Stratospheric response to chemical perturbations     

Guy Brasseur  Anne De Rudder  Christian Tricot 《Journal of Atmospheric Chemistry》1985,3(2):261-288

The paper presents a coupled chemical-radiative one-dimensional model which is used to assess the steady-state and time-dependent composition and temperature changes in relation to the release in the atmosphere of chemicals such as CO₂, N₂O, CH₄, NO _x and chlorofluorocarbons.The model indicates that a doubling in CO₂ leads to an increase in temperature of 12.7 K near the stratopause and to an increase in total ozone of 3.3% with a local enhancement of 17% at 40 km altitude. Additional release of N₂O leads to an ozone reduction in the middle stratosphere. The reduction in the ozone column is predicted to be equal to 8.8% when the amount of N₂O is doubled. The chemical effect of CH₄ on ozone is particularly important in the troposphere. A doubling in the mixing ratio of this gas enhances the O₃ concentration by 11% at 5 km. The predicted increase of the ozone column is equal to 1.4%. A constant emission of CFCl₃ (230 kT/yr) and CF₂Cl₂ (300 kT/yr) leads to a steady-state reduction in the ozone column of 1.9% compared to the present-day situation. The effect of some uncertainties in the chemical scheme as well as the impact of a high chlorine perturbation are briefly discussed.Finally the results of a time dependent calculation assuming a realistic scenario for the emission of chemical species are presented and analyzed.  相似文献   

Observations on the distribution of PCBs in the deepwater sediments of the Gulf of Maine     

Peter F. Larsen  Donald F. Gadbois  Anne C. Johnson 《Marine pollution bulletin》1985,16(11):439-442

Nineteen stations were occupied in the deeper regions of the Gulf of Maine to determine the geographic extent of the PCB contamination reported from recent inshore surveys. Detectable levels of PCBs were found in all 94 samples in concentrations ranging from trace amounts to 0.13 ppm (dry wt). The complex topography of the Gulf of Maine required the subdivision of the Gulf into major basin regions for proper data analysis and interpretation. Two of the three major basins, Jordan and Georges, appeared to be depositional areas for PCBs. No significant relationships existed between PCB concentration and either TOC or depth in Wilkinson Basin, however, which is located in the western Gulf of Maine closer to presumed sources.  相似文献   

The transformation of amphibolite facies gneiss to charnockite in southern Karnataka and northern Tamil Nadu,India   总被引：4，自引：0，他引：4  

A. S. Janardhan  R. C. Newton  E. C. Hansen 《Contributions to Mineralogy and Petrology》1982,79(2):130-149

Amphibolite facies metamorphic grade gives way southward to the granulite grade in southern Karnataka, as acid gneisses develop charnockite patches and streaks and basic enclaves develop pyroxenes. Petrologic investigations in the transitional zone south of Mysore have established the following points:

1. The transition is prograde. Amphibole-bearing gneisses intimately associated with charnockite at Kabbal and several similar localities are not retrogressive after charnockite, as proved by patchy obliteration of their foliation by transgressive, very coarse-grained charnockite, high fluorine content of biotite and amphibole in gneisses, and high large-ion lithophile element contents in gneisses and charnockites. These features are in contrast to very low fluorine in retrogressive amphiboles and biotites, very low large-ion lithophile element contents, and zonal bleaching of charnockite, in clearly retrogressive areas, as at Bhavani Sagar, Tamil Nadu.
2. Metamorphic temperatures in the transitional areas were 700°–800° C, pressures were 5–7 kbar, and H₂O pressures were 0.1–0.3 times total pressures, based on thermodynamic calculations using mineral analyses. Dense CO₂-rich fluid inclusions in the Kabbal rocks confirm the low H₂O pressures at the first appearance of orthopyroxene. Farther to the south, in the Nilgiri Hills and adjacent granulite massif areas, peak metamorphic temperatures were 800°–900° C, pressures were 7–9 kbar, and water pressures were very low, so that primary biotites and amphiboles (those with high F contents) are rare.
3. The incipient granulite-grade metamorphism of the transitional areas was introduced by a wave of anatexis and K-metasomatism. This process was arrested by drying out under heavy CO₂ influx. Charnockites so formed are hybrids of anatectic granite and metabasite, of metabasite and immediately adjacent gneiss, or are virtually isochemical with pre-existing gneiss despite gross recrystallization to granulite mineralogy. These features show that partial melting and metasomatism are attendant, rather than causative, in charnockite development. Copious CO₂ from a deep-crustal or mantle source pushed ahead of it a wave of more aqueous solutions which promoted anatexis. Granulite metamorphism of both neosome and paleosome followed. The process is very similar to that deduced for the Madras granulites by Weaver (1980). The massif charnockites, for the most part extremely depleted in lithophile minor elements, show many evidences of having gone through the same process.

A major problem remaining to be solved is the origin of the large amount of CO₂ needed to charnockitize significant portions of the crust. The most important possibilities include CO₂ from carbonate minerals in a mantle “hot spot” or diapir, from emanations from a crystallizing basaltic underplate, or from shelf sediments trapped at the continent-continent interface in continental overthrusting. Ancient granulite massifs may be such suture zones of continental convergence.  相似文献   

Pyrite and oxidized iron mineral phases formed from pyrite oxidation in salt marsh and estuarine sediments     

George W. Luther  Anne Giblin  Robert W. Howarth  Robert A. Ryans 《Geochimica et cosmochimica acta》1982,46(12):2665-2669

We used scanning electron microscopy and energy dispersive X-ray analysis to examine sediments from vegetated portions of three salt marshes, the Great Sippewissett Marsh (Cape Cod, MA), Sapelo Island (Georgia), and the Hackensack Meadowlands (N.J.), and from the sediments of an estuary, Newark Bay (N.J.). Pyrite particles were abundant in sediments from all sites. Both fine grained pyrite crystals and framboids were found. Single, fine grained crystals (diameter = 0.2 to 2.0 micrometers) predominated in all samples, strong evidence for rapid formation of pyrite.We also found both microcrystalline and framboidal iron-oxyhydroxide phases in many of the sediment samples. This is evidence of pyrite oxidation within the sediments and suggests that iron is conserved in salt marshes even as pyrite is oxidized. The thermodynamic stability of iron phases in marsh sediments, and recent pyrite oxidation studies in coal, suggest goethite as the crystalline iron-oxyhydroxide phase present. In addition, we sometimes found a red amorphous coating on grass roots from the Great Sippewissett and Sapelo Island marshes. This coating is likely a form of hydrated iron (III) oxide.  相似文献   

Observational study of terrestrial eigenvibrations     

Roger A. Hansen 《Physics of the Earth and Planetary Interiors》1982,28(1):27-69

A comprehensive analysis has been made of analog and digital recordings of eigenvibration ground motion obtained following four great earthquakes; August 1976 (Philippines), August 1977 (Indonesia), September 1979 (West Irian), and December 1979 (Colombia). The time series (ranging in length from ～28 to ～140 h) are assumed to be linear combinations of damped harmonics in the presence of noise. Tables are calculated from values of the four parameters: Θ, used in describing eigenvibrations, period of oscillation, amplitude, damping factor Q, and phase together with their statistical uncertainties (53 spheroidal modes, ${}_0\text{S}{}_4\text{to}{}_0\text{S}{}_{48}$, and 13 torsional modes, ${}_0\text{T}{}_8\text{to}{}_0\text{T}{}_{45}$). The estimation procedures are by the methods of complex demodulation and non-linear regression that specifically incorporate into the basic model the decaying aspect of the oscillations. These methods, extended to simultaneous estimations of groups of modes, help to eliminate measurement error and measurement bias from estimations of Θ. The result is that overtone modes very near in frequency to fundamental modes can, under certain conditions, be resolved through a non-linear regression technique, although parameter uncertainties are underestimated in general.Of the time series analyzed, 17 were from a northern California regional network of ultra-long period seismographs at Berkeley (three components), Jamestown (vertical component), and Whiskeytown (vertical component) following the four listed earthquakes. The other 7 time series were recorded digitally by the worldwide IDA network following the 1977 Indonesian earthquake. Weighted regional and worldwide averages were made for period and Q of each eigenvibration mode.From the theoretical viewpoint, comparisons of measured period, Q, amplitude, and phase for all modes analyzed led to five conclusions. First, there are no detectable systematic shifts in period, Q, or phase of eigenvibrations within a region whose dimensions are less than a wavelength. Second, though not conclusive, there may be slight systematic shifts in period (<0.65 s) and relative amplitudes within the California regional network due to different source positions and mechanisms. Differences in Q values are not statistically significant. Third, even though differences in period obtained worldwide were as great as 1.33 s (≈0.33%), differences between Q values (as great as 20%) for the same mode were not significant. The conclusion is that the damping characteristics of singlet eigenfunctions are not observed to be significantly different. Fourth, the assumption that a multiplet ${}_{\mathrm{n}}\text{S}{}_{\mathrm{l}}$ behaves as a single oscillation is valid from at least ${}_0\text{S}{}_7$ through ${}_0\text{S}{}_{30}$. Fifth, no systematic pattern emerged for the shift of eigenperiod as a function of order / or posit on the Earth.  相似文献   

Arrested charnockite formation in southern India and Sri Lanka   总被引：7，自引：3，他引：7  

E. C. Hansen  A. S. Janardhan  R. C. Newton  W. K. B. N. Prame  G. R. Ravindra Kumar 《Contributions to Mineralogy and Petrology》1987,96(2):225-244

Arrested prograde charnockite formation in quartzofeldspathic gneisses is widespread in the high-grade terrains of southern India and Sri Lanka. Two major kinds of orthopyroxene-producing reactions are recognized. Breakdown of calcic amphibole by reaction with biotite and quartz in tonalitic/granitic gray gneiss produced the regional orthopyroxene isograd, manifest in charnockitic mottling and veining of mixed-facies exposures, as at Kabbal, Karnataka, and in the Kurunegala District of the Sri Lanka Central Highlands. Chemical and modal analyses of carefully chosen immediately-adjacent amphibole gneiss and charnockite pairs show that the orthopyroxene is produced by an open system reaction involving slight losses of CaO, MgO and FeO and gains of SiO₂ and Na₂O. Rb and Y are depleted in the charnockite. Another kind of charnockitization is found in paragneisses throughout the southern high-grade area, and involves the reaction of biotite and quartz±garnet to produce orthopyroxene and K-feldspar. Although charnockite formation along shears and other deformation zones at such localities as Ponmudi, Kerala is highly reminiscent of Kabbal, close pair analyses are not as suggestive of open-system behavior. This type of charnockite formation is found in granulite facies areas where no prograde amphibole-bearing gneisses exist and connotes a higher-grade reaction than that of the orthopyroxene isograd. Metamorphic conditions of both Kabbaltype and Ponmudi-type localities were 700°–800° C and 5–6 kbar. Lower P(H₂O) in the Ponmudi-type metamorphism was probably the definitive factor.CO₂-rich fluid inclusions in quartz from the Kabbaltype localities support the concept that this type of charnockite formation was driven by influx of CO₂ from some deep-seated source. The open-system behavior and high oxidation states of the metamorphism are in accord with the CO₂-streaming hypothesis. CO₂-rich inclusions in graphitebearing charnockites of the Ponmudi type, however, commonly have low densities and compositions not predictable by vapor-mineral equilibrium calculations. These inclusions may have suffered post-metamorphic H₂ leakage or some systematic contamination.Neither the close-pair analyses nor the fluid inclusions strongly suggest an influx of CO₂ drove charnockite formation of the Ponmudi type. The possibility remains that orthopyroxene and CO₂-rich fluids were produced by reaction of biotite with graphite without intervention of fluids of external origin. Further evidence, such as oxygen isotopes, is necessary to test the CO₂-streaming hypothesis for the Ponmudi-type localities.  相似文献   

Textural evolution of synthetic anhydrite-halite mylonites     

John V. Ross  Stephen J. Bauer  Francis D. Hansen   《Tectonophysics》1987,140(2-4):307-326

The rheology and textural evolution of mylonites for both crustal and mantle rocks are generally poorly understood. Stress and strain partitioning between shear zones and wall-rock, foliation development, flow mechanisms, and constitutive relations are little known. To address these problems, we have begun an experimental study in which anhydrite and halite aggregates are deformed in simple shear. Homogeneous mixes at intervals of 10 vol.% of anhydrite and halite powders of 90 to 180-μ m grain-size comprise the 1-mm-thick zone between the 35 °-precut surfaces in 2 by 4 cm right-circular cylinders of anhydrite. All specimens are confined under 200 MPa (P_c) and tested at 300 °C (T), producing an aggregate of near-zero porosity. All specimens are shortened at an axial displacement rate of 5×l0⁻⁶ cm/s to shear strains of about 2.0. Most stress-strain curves have a similar form. They are characterized by an initial linear response that is followed by a work-hardening region that leads to a plateau of constant stress whilst strain continues to accumulate. This apparent steady-state behavior is followed by a drop in stress to a second apparent steady-state stress. The strain at this stress drop and the magnitude of the drop increase with increasing anhydrite content. The second (lower) steady-state stress for all mixes approaches that of sheared pure halite. Optical examination of the fabrics shows that straining under the initial apparent steady-state is accommodated by both mineral phases. A foliation evolves as defined by mineral segregation and grain elongation of halite at 15 ° to 30 ° to the shear-zone walls. Anhydrite grains rotate until their (001) 010 slip system parallels the foliation. The anhydrite also exhibits twin lamellae, kinks and microfractures. Following the stress drop, rheologic behavior is dominated by dynamic recovery in halite, the recrystallized grain size increasing, consistent with the lower stress level.  相似文献   

A quantitative method for estimating Pasquill stability class from windspeed and sensible heat flux density   总被引：1，自引：0，他引：1  

Robert A. Sutherland  Frank V. Hansen  Walter D. Bach 《Boundary-Layer Meteorology》1986,37(4):357-369

A simple exponential expression, based upon a form of the Kazanski-Monin stability parameter, modified to account explicitly for effects of surface roughness, and semi-empirically derived from both qualitative and quantitative observations, is presented that relates windspeed and sensible heat flux density to Pasquill stability class. The method, though simple in mathematical form, gives results consistent with physical intuition and reproduces, quantitatively, the essential features of previously published nomograms with an added capability for treating all stability classes and any surface roughness from 0.10 to 100 cm. For the stable classes, a new expression for the wind profile stability factor, predicted by similarity theory, is introduced that produces results more consistent than the more common linear form.  相似文献   

OCS,H2S,and CS2 fluxes from a salt water marsh     

Mary Anne Carroll  Leroy E. Heidt  Ralph J. Cicerone  Ronald G. Prinn 《Journal of Atmospheric Chemistry》1986,4(3):375-395

The diurnal-to-monthly behavior of the fluxes of OCS, H₂S, and CS₂ from a mixed-Spartina grass-covered site in a Wallops Island salt water marsh was determined through a series of experiments in August and September, 1982. Absolute flux values were determined for OCS and H₂S, while only relative values were determined for CS₂. The rates of emission of OCS and H₂S were observed to vary diurnally and to be strongly influenced by tides. The time-averaged flux values show that such mixed-Spartina stands are insignificant ( 1%) global sources of H₂S or CS₂ and insignificant contributors to the global OCS cycle (< 1%). These results demonstrate that some marsh regions play a minor role in the global sulfur budget and, consequently, that the inclusion of such areas in extrapolations of measurements of more productive regions could lead to an overestimate of the role of salt water marshes in the global sulfur budget.  相似文献   

Single-crystal absorption and reflection infrared spectroscopy of forsterite and fayalite     

Anne M. Hofmeister 《Physics and Chemistry of Minerals》1987,14(6):499-513

Polarized single-crystal absorption and reflection spectra of fundamental modes in both the mid- and far-infrared are presented for microscopic crystals of forsterite and fayalite. All modes predicted by symmetry were observed for forsterite, but two B_3u modes were not observed for fayalite. Consideration of previously determined frequency shifts for isotopically and chemically substituted olivines, along with symmetry analysis, produced a complete set of band assignments satisfying all constraints for forsterite. A plausible assingment was derived for fayalite by analogy. The frequency shifts from forsterite to fayalite are consistently small for bands assigned to SiO₄ stretching and bending, moderate for rotations, and large for translations of M-site ions, suggesting that in olivine, SiO₄ groups vibrate separately from the lattice. Allocating the bending and external modes among multiple continua in Kieffer's (1979c) model considerably improves prediction of quasiharmonic heat capacityC _v and entropy for forsterite (～1% discrepancy from 200–1000 K). The experimental entropy of fayalite is closely accounted for (1.8 to 0.1%) by summing lattice, electronic (from Burns' (1985) optical band assignment), and constant magnetic contributions above 200 K.S _magnetic determined from the difference of the experimental and model lattice entropies shows inflection points at the two magnetic transition temperatures (23 and 66 K) and indicates that complete spin disorder is not achieved below 680 K.  相似文献