Application of Compositional Techniques in the Field of Crystal Chemistry: A Case Study of Luzonite, a Sn-Bearing Mineral   总被引：1，自引：1，他引：0  

Miria Borgheresi  Antonella Buccianti  Francesco Di Benedetto  David John Vaughan 《Mathematical Geosciences》2013,45(2):183-206

Out-of-equilibrium crystallization often produces complex compositional variability in minerals, generating zoning and other mixing phenomena. The appropriate microchemical characterization of the resulting out-of-equilibrium patterns is of critical importance in understanding the overall physical and chemical properties of the host crystalline phases. In this framework, the modeling of compositional changes assumes a fundamental role. However, when compositional data are used, their management with standard exploratory, statistical, graphical, and numerical tools may give misleading results attributable to the phenomenon of induced correlations. To avoid these problems, methods able to extract compositional data from their constrained space (the simplex) in order to apply standard statistics, have to be adopted. As an alternative, the use of tools having properties able to work in the simplex geometry has to be considered. A luzonite single crystal (ideal composition, Cu₃AsS₄) exhibiting concentric and sector zoning was studied using electron probe microanalysis in order to understand the mechanisms which give rise to chemical variability and conditions in the developing environment. Compositional variations were determined by collecting data along three different transects. The major and minor elements (Cu, As, S, Fe, Sb, Sn) were analyzed with the aim of characterizing their patterns of association in the crystal and, hence, crystal evolution. The whole covariance structure as well as the chemical relationships between the successive zones was investigated by means of compositional methods, considering both data transformation and the stay in the simplex approach. Results indicate that the crystal grew under quiescent conditions, where chemical control was primarily exercised by the mineral’s surface and only minor effects were due to changes in the composition of the surrounding fluid. Consequently, an oscillatory uptake of chemical components occurred in which a competition between famatinite-like (Cu₃SbS₄) and kuramite-like (Cu₃SnS₄) domains characterized the As-poor zones.  相似文献   

Vent conditions for expected eruptions at Vesuvius     

Paolo Papale  Antonella Longo 《Journal of Volcanology and Geothermal Research》2008

Determining consistent sets of vent conditions for next expected eruptions at Vesuvius is crucial for the simulation of the sub-aerial processes originating the volcanic hazard and the eruption impact. Here we refer to the expected eruptive scales and conditions defined in the frame of the EC Exploris project, and simulate the dynamics of magma ascent along the volcanic conduit for sub-steady phases of next eruptions characterized by intensities of the Violent Strombolian (VS), Sub-Plinian 2 (SP2), and Sub-Plinian 1 (SP1) scale. Sets of conditions for the simulations are determined on the basis of the bulk of knowledge on the past history of Vesuvius [Cioni, R., Bertagnini, A., Santacroce, R., Andronico, D., Explosive activity and eruption scenarios at Somma–Vesuvius (Italy): towards a new classification scheme. Journal of Volcanology and Geothermal Research, this issue.]. Volatile contents (H₂O and CO₂) are parameterized in order to account for the uncertainty in their expected amounts for a next eruption. In all cases the flow in the conduit is found to be choked, with velocities at the conduit exit or vent corresponding to the sonic velocity in the two-phase non-equilibrium magmatic mixture. Conduit diameters and vent mixture densities are found to display minimum overlapping between the different eruptive scales, while exit gas and particle velocities, as well as vent pressures, largely overlap. Vent diameters vary from as low as about 5 m for VS eruptions, to 35–55 m for the most violent SP1 eruption scale. Vent pressures can be as low as less than 1 MPa for the lowest volatile content employed of 2 wt.% H₂O and no CO₂, to 7–8 MPa for highest volatile contents of 5 wt.% H₂O and 2 wt.% CO₂ and large eruptive scales. Gas and particle velocities at the vent range from 100–250 m/s, with a tendency to decrease, and to increase the mechanical decoupling between the phases, with increasing eruptive scale. Except for velocities, all relevant vent quantities are more sensitive to the volatile content of the discharged magma for the highest eruptive scales considered.  相似文献   

Invertebrate communities and epiphytic biomass associated with metaphyton and emergent and submerged macrophytes in a large river     

Céline Tessier  Antonella Cattaneo  Bernadette Pinel-Alloul  Christiane Hudon  Daniel Borcard 《Aquatic Sciences - Research Across Boundaries》2008,70(1):10-20

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The 1997 Umbria-Marche (Italy) earthquake sequence: analysis of the data recorded by the local and temporary networks   总被引：1，自引：0，他引：1  

M. Cattaneo  P. Augliera  G. De Luca  A. Gorini  A. Govoni  S. Marcucci  A. Michelini  G. Monachesi  D. Spallarossa  L. Trojani  Xgums 《Journal of Seismology》2000,4(4):401-414

We present some preliminary results obtained from thejoined analysis of the data collected by the permanentand the temporary networks operating in the area ofthe earthquake sequence that followed (andanticipated) the 26 September, Central Italy, mainshocks. In particular, these earthquake data haveallowed us to determine a well constrainedwave-velocity model (both P and S) with stationcorrections which demonstrated to produce robusthypocentral locations. These velocity modelswith station corrections have been used forre-locating the whole September 1997–July 1998subset of data of the permanent network, and theprevious background seismicity, starting from May1996. The focal mechanisms of the largest events werealso obtained from an analysis of the first-motionpolarities.Our results indicate that 1) the seismic activityaligns on a SE-NW trend for a total length of about50 km of extension; 2) the focal depth of theseevents is restricted to the range 0–9 km; 3) mostevents can be related to sub-parallel SW dipping faultplanes; 4) focal mechanisms of the largest shocks(M_L > 4) show a coherent behaviour, withnormal fault solution on SSE-NNW striking, SW dippingplanes; 5) the space-time evolution of the activitydisplays a discontinuous mode of energy release, withdifferent episodes of activation and an apparentclustering of aftershocks at the edges of the areaswhich presumably ruptured in the main shocks.  相似文献   

Removing tidal and atmospheric effects from Earth deformation measurements     

Antonella Amoruso  Luca Crescentini  & Roberto Scarpa 《Geophysical Journal International》2000,140(3):493-499

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Multi-criteria Evaluation of Bran Use to Promote Circularity in the Cereal Production Chain     

Grippo  Valeria  Romano  Severino  Vastola  Antonella 《Natural Resources Research》2019,28(1):125-144

Natural Resources Research - A reliable and realistic subsurface resource spatial modeling is a common and critical task for geosciences projects (mining, petroleum and environmental) because the...  相似文献   

Neo-deterministic definition of seismic input for residential seismically isolated buildings   总被引：1，自引：1，他引：0  

Elisa Zuccolo  Franco Vaccari  Antonella Peresan  Alberto Dusi  Alessandro Martelli  Giuliano F. Panza   《Engineering Geology》2008,101(3-4):89-95

This paper deals with the neo-deterministic definition of the seismic input in the municipality of Nimis (Italy), aimed at the design of residential seismically isolated buildings. The seismic input is defined by the computation of realistic synthetic seismograms considering different levels of detail for the earthquake source, both for a bedrock model and taking into account the specific site conditions. The horizontal response spectrum, calculated in the centre of the municipality by modelling the most dangerous source, advises against the construction of a building with a fixed base, but it is compatible with the seismic isolation, and it has been, therefore, used for the design of a residential seismically isolated building. The maximum displacement for the isolation system has been estimated about 17 cm, a value much lower than that provided by the code design response spectrum (28 cm). The importance of the realistic modelling, which permits the generalization of empirical observations by means of, physically sound, theoretical considerations, is evident, as it allows for the optimisation of the structural design with respect to the site of interest.  相似文献   

High‐resolution evolution of terrigenous sediment yields in the Provence Basin during the last 6 Ma: relation with climate and tectonics          下载免费PDF全文

Estelle Leroux  Marina Rabineau  Daniel Aslanian  Christian Gorini  Stéphane Molliex  Francois Bache  Cécile Robin  Laurence Droz  Maryline Moulin  Jeffrey Poort  Jean‐Loup Rubino  Jean‐Pierre Suc 《Basin Research》2017,29(3):305-339

Basin‐wide correlation of Messinian units and Plio‐Quaternary chronostratigraphic markers (5.3 Ma, 2.6 Ma, 0.9 Ma and 0.45 Ma), the mapping of total sediment thickness and the determination of overall sedimentary volumes enabled us to provide a high‐resolution quantitative history of sediment volumes for the last 6 Ma along the Gulf of Lions margin. The results point to (i) a dramatic increase in terrigenous sediment input during the Messinian Salinity Crisis. This increased sedimentation reflects enhanced regional fluvial erosion related to the dramatic fall of Mediterranean base‐level. Stronger weathering due to a regional wetter climate probably also increased erosional fluxes. (ii) A sediment input three times higher during the Plio‐Quaternary compared to the Miocene seems in agreement with published measurements from World's ocean. However, the timing of this increase being uncertain, it implies that the trigger(s) also remain(s) uncertain. (iii) A decrease in detrital volume around 2.6 Ma is attributed to a regional change in the drainage pattern of rivers in the northwestern Alps. (iv) This study also highlights the Mid‐Pleistocene Revolution around 0.9 Ma, which resulted in an almost doubling of sediment input in the Provencal Basin.  相似文献   

Dealing with double vagueness in DEM morphometric analysis     

Marcello Antonio Ventura Gorini  Guilherme Lucio Abelha Mota 《International journal of geographical information science》2016,30(8):1644-1666

A method is presented to explicitly incorporate spatial and scale vagueness – double vagueness – into geomorphometric analyses. Known limitations of usual practices include using a single fixed set of crisp thresholds for morphometric classification and the imposition of a single arbitrary number of scales of analysis to the entire digital elevation model (DEM). Among the advantages of the proposed method are: fuzzification of morphometric classification rules, scale-dependent adaptive fuzzy set parametrization and an objective definition of maximum scale of analysis on a cell-by-cell basis. The method was applied to several DEMs ranging from the ocean floor to surface landscapes of both Earth and Mars. The result was evaluated with respect to modal morphometric features and to characteristic scales, suggesting a more robust method for deriving both morphometric classifications and terrain attributes. We argue that the method would be preferable to any single-scale crisp approach, at least in the context of preliminary hands-off morphometric analyses of DEMs.  相似文献   

Evaluation of ecotoxicological effects of endocrine disrupters during a four-year survey of the Mediterranean population of swordfish (Xiphias gladius)   总被引：2，自引：0，他引：2  

Fossi MC  Casini S  Marsili L  Ancora S  Mori G  Neri G  Romeo T  Ausili A 《Marine environmental research》2004,58(2-5):425-429

In this project we investigated the ecotoxicological effects of endocrine disrupters in a four-year survey of the Mediterranean population of swordfish (Xiphias gladius). In the Mediterranean environment, top predators, such as swordfish, accumulate high concentrations of polyhalogenated aromatic hydrocarbons (PHAHs) and toxic metals, potentially incurring high toxicological risk. The effects of organochlorines and trace elements (Hg, Cd and Pb) in 192 swordfish specimens, caught in the Strait of Messina, Sicily, Italy, were investigated using vitellogenin (Vtg), zona radiata proteins (Zrp) and CYP1A (BPMO, EROD) activities. Vtg and Zrp were found to be dramatically induced in some adult male specimens, suggesting that this species is highly exposed to estrogens in the Mediterranean Sea. A role of organochlorines in this induction phenomenon is suggested by the statistically significant correlations between Zrp in plasma and PCB concentrations in muscle (p<0.032) and Vtg in plasma and PCB concentrations in liver (p<0.034) of male specimens. Levels of trace elements in liver were in the following ranges: Hg 1-22, Cd 1-28 and Pb 0-1.6 ppm d.w. These data indicate potential reproductive alterations in large pelagic fish and suggest the need for continuous monitoring to avoid reductions in the population of this fish species of high commercial and ecological interest.  相似文献