in the upper crust. Apatite FT ages range between 60.9 ± 3.6 and 37.3 ± 2.3 Ma with mean track lengths between 13.26 ± 0.16 µm and 13.95 ± 0.19 µm whilst AHe ages are marginally younger 47.5 ± 1.9–15.3 ± 0.5 Ma. These results show the sampled rocks resided in the top 1–1.5 km of the crust for most of the Cenozoic. Thermal history modeling of the combined FT and (U–Th)/He datasets reveal a common three stage cooling history which differed systematically in timing inland away from the rifted margin. 1) Initial phase of rapid cooling that youngs to the north, 2) a period of relative (but not perfect) thermal stasis at ~ 70–60 °C which increases in duration from the south to the north; 3) final-stage cooling to surface temperatures that initiated in all samples between 15 and 10 Ma. The timing and pattern of rock uplift and erosion does not fit with conventional passive margin landscape models that require youngest exhumation ages to be concentrated at or close to the rifted margin. The history of South China margin is more complex aided by weakened crust from the active margin period that immediately preceded rifting and opening of the South China Sea. This rheological inheritance created a transition zone of steeply thinned crust that served as a flexural filter disconnecting the northern margin of the South China block and site of active rifting to the south. Consequently whilst the South China margin displays many features of a rifted continental margin its exhumation history does not conform to conventional images of a passive margin.  相似文献   

Cell-Specific Alkaline Phosphatase Expression by Phytoplankton from Winyah Bay,South Carolina,USA     

Melissa L. Ranhofer  Evelyn Lawrenz  James L. Pinckney  Claudia R. Benitez-Nelson  Tammi L. Richardson 《Estuaries and Coasts》2009,32(5):943-957

Alkaline phosphatase expression by phytoplankton from two sites in Winyah Bay, SC, USA was investigated using nutrient-addition bioassays and cell-specific enzyme-labeled fluorescence (ELF) measurements. Our aim was to determine whether expression was group- or species-specific within the phytoplankton community. Diatoms dominated the riverine site in May, the coastal site in July, and both sites in August. Phytoplankton growth was limited by nitrogen (N) availability at the coastal site in May and the riverine site in August, but phosphate limitation was not observed. Alkaline phosphatase expression ranged from ∼30% of cells enumerated to less than 1% and was significantly reduced by inorganic phosphorus (P; 10 μM P) additions. Expression was restricted to species with low abundance, and there were no shifts in community composition consistent with alkaline phosphatase expression. Lack of phosphate limitation at higher-than-Redfield N/P ratios (up to 40:1), however, points to a potentially wider role of dissolved organic phosphorus in nutrition of Winyah Bay phytoplankton than indicated by the ELF assay.  相似文献   

Glacial Landsystems of Southeast Iceland – Quaternary Applications. Quaternary Research Association Field Guide,edited by David J.A. Evans. Quaternary Research Association,London (2018). 311 pp., paperback. ISBN: 0 9077 80288. Price £24.00 (£19.20 for QRA members).     

Andy R. Emery 《Proceedings of the Geologists' Association. Geologists' Association》2019,130(2):259

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The use of selected genotoxicity assays in green-lipped mussels (Perna viridis): a validation study in Hong Kong coastal waters     

Siu SY  Lam PK  Martin M  Caldwell CW  Richardson BJ 《Marine pollution bulletin》2008,57(6-12):479-492

In Hong Kong, discharges of domestic and industrial wastewaters and disposal of contaminated muds into coastal waters have resulted in high levels of persistent organic contaminants in the water column, biota and bottom sediments. Although the acute toxicity of effluents has been tested by government regulators using mortality-based bioassays, the sublethal effects of many of the pollutants, including environmental carcinogens, have not been well studied. The objective of the present work was to examine the efficiency and efficacy of using: (1) DNA strand breaks (comet assay and alkaline agarose gel electrophoresis assay); (2) oxidative DNA damage (levels of 8-hydroxy-2-deoxyguanosine in cellular DNA) and (3) micronuclei (MN) formation as early warning toxicological indicators of potential environmental carcinogen exposure. Green-lipped mussels (Perna viridis) were transplanted to study sites and retrieved after 4, 8, 12, 16 and 30 days. The bioaccumulation of organic pollutants, including the polycyclic aromatic hydrocarbons (PAHs), organochlorine pesticides (OC pesticides) and polychlorinated biphenyls (PCBs) was observed, and compared with biomarker assays. Some significant dose- and time-dependent inductions of the genotoxic biomarkers, including 8-OHdG, DNA strand breaks and micronuclei were observed. In particular, several very strong (r>0.9) and significantly positive relationships were found at all sites during days 0-12. In addition, significant strong relationships between certain organic contaminants (carcinogenic PAHs and 4 common OC pesticides) and micronuclei were detected at the polluted sites, Tsim Sha Tsui and Sai Wan Ho. The results suggest that the use of micronuclei as a biomarker is potentially effective, especially at the more polluted sites. Nonetheless, further research is required to validate their effectiveness under varying field conditions, especially to elucidate responses under lower contaminant loads, interactions between the environmental and physiological factors affecting organisms in differing coastal environments, and changes in biotransformation and DNA repair enzymes in test organisms.  相似文献