Characterization and migration of atmospheric REE in soils and surface waters     

Dominique AubertPeter Stille  Anne ProbstFrançois Gauthier-lafaye  Laurent PourcelotMireille Del nero 《Geochimica et cosmochimica acta》2002,66(19):3339-3350

Rainwater and snow collected from three different sites in France (Vosges Mountains, French Alps and Strasbourg) show more or less similar shapes of their REE distribution patterns. Rainwater from Strasbourg is the most REE enriched sample, whereas precipitations from the two mountainous, less polluted catchments are less REE enriched and have concentrations close to seawater. They are all strongly LREE depleted.Different water samples from an Alpine watershed comprising snow, interstitial, puddle and streamwater show similar REE distributions with LREE enrichment (rainwater normalized) but MREE and HREE depletion. In this environment, where water transfer from the soil to the river is very quick due to the low thickness of the soils, it appears that REE in streamwater mainly originate from atmospheric inputs. Different is the behaviour of the REE in the spring- and streamwaters from the Vosges Mountains. These waters of long residence time in the deep soil horizons react with soil and bedrock REE carrying minerals and show especially significant negative Eu anomalies compared to atmospheric inputs. Their Sr and Nd isotopic data suggest that most of the Sr and Nd originate from apatite leaching or dissolution. Soil solutions and soil leachates from the upper soil horizons due to alteration processes strongly depleted in REE carrying minerals, have REE distribution patterns close to those of lichens and throughfall. Throughfall is slightly more enriched especially in light REE than filtered rainwater probably due to leaching of atmospheric particles deposited on the foliage and also to leaf excretion.Data suggest that Sr and Nd isotopes of the soil solutions in the upper soil horizons originate from two different sources: 1) An atmospheric source with fertilizer, dust and seawater components and 2) A source mainly determined by mineral dissolution in the soil. These two different sources are also recognizable in the Sr and Nd isotopic composition of the tree’s throughfall solution. The atmospheric contributions of Sr and Nd to throughfall and soil solution are of 20 to 70 and 20%, respectively. In springwater, however, the atmospheric Sr and REE contribution is not detectable.  相似文献   

Use of Chemotaxonomy To Study the Influence of Benzalkonium Chloride on Bacterial Populations in Biodegradation Testing     

Klaus Kümmerer  Ali Al‐Ahmad  Almut Henninger 《洁净——土壤、空气、水》2002,30(4):171-178

Contradictory results are reported for the behaviour of quaternary ammonium compounds (QACs) in sewage treatment plants (STPs). QACs may sorb onto activated sludge. Only little information is available with respect to effects of QACs against bacteria in STPs. Only 5 to 15 % of bacteria present in sewage sludge can be detected by means of culture dependent microbiological methods. The shift of the bacterial populations due to effects of test compounds have not been studied up to now with culture independent methods. The microbial populations shift was studied in situ using culture independent chemotaxonomy profiling ubiquinones and polyamines. Additionally, toxic effects of QACs against bacteria present in the test vessels of the Zahn‐Wellens test (OECD 302 B) were assessed with a toxicity control in the test. The ubiquinone profiles representing changes in Gram‐negative populations mainly showed that the activated sludge was affected only in test vessels containing benzalkonium chloride. According to chemotaxonomy Acinetobacter or/and some members of Pseudomonas spp. have been selected by benzalkonium chloride after some adaptation period (8 to 12 days).  相似文献   

Sediment yield and storage variations in the Négron River catchment (south western Parisian Basin,France) during the Holocene period     

Jean‐Jacques Macaire  Saïda Bellemlih  Christian Di‐Giovanni  Patrick De Luca  Lionel Visset  Jacques Bernard 《地球表面变化过程与地形》2002,27(9):991-1009

In the Négron River catchment area (162 km²), surface‐sediment stores are composed of periglacial calcareous ‘grèze’ (5 × 10⁶ t) and loess (21 × 10⁶ t), and Holocene alluvium (12·6 × 10⁶ t), peat (0·6 × 10⁶ t) and colluvium (18·5 × 10⁶ t). Seventy‐five per cent of the Holocene sediments is stored along the thalwegs. Present net sediment yield, calculated from solid discharge at the Négron outlet, is low (0·6 t km^?2 a^?1) due to the dominance of carbonate rocks in the catchment. Mean sediment yield during the Holocene period is 7·0 t km^?2 a^?1 from alluvium stores and 7·6 t km^?2 a^?1 from colluvium stores. Thus, the gross sediment yield during the Holocene period is about 18·7 t km^?2 a^?1 and the sediment delivery ratio 3 per cent. The yield considerably varies from one sub‐basin to another (3·9 to 24·5 t km^?2 a^?1) according to lithology: about 25 per cent and 50 per cent of initial stores of periglacial grèze and loess respectively were reworked during the Holocene period. Sediment yield has increased by a factor of 6 in the last 1000 years, due to the development of agriculture. The very high rate of sediment storage on the slope during that period (88 per cent of the yield) can be accounted for by the formation of cultivation steps (‘rideaux’). It is predicted that the current destruction of these steps will result in a sediment wave reaching the valley floors in the coming decades. Subboreal and Subatlantic sediments and pollen assemblages in the Taligny marsh, where one‐third of the alluvium is stored, show the predominant influence of human activity during these periods in the Négron catchment. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

Tectonique transpressive en terre Adélie au Paléoprotérozoı̈que (Est Antarctique)Palaeoproterozoic transpression in Terre Adélie (East Antarctica)     

Anne Pelletier  Denis Gapais  René-Pierre Ménot  Jean-Jacques Peucat 《Comptes Rendus Geoscience》2002,334(7):505-511

The Palaeoproterozoic units of Terre Adélie show two types of structural domains associated with HT–LP metamorphic conditions: domes and NS–N340° striking vertical shear zones. Shear zones reflect dextral transpressive motions. Domes reflect sub-vertical shortening and principal stretching subparallel to shear zones. They could partly result from longitudinal flow coeval with transpression. Deformations are comparable to those described along the eastern and western boundaries of the Archean Gawler Craton (South-East Australia), which underlines the continuity between these two areas before opening of the Austral Ocean. To cite this article: A. Pelletier et al., C. R. Geoscience 334 (2002) 505–511.  相似文献   

Separation of intrinsic absorption and scattering attenuation from Lg coda decay in central France using acoustic radiative transfer theory   总被引：3，自引：0，他引：3  

Céline Lacombe  Michel Campillo  Anne Paul  Ludovic Margerin 《Geophysical Journal International》2003,154(2):417-425

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Seismic evidence for deep low-velocity anomalies in the transition zone beneath West Antarctica   总被引：1，自引：0，他引：1  

Anne Sieminski  Eric Debayle  Jean-Jacques Lévêque 《Earth and Planetary Science Letters》2003,216(4):645-661

We present a three-dimensional (3D) SV-wave velocity model of the upper mantle beneath the Antarctic plate constrained by fundamental and higher mode Rayleigh waves recorded at regional distances. The good agreement between our results and previous surface wave studies in the uppermost 200 km of the mantle confirms that despite strong differences in data processing, modern surface wave tomographic techniques allow to produce consistent velocity models, even at regional scale. At greater depths the higher mode information present in our data set allows us to improve the resolution compared to previous regional surface wave studies in Antarctica that were all restricted to the analysis of the fundamental mode. This paper is therefore mostly devoted to the discussion of the deeper part of the model. Our seismic model displays broad domains of anomalously low seismic velocities in the asthenosphere. Moreover, we show that some of these broad, low-velocity regions can be more deeply rooted. The most remarkable new features of our model are vertical low-velocity structures extending from the asthenosphere down to the transition zone beneath the volcanic region of Marie Byrd Land, West Antarctica and a portion of the Pacific-Antarctic Ridge close to the Balleny Islands hotspot. A deep low-velocity anomaly may also exist beneath the Ross Sea hotspot. These vertical structures cannot be explained by vertical smearing of shallow seismic anomalies and synthetic tests show that they are compatible with a structure narrower than 200 km which would have been horizontally smoothed by the tomographic inversion. These deep low-velocity anomalies may favor the existence of several distinct mantle plumes, instead of a large single one, as the origin of volcanism in and around West Antarctica. These hypothetical deep plumes could feed large regions of low seismic velocities in the asthenosphere.  相似文献   

Asymmetric one‐storey elastic systems with non‐linear viscous and viscoelastic dampers: Simplified analysis and supplemental damping system design     

Wen‐Hsiung Lin  Anil K. Chopra 《地震工程与结构动力学》2003,32(4):579-596

Investigated is the accuracy in estimating the response of asymmetric one‐storey systems with non‐linear viscoelastic (VE) dampers by analysing the corresponding linear viscous system wherein all non‐linear VE dampers are replaced by their energy‐equivalent linear viscous dampers. The response of the corresponding linear viscous system is determined by response history analysis (RHA) and by response spectrum analysis (RSA) extended for non‐classically damped systems. The flexible and stiff edge deformations and plan rotation of the corresponding linear viscous system determined by the extended RSA procedure is shown to be sufficiently accurate for design applications with errors generally between 10 and 20%. Although similar accuracy is also shown for the ‘pseudo‐velocity’ of non‐linear VE dampers, the peak force of the non‐linear VE damper cannot be estimated directly from the peak damper force of the corresponding linear viscous system. A simple correction for damper force is proposed and shown to be accurate (with errors not exceeding 15%). For practical applications, an iterative linear analysis procedure is developed for determining the amplitude‐ and frequency‐dependent supplemental damping properties of the corresponding linear viscous system and for estimating the response of asymmetric one‐storey systems with non‐linear VE dampers from the earthquake design (or response) spectrum. Finally, a procedure is developed for designing non‐linear supplemental damping systems that satisfy given design criteria for a given design spectrum. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

Inelastic displacement ratios for evaluation of existing structures     

Jorge Ruiz‐García  Eduardo Miranda 《地震工程与结构动力学》2003,32(8):1237-1258

Results of a detailed statistical study of constant relative strength inelastic displacement ratios to estimate maximum lateral inelastic displacement demands on existing structures from maximum lateral elastic displacement demands are presented. These ratios were computed for single‐degree‐of‐freedom systems with different levels of lateral strength normalized to the strength required to remain elastic when subjected to a relatively large ensemble of recorded earthquake ground motions. Three groups of soil conditions with shear wave velocities higher than 180m/s are considered. The influence of period of vibration, level of lateral yielding strength, site conditions, earthquake magnitude, distance to the source, and strain‐hardening ratio are evaluated and discussed. Mean inelastic displacement ratios and those associated with various percentiles are presented. A special emphasis is given to the dispersion of these ratios. It is concluded that distance to the source has a negligible influence on constant relative strength inelastic displacement ratios. However, for periods smaller than 1s earthquake magnitude and soil conditions have a moderate influence on these ratios. Strain hardening decreases maximum inelastic displacement at a fairly constant rate depending on the level of relative strength for periods of vibration longer than about 1.0s while it decreases maximum inelastic displacement non‐linearly as the period of vibration shortens and as the relative‐strength ratio increases for periods of vibration shorter than 1.0s. Finally, results from non‐linear regression analyses are presented that provide a simplified expression to be used to approximate mean inelastic displacement ratios during the evaluation of existing structures built on firm sites. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

Landslide susceptibility analysis using GIS and artificial neural network     

Saro Lee  Joo‐Hyung Ryu  Kyungduck Min  Joong‐Sun Won 《地球表面变化过程与地形》2003,28(12):1361-1376

The purpose of this study is to develop landslide susceptibility analysis techniques using an arti?cial neural network and to apply the newly developed techniques to the study area of Yongin in Korea. Landslide locations were identi?ed in the study area from interpretation of aerial photographs, ?eld survey data, and a spatial database of the topography, soil type and timber cover. The landslide‐related factors (slope, curvature, soil texture, soil drainage, soil effective thickness, timber age, and timber diameter) were extracted from the spatial database. Using those factors, landslide susceptibility was analysed by arti?cial neural network methods. The landslide susceptibility index was calculated by the back‐propagation method, which is a type of arti?cial neural network method, and the susceptibility map was made with a geographic information system (GIS) program. The results of the landslide susceptibility analysis were veri?ed using landslide location data. The validation results showed satisfactory agreement between the susceptibility map and the existing data on landslide location. A GIS was used to ef?ciently analyse the vast amount of data, and an arti?cial neural network to be an effective tool to maintain precision and accuracy. The results can be used to reduce hazards associated with landslides and to plan land use and construction. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

A procedure for evaluating seismic energy demand of framed structures     

Chung‐Che Chou  Chia‐Ming Uang 《地震工程与结构动力学》2003,32(2):229-244

Energy serves as an alternative index to response quantities like force or displacement to include the duration‐related seismic damage effect. A procedure to evaluate the absorbed energy in a multistorey frame from energy spectra was developed. For low‐ to medium‐rise frames, it required a static pushover analysis of the structure to determine the modal yield force and ductility factor of an equivalent single‐degree‐of‐freedom system for the first two modes. The energy spectra were then used to determine the energy contribution of each mode. A procedure was also developed to distribute the energy along the frame height based on energy shapes. This study showed that the second‐mode response in some cases needs to be considered to reflect the energy (or damage) concentration in the upper floors. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献