Ph isotopic analyses are reported for 119 samples of late Archaean (ca. 3000-2800 Myr) calc alkaline orthogneisses and associated anorthosites from southern West Greenland. Over most of the area. whole rock isotope systematics indicate derivation of the magmatic precursors of the gneisses and anorthosites from a source region with a typically mantle-type ratio (μ1 value of 7.5) at. or shortly before, ca. 3000-2800 Myr ago. In contrast, in the Godthaabsfjord region, late Archaean Nûk gneisses and associated anorthosites were emplaced into or through early Archaean (ca. 3700 Myr) Amîtsoq gneisses, and crystallised with variable proportions of two isotopically distinct types of Pb which commenced their respective crustal developments at ca. 3000-2800 Myr and at ca. 3700 Myr ago. Isotopic and other geochemical constraints demonstrate that Nûk gneisses and their temporal equivalents were not produced by reworking or melting of Amîtsoq gneisses. Mixing of early and late Archaean Pb results from contamination of the magmatic precursors of Nûk gneisses and anorthosites (characterised by mantle-type Pb at time of emplacement) with ancient, unradiogenic Pb derived from ca. 3700 Myr-old Amîtsoq-type continental crust invaded by the Nûk magmas. The contaminant is considered to be a trace-element enriched fluid phase released from dehydrating older continental crust during progressive burial and heating by emplacement of calc alkaline magmas in the late Archaean ‘accretion differentiation superevent’. This was followed by mixing of the released fluids with younger Nûk magmas.Pb isotopic compositions of late Archaean gneisses and anorthosites outside the Godthaabsfjord region provide no evidence for the presence of early Archaean Amîtsoq-type continental crust in southern West Greenland in areas more than a few tens of km outside the known outcrop of Amîtsoq gneisses. We suggest that early Archaean crust does not exist at depth in late Archaean areas with undisturbed Pb-isotope systematics, either in Greenland or elsewhere in the North Atlantic craton.Pb-isotope evidence for crust magma interaction, involving selective extraction of certain trace elements by a fluid phase from wall rock and subsequent mixing between magma and contaminant fluid, provides a powerful tool for detection, sub-surface ‘mapping’, and geochronological and geochemical characterisation of deep, ancient continental crust. 相似文献
The SOFIA (Surface of the Ocean: Flux and Interaction with the Atmosphere) experiment, included in the ASTEX (Atlantic Stratocumulus Transition EXperiment) field program, was conducted in June 1992 in the Azores region in order to investigate air-sea exchanges, as well as the structure of the atmospheric boundary layer and its capping low-level cloud cover. We present an analysis of the vertical structure of the marine atmospheric boundary layer (MABL), and especially of its turbulence characteristics, deduced from the aircraft missions performed during SOFIA. The meteorological situations were characteristic of a temperate latitude under anticyclonic conditions, i.e., with weak to moderate winds, weak surface sensible heat flux, and broken capping low-altitude cloud cover topped by a strong trade inversion. We show that the mixed layer, driven by the surface fluxes, is decoupled from the above cloud layer. Although weak, the surface buoyancy flux, and the convective velocity scale deduced from it, are relevant for scaling the turbulence moments. The mixed layer then follows the behavior of a continental convective boundary layer, with the exception of the entrainment process, which is weak in the SOFIA data. These results are confirmed by conditional sampling analysis, which shows that the major turbulence source lies in the buoyant moist updrafts at the surface. 相似文献
Key trends in labour demand and supply in the 1980s, and their interactions, had uneven impacts on different population sub-groups and areas in Britain. As the structure of employment shifted from manufacturing to services, and there was a growth in high level non-manual occupations at the expense of less skilled manual jobs, there was increasing concern that the ‘losers’ from these processes of economic and social change would become increasingly ‘isolated’—in socioeconomic and spatial terms. This paper traces the changing contours of the geography of unemployment and inactivity in Great Britain between 1981 and 1991, at the regional and local scales, using a variety of indicators of spatial distribution and segregation. While on some measures there is evidence that unemployment became more widespread, there is evidence that the extent and intensity of non-employment, and the segregation of those without jobs, were exacerbated over the decade. 相似文献
A wide variety of rock types are present in the O'Leary Peak and Strawberry Crater volcanics of the Pliocene to Recent San Francisco Volcanic Field (SFVF), AZ. The O'Leary Peak flows range from andesite to rhyolite (56–72 wt % SiO2) and the Strawberry Crater flows range from basalt to dacite (49–64 wt % SiO2). Our interpretation of the chemical data is that both magma mixing and crustal melting are important in the genesis of the intermediate composition lavas of both suites. Observed chemical variations in major and trace elements can be modeled as binary mixtures between a crustal melt similar to the O'Leary dome rhyolite and two different mafic end-members. The mafic end-member of the Strawberry suite may be a primary mantle-derived melt. Similar basalts have also been erupted from many other vents in the SFVF. In the O'Leary Peak suite, the mafic end-member is an evolved (low Mg/(Mg+ Fe)) basalt that is chemically distinct from the Strawberry Crater and other vent basalts as it is richer in total Fe, TiO2, Al2O3, MnO, Na2O, K2O, and Zr and poorer in MgO, CaO, P2O5, Ni, Sc, Cr, and V. The derivative basalt probably results from fractional crystallization of the more primitive, vent basalt type of magma. This evolved basalt occurs as xenolithic (but originally magmatic) inclusions in the O'Leary domes and andesite porphyry flow. The most mafic xenolith may represent melt that mixed with the O'Leary dome rhyolite resulting in andesite preserved as other xenoliths, a pyroclastic unit (Qoap), porphyry flow (Qoaf) and dacite (Darton Dome) magmas. Thermal constraints on the capacity of a melt to assimilate (and melt) a volume of solid material require that melt mixing and not assimilation has produced the observed intermediate lavas at both Strawberry Crater and O'Leary Peak. Textures, petrography, and mineral chemistry support the magma mixing model. Some of the inclusions have quenched rims where in contact with the host. The intermediate rocks, including the andesite xenoliths, contain xenocrysts of quartz, olivine and oligoclase, together with reversely zoned plagioclase and pyroxene phenocrysts. The abundance of intermediate volcanic rocks in the SFVF, as observed in detail at O'Leary Peak and Strawberry Crater, is due in part to crustal recycling, the result of basalt-driven crustal melting and the subsequent mixing of the silicic melts with basalts and derivative magmas. 相似文献
The stratigraphic and regional variation of petrographic and chemical properties within the coals of the Upper Carboniferous Tradewater Formation and surrounding rocks in the Western Kentucky coal field were analyzed with the intent of constructing a depositional model for the occurrence of these low sulfur coals. Cores were megascopically described, and coal samples were analyzed for maceral, ash, and sulfur contents. These data were then analyzed to determine regional variation within the study area, as well as vertical variation within single coal columns.Sedimentological data from core logs indicate that the majority of the Tradewater rocks consist of irregularly distributed, coarsening-upward, fine-grained detrital material that was deposited in shallow bodies of water. Fossiliferous shales and limestones indicate a marine influence. Less common coarse-grained, fining-upward sequences appear to represent deposits of meandering or braided channels.Like the detrital rocks, the coal seams are irregularly distributed and exhibit substantial variation in petrographic and chemical properties which reflect changes in the Eh and pH of the coal swamp waters. These individual swamps were relatively limited in extent and probably occupied a low-lying coastal area. The relatively high vitrinite content of most of the coals suggests a reasonable degree of preservation of decaying plant materials. The study of benched samples from surface mines suggests a distinct dichotomy between swamps that were in more or less continuous contact with sulfate-rich marine or brackish water and those in which peat accumulated in a dominantly fresh-water setting. Most of the latter show a pattern of upward increasing sulfur content and decreasing vitrinite content, indicating increasing influences of oxygenated water that would encourage microbial action and which would degrade the peat and increase the tendency for sulfide precipitation. The high sulfur coals do not display this variability. The high rates of lateral variability encountered in the data suggest that future study should concentrate on smaller areas where variation can be completely documented. 相似文献
The Bindal Batholith is the largest granitoid batholith in the Scandinavian Caledonides, emplaced prior to or during the Scandian collision in a complex scenario of Ordovician to Middle Silurian nappe assembly. The Bindal Batholith ranges in compositon from mafic gabbro to leucogranite, but granites and granodiorites are by far the most abundant rock types.
Pb---Pb, Sm---Nd and Rb---Sr isotopic results from plutons of the batholith constrain the origin of the Bindal Batholith magmas. The isotope results suggest the presence of several source reservoirs, giving rise to the granitoid magmas. Both a source relatively depleted in U, Th and Rb and enriched in Sm, a source enriched in U and Rb and depleted in Sm, a source enriched in Th and Rb, but depleted in Sm, and, finally, a source enriched in Th and Sm, but depleted in Rb, is indicated by the initial compositions of the radiogenic isotope ratios. It is suggested that the depleted source reservoirs were contemporaneous depleted mantle and mantle derived rocks in the nappe sequences, that the enriched source reservoir was sediments derived from Proterozoic upper crust of Baltic Shield affinity and that the Th-enriched source reservoir was various Proterozoic rocks, in a lower crustal position, of either Baltic or Laurentian affinity. 相似文献
Temperate shelf carbonates form in cool marine waters and have skeletal and mineralogical compositions which are different from their tropical counterparts. They commonly lack non-skeletal grains and are often composed of low- and high-magnesium calcite with subordinate aragonite. Many of the aragonitic components found in tropical carbonates, such as corals, ooids, blue-green algae and lime mud, are absent.
Temperate shelf carbonates undergo diagenesis in marine waters with lower carbonate saturation than do tropical carbonates, and are exposed to cool climates with moderate to low rainfall. Marine cementation is rare because of low carbonate saturations in the surrounding waters. However, aragonite and high-magnesium calcite cements have been reported forming under specialized conditions associated with biogenic precipitation, submarine methane and sulphate-reducing bacteria, and more commonly in the intertidal environment where evaporation has increased carbonate concentrations.
In Pleistocene and Tertiary temperate shelf carbonates from southeastern Australia, evidence of marine diagenesis is rare to absent. Diagenetic stabilization of aragonite and high-magnesium calcite has taken from 80,000 y to 1 My, or longer, during subaerial exposure. This is slower than rates reported from tropical climates. A general lack of aragonite in some facies within these temperate carbonates leads to a lack of secondary porosity and only sparse low-magnesium calcite cement, even after prolonged fresh-water diagenesis. However, with lengthy exposure and under the right climatic conditions, karstic solution and calcrete precipitation can occur.
In sequences containing siliciclastic clays, pyrite and glauconite, abundant iron is present in interstitial waters leading to the precipitation of ferroan calcite cements in the phreatic and shallow burial environments, and to the substitution of iron for magnesium in stabilizing high-magnesium calcite skeletal material.
A unique void-filling, micritic internal sediment occurs in discrete layers in many of the Tertiary temperate shelf carbonate sequences in southeastern Australia. This internal sediment is localized as a pore-filling material above permeability barriers such as fine-grained sediments or volcanics, and above paleo-water tables which formed during periods of subaerial exposure. It is a feature of the vadose zone and lithifies to form a dense micritic low-magnesium calcite cement with characteristic pink/brown coloration, often associated with erosion surfaces and nodule beds.
Dolomite is uncommon in the southeastern Australian temperate shelf carbonates. It forms associated with preferential fluid pathways or mixing zones. Ferroan dolomite forms in siliciclastic clay-rich carbonates in the shallow burial environment. The ubiquitous fine, evaporite-related dolomite so common in tropical carbonates is absent. 相似文献
Abstract. Along the Atlantic coast of the United States, the mud crab Dyspanopeus sayi frequently occurs in crevices and depressions within aggregated calcareous tubes (termed “heads”) of the serpulid polychaete Filograna implexa. In New Jersey, U.S.A., waters, crab number was significantly correlated with the logarithm of worm tube colony volume. Laboratory experiments suggested that crabs compete for shelter within worm colonies. Additional laboratory experiments indicated that colony occupancy greatly decreased the risk of predation by blue crabs (Callinectes sapidus), and field tethering experiments also demonstrated that colony occupancy significantly decreased predation risk. Thus, the consequence of holding space on worm tube heads is a greatly increased probability of survival. 相似文献
Organic matter from the cap dolostones overlying the Marinoan‐age glacigenic diamictites of the Araras Group, Amazon craton, has been studied to reconstruct the post‐glacial ecosystem. Molecular fossils indicate that the post‐Marinoan ecosystem was marked by an apparent decline in marine algal diversity. The proliferation of red algae may be explained by environmental changes, such as a massive nutrient input accompanying continental weathering after the ice thaw and a dimer light penetrating sea water due to the drowning of the platform. In addition, the presence of green sulphur bacteria indicates that sea water was stratified with an anoxic (possibly euxinic, i.e. sulphidic) layer at the water–sediment interface. Sulphur cycling probably occurred at the redox boundary as suggested by the recognition of active sulphate reduction. This observation supports a microbially induced model for the formation of the cap dolostones. 相似文献
