Contributions of boron isotopes to understanding the hydrogeochemistry of the coastal detritic aquifer of Castellón Plain,Spain   总被引：1，自引：0，他引：1  

Elena Giménez Forcada  Ignacio Morell Evangelista 《Hydrogeology Journal》2008,16(3):547-557

The Castellón Plain alluvial aquifer, Spain, is intensively exploited to meet the demand for agricultural irrigation and industrial water supply. The geochemistry of its groundwater shows complex salinization in the northern and southern parts of the aquifer, with significant pollution from human origin in the central portion. Boron content and B isotope geochemistry are useful for distinguishing between various sources of pollution and their relative importance in different parts of this aquifer. Boron concentrations in the groundwater vary between 0.01 and 0.85 mg/L. In the more saline groundwaters, found at the northern and southern ends of the study area, the presence of B is linked to inputs from seawater and water with a calcium-magnesium sulphate facies, which feed the aquifer and clearly influence the chemistry of its waters. Evidence of B adsorption processes in some samples is shown by the low B/Cl ratios and the high values of δ¹¹B. In the central portion of the aquifer, the high B/Cl ratios and the strongly negative δ¹¹B are related to pollution of human origin.  相似文献   

New age constraints on emplacement of the Cévenol granitoids, South French Massif Central     

Stéphanie Brichau  Jean-Patrick Respaut  Patrick Monié 《International Journal of Earth Sciences》2008,97(4):725-738

During the development of the Variscan orogeny, large amounts of granitic melt were produced, giving rise to the intrusion of granitoids at different structural levels. Despite numerous studies, ages available from previous work on the Cévennes granites remain largely imprecise. In order to better constrain the age and emplacement mode of these granites, we have combined U–Pb dating on monazites and zircons and ⁴⁰Ar/³⁹Ar dating on biotites with petrological observations, major element chemical analysis and SEM zircon imaging on five samples from the Aigoual–St Guiral–Liron and Mont Lozère granitic massifs. The results revealed that granitic intrusions and cooling in Southern Cévennes occurred in a short time span at ∼306 Ma after the main episode of regional metamorphism. Petrological and chemical data suggest that they result from a mixing between mantle-derived basic magmas (lamprophyres) and lower crust acid magmas. At a regional scale the production of these melts occurred at the end of crustal thickening induced by nappe stacking, at the same time as the late anatectic events recorded further north in the Velay dome and the granulite facies metamorphism recorded in metasedimentary granulite enclaves brought up by Tertiary volcanoes of the Velay area (Bournac).  相似文献   

Provenance of the Bosnian Flysch     

Tamás Mikes  Dominik Christ  Rüdiger Petri  István Dunkl  Dirk Frei  Mária Báldi-Beke  Joachim Reitner  Klaus Wemmer  Hazim Hrvatović  Hilmar von Eynatten 《Swiss Journal of Geoscience》2008,101(1):31-54

Sandwiched between the Adriatic Carbonate Platform and the Dinaride Ophiolite Zone, the Bosnian Flysch forms a c. 3000 m thick, intensely folded stack of Upper Jurassic to Cretaceous mixed carbonate and siliciclastic sediments in the Dinarides. New petrographic, heavy mineral, zircon U/Pb and fission-track data as well as biostratigraphic evidence allow us to reconstruct the palaeogeology of the source areas of the Bosnian Flysch basin in late Mesozoic times. Middle Jurassic intraoceanic subduction of the Neotethys was shortly followed by exhumation of the overriding oceanic plate. Trench sedimentation was controlled by a dual sediment supply from the sub-ophiolitic high-grade metamorphic soles and from the distal continental margin of the Adriatic plate. Following obduction onto Adria, from the Jurassic–Cretaceous transition onwards a vast clastic wedge (Vranduk Formation) was developed in front of the leading edge, fed by continental basement units of Adria that experienced Early Cretaceous synsedimentary cooling, by the overlying ophiolitic thrust sheets and by redeposited elements of coeval Urgonian facies reefs grown on the thrust wedge complex. Following mid-Cretaceous deformation and thermal overprint of the Vranduk Formation, the depozone migrated further towards SW and received increasing amounts of redeposited carbonate detritus released from the Adriatic Carbonate Platform margin (Ugar Formation). Subordinate siliciclastic source components indicate changing source rocks on the upper plate, with ophiolites becoming subordinate. The zone of the continental basement previously affected by the Late Jurassic–Early Cretaceous thermal imprint has been removed; instead, the basement mostly supplied detritus with a wide range of pre-Jurassic cooling ages. However, a c. 80 Ma, largely synsedimentary cooling event is also recorded by the Ugar Formation, that contrasts the predominantly Early Cretaceous cooling of the Adriatic basement and suggests, at least locally, a fast exhumation.  相似文献   

Regional retrograde alteration of sub-greenschist facies chlorite to smectite     

Fernando Nieto  Nicolás Velilla  Donald R. Peacor  Miguel Ortega Huertas 《Contributions to Mineralogy and Petrology》1994,115(3):243-252

Dioctahedral smectite is present as a retrograde alteration product of chlorite in Permian-Triassic red slates of the Malaguide Complex in Sierra de Espuña (Betic Cordillera). Mineral assemblages and textures, illite crystallinity indices, and fluid inclusion data indicate sub-greenschist facies conditions that reached at least 180°C in the higher-grade tectonic unit of the Malaguide Complex, preceding formation of smectite. Smectite, having K as the dominant interlayer cation, occurs ubiquitously intercalated with trioctahedral chlorite as thin packets of layers and as individual layers that commonly change to chlorite along layers. Although some chlorite is typically homogeneous and trioctahedral, much chlorite shows signs of alteration and has compositions corresponding to different degrees of smectite contaimination. The incompatibility of metamorphic grade with the occurrence of smectite, the general association of chlorite and smectite, and the textural relations collectively show that dioctahedral smectite is derived through replacement of trioctahedral chlorite. Such replacement occurs on a regional basis and demonstrates that caution must be used in interpreting the occurrence of smectite in pelites as being due to prograde processes. Alteration of trioctahedral chlorite under oxidizing conditions due to introduction of phreatic water after uplift of the Betic Cordillera is proposed as the cause of formation of smectite.  相似文献   

Phase differences between irradiance and velocity low degree solar acoustic modes revisited     

A. Jiménez 《Solar physics》1994,152(1):319-319

Since 1984, simultaneous observations of irradiance and velocity solar acoustic modes, have been carried out by several authors in order to measure the phase difference between irradiance and velocity modes. Following the earliest observations with stratospheric balloon (Frolich and van Der Raay, 1984), a two ground-based stations (Tenerife and Baja California) were established (Jimenez et al, 1990) obtaining coherence results in the frequency range from 2.5 mHz to 4.3 mHz. These phase differences between irradiance and velocity solar acoustic modes are interpreted in terms of the non-adiabatic behaviour of the solar atmosphere. In 1988 the IPHIR (Frolich et al, 1988) instrument flown on the PHOBOS-2 mission to Mars and measured the solar irradiance during 150 consecutive days. The best velocity observations obtained in Tenerife for this period were compared with IPHIR data to compute the phase differences (Schrijver et al, 1991). The final conclusion is that good agreement is attained between space quadsi-space and ground observations which yield a phase diffenrece of about -125 degrees in the frequency range 2.5 mHz to 4.2 mHz, with a slight increase suggested by the data running up to 4.6 mHz.  相似文献   

Generalized Lyapunov exponents indicators in Hamiltonian dynamics: An application to a double star system     

E. Lohinger  C. Froeschlé  R. Dvorak 《Celestial Mechanics and Dynamical Astronomy》1993,56(1-2):315-322

The Lyapunov characteristic numbers (LCNs) which are defined as the mean value of the distribution of the local variations of the tangent vectors to the flow (=ln _k ⁱ ) (see Froeschlé, 1984) have been found to be sensitive indicators of stochasticity. So we computed the distribution of these local variations and determined the moments of higher order for the integrable and stochastic regions in a binary star system with =0.5.  相似文献   

Chemical abundance behavior of type I planetary nebulae     

M. Faúndez-Abans  J. L. Jiménez O 《Astrophysics and Space Science》1993,207(1):47-53

In this work 13 Planetary Nebulae have been classified as Type I according to Peimbert's criteria (Peimbert, 1978). These objects have been added to a previous sample (Maciel and Faúndez-Abans, 1985) and diagrams of O/H versus N/H, S/H, Ne/H and Ar/H, as well as N/H versus S/H, Ne/H and Ar/H have been drawn. All of them exhibit a tendency for linear correlation; moreover, the behavior of O and N versus Ar and S are very similar, with approximately the same slope. When the excitation class parameter was included in the diagrams, no clear tendency can be discerned, for any class.  相似文献   

The role of bathymetry and directional wave conditions on observed crescentic bar dynamics     

Rinse L. de Swart  Francesca Ribas  Gonzalo Simarro  Jorge Guillén  Daniel Calvete 《地球表面变化过程与地形》2021,46(15):3252-3270

Nearshore sandbars are important features in the surf zone of many beaches because they strongly influence the mean circulation and evolving morphology. Due to variations in wave conditions, sandbars can experience cross-shore migration and vary in shape from alongshore uniform (shore-parallel) to alongshore rhythmic (crescentic). Sandbar dynamics have been studied extensively, but existing observational studies usually do not quantify the processes leading to crescentic bar formation and straightening. This study analyses the dynamics of crescentic bar events at the fetch-limited beach of Castelldefels (northwestern Mediterranean Sea, Spain) using 7.5 years of hourly time-exposure video images and detailed wave conditions. The results show that, despite the generally calm wave conditions, the sandbars were very dynamic in the cross-shore and longshore directions. They often migrated rapidly offshore during storms (up to 70 m in one day) and more slowly onshore during post-storm conditions. Crescentic bars were often present at the study site (48% of the time), but only when the sandbar was at least 10 m from the shoreline. They displayed a large variability in wavelengths (100–700 m), alongshore migration speeds (0–50 m/day) and cross-shore amplitudes (5–20 m). Wavelengths increased for larger bar–shoreline distances and the alongshore migration speeds were strongly correlated with the alongshore component of the radiation stresses. Crescentic patterns typically developed during low–medium energetic waves with limited obliquity ( $\theta \lesssim 20$° at 10 m depth), while bar straightening occurred during medium–high energetic waves with strong oblique angles of incidence ( $\theta \gtrsim 15$°). Overall, this study provides further proof for the important role of wave direction in crescentic bar dynamics and highlights the strong dependence of crescentic bar development on the initial bathymetric configuration.  相似文献   

The use of rogation ceremony records in climatic reconstruction: a case study from Catalonia (Spain)     

Javier Martín-Vide  Mariano Barriendos Vallvé 《Climatic change》1995,30(2):201-221

The use of rogation ceremonies due to environmental causes constitutes an important source of information in paleoclimatic reconstructions. Their specific characteristics and full documental records permit highly reliable series to be reconstructed with daily, monthly, seasonal or annual resolution over periods of several centuries (3–4 centuries in the case of Catalonia). The levels of intensity, reflected in the type of religious ceremony enacted, allows quantification. Comparative analysis is made possible by the similarity of the mechanisms developed in different localities. The use of these series in paleoclimatological studies is a promising line of research, particularly as regards the pro pluvia rogations celebrated in the Mediterranean countries and in South America.  相似文献   

Ozone production due to emissions from vegetation burning     

Günter Helas  Jürgen Lobert  Dieter Scharffe  Luise Schäfer  Johann Goldammer  Jean Baudet  Brou Ahoua  Ayité-Lô Ajavon  Jean-Pierre Lacaux  Robert Delmas  Meinrat O. Andreae 《Journal of Atmospheric Chemistry》1995,22(1-2):163-174

Ozone has been observed in elevated concentrations by satellites over areas previously believed to be background. There is meteorological evidence, that these ozone plumes found over the Atlantic Ocean originate from vegetation fires on the African continent.In a previous study (DECAFE-88), we have investigated ozone and assumed precursor compounds over African tropical forest regions. Our measurements revealed large photosmog layers at altitudes from 1.5 to 4 km. Both chemical and meteorological evidence point to savanna fires up to several thousand km upwind as sources.Here we describe ozone mixing ratios observed over western Africa and compare ozone production ratios from different field measurement campaigns related to vegetation burning. We find that air masses containing photosmog ingredients require several days to develop their oxidation potential, similar to what is known from air polluted by emissions from fossil fuel burning. Finally, we estimate the global ozone production due to vegetation fires and conclude that this source is comparable in strength to the stratospheric input.  相似文献