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81.
The use of sequential measurements of hemolymph cholinesterase activities as a non-invasive biomarker of seasonal organophosphate/carbamate exposure was investigated for the tropical scallop, Euvola (Pecten) ziczac. Overall activities of both acetylcholinesterase and butyrylcholinesterase were relatively high compared to studies with bivalve tissues. Acute in vivo experiments showed inhibition of hemolymph acetylcholinesterase activity at concentrations of the organophosphate insecticide chlorpyrifos of 0.1, 1 and 10 ng l(-1). Monthly sampling of hemolymph from scallops at two sites in Bermuda over a 15 month period showed seasonal acetylcholinesterase and butyrylcholinesterase inhibition. Direct and indirect evidence suggests that this inhibition did not relate to biochemical or physiological changes associated with gonad maturation and spawning, but rather reflected diffuse contamination of the marine environment by cholinesterase inhibitors or increased bioavailability of such inhibitors at these times. Repetitive sampling of scallop hemolymph for cholinesterase activities represents a rapid, sensitive and non-invasive method for assessing seasonal, sublethal pesticide exposure in these commercially important bivalves and suggests a wider use in marine pollution monitoring.  相似文献   
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Pyridine-2,6-bis(monothiocarboxylate) (pdtc), a metabolic product of microorganisms, including Pseudomonas putida and Pseudomonas stutzeri was investigated for its ability of dissolve Fe(III)(hydr)oxides at pH 7.5. Concentration dependent dissolution of ferrihydrite under anaerobic environment showed saturation of the dissolution rate at the higher concentration of pdtc. The surface controlled ferrihydrite dissolution rate was determined to be 1.2 × 10−6 mol m−2 h−1. Anaerobic dissolution of ferrihydrite by pyridine-2,6-dicarboxylic acid or dipicolinic acid (dpa), a hydrolysis product of pdtc, was investigated to study the mechanism(s) involved in the pdtc facilitated ferrihydrite dissolution. These studies suggest that pdtc dissolved ferrihydrite using a reduction step, where dpa chelates the Fe reduced by a second hydrolysis product, H2S. Dpa facilitated dissolution of ferrihydrite showed very small increase in the Fe dissolution when the concentration of external reductant, ascorbate, was doubled, suggesting the surface dynamics being dominated by the interactions between dpa and ferrihydrite. Greater than stoichiometric amounts of Fe were mobilized during dpa dissolution of ferrihydrite assisted by ascorbate and cysteine. This is attributed to the catalytic dissolution of Fe(III)(hydr)oxides by the in situ generated Fe(II) in the presence of a complex former, dpa.  相似文献   
85.
土地覆盖制图:基于最优化遥感数据的支撑向量机分类   总被引:1,自引:0,他引:1  
遥感数据具有在不同空间、光谱和时间尺度上获取地表测量信息的能力,使其成为获取土地覆盖信息的一个主要数据源。影像分类即把卫星影像上的相关像元划分给某类已知的土地覆盖类型的过程。支撑向量机(SVMs)是一种土地覆盖分类的新技术。三种常用的SVMs是:基于线性和多项式的SVM以及具有高斯核函数的SVM分类器,分类能否成功地应用有赖于其各自选择的最佳参数。但是海量的遥感数据使得这些参数的确定速度十分缓慢。本文研究了一种新的基于最优化遥感数据压缩技术的SVM分类方法。研究显示用于获取SVM参数的数据量能够在不影响土地覆盖的分类精度的前提下进行压缩。数据压缩成功的应用于多项式和高斯核函数的SVM分类,而线性SVM的分类精度却非常低。  相似文献   
86.
We present HST-WFPC2/Hα deep images of the ejected nebula M1-67. Our data suggest that M1-67 is the imprint of a previous, slow LBV wind ejected from the central star WR124, now a WN8 star. We find evidence that the LBV wind is highly variableand anisotropic. Some dense, persisting clumps have possibly been ejected directly from the stellar surface. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   
87.
In an investigation of the starspot hypothesis as it applies to the 'slowly variable' F-type dwarfs, we spectroscopically observed eight promising γ Doradus candidates to search for Ca  ii H&K emission. We found that there are no significant emission reversals in the cores of these resonance lines. Based on the ceiling flux calculations of the Ca  ii K line and on calculations of the Rossby number, we conclude that there is no support for the presence of strong magnetic activity and the starspot hypothesis in these objects.  相似文献   
88.
The Howqua Olivine Pyroxenite of eastern Victoria, Australia, intrudes a metamorphosed sequence of Cambrian high-Mg lavas. It crystallized an unusual mineral assemblage: Cr-rich magnesiochromite, olivine (Fo94), and protoenstatite (now inverted to polysynthetically-twinned clinoenstatite). Residual liquid crystallized strongly-zoned interstitial pyroxenes followed by pargasite. Pargasite, often showing quench habit, crystallized in interstitial glass which is now altered to serpentine.The extremely refractory nature of the cumulus phases indicates a very high temperature of crystallization for liquidus olivine and chromite from a high-MgO, low-Al2O3 parent liquid similar in some respects to Archaean peridotitic komatiites. The suggested origin by hydrous melting of depleted mantle peridotite, plus other compositional and mineralogical similarities (especially the olivine-liquid reaction producing protoenstatite) indicate that the parent magma of the Howqua Olivine Pyroxenite had many features in common with the high-SiO2, high-MgO clinoenstatite-bearing boninitic lavas of the Western Pacific. It is interpreted as a more extreme melt with affinities to boninite and it demonstrates that ultramafic magmas existed in the Cambrian.  相似文献   
89.
Subsolidus and melting relations for the CaCO3-MgCO3 join at 30 kb have been determined using piston-cylinder apparatus. Data are also presented for the melting curve of CaCO3 to 30 kb, the decomposition and melting curves of MgCO3 to 36 kb, and the calcite-aragonite transition at 800°C, 950°C and 1100°C. At 30kb, the melting loop for the CaCO3-MgCO3 join extends from 1610°C (CaCO3) to 1585°C (MgCO3) through a liquidus minimum at 1290°C (near 42 mole% MgCO3). The dolomite-magnesite solvus barely intersects the 30 kb melting loop to produce a peritectic reaction at 1385°C. Integration of the new experimental data with other published data permits construction of a complete P-T projection and a sequence of isobars for the CaCO3-MgCO3 join for pressures between 5 and 30 kb. The phase relations for this join provide part of the essential framework of the model peridotite system CaO-MgO-SiO8-CO2-H2O, which has particular application to the origin of carbonatitic and kimberlitic magmas. In light of the accumulating evidence for CO2 in various forms within the upper mantle and of its effect on magmatic processes, analysis of the melting relations in this system is of considerable importance.  相似文献   
90.
Effect of freezing and thawing on the permeability and structure of soils   总被引:17,自引:0,他引:17  
The permeability and structure of four fine-grained soils were observed to be changed by freezing and thawing. In all cases freezing and thawing caused a reduction in void ratio and an increase in vertical permeability. The increase in permeability is attributed to the formation of polygonal shrinkage cracks and/or to the reduction of the volume of fines in the pores of the coarse fraction, the mechanism controlling the process depending on material type. No definite relationships are established; however, it appears that the largest increase in permeability occurs for the soil of highest plasticity.  相似文献   
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