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41.
We describe several pioneering organic geochemical studies from the 1930s on estrogenic substances isolated from various fossil fuels and bituminous materials and from water and sediments of the Dead Sea. The techniques employed were bioanalytical and not chemical. One of the studies, although not done on the same molecular level as his, precedes the work of Alfred Treibs, who is considered the father of organic geochemistry. By shedding light on a relatively unknown chapter of organic geochemistry, the roots of this discipline are shown to extend wider than usually recognized.  相似文献   
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#Earthquake: Twitter as a Distributed Sensor System   总被引:10,自引:1,他引:9  
Social media feeds are rapidly emerging as a novel avenue for the contribution and dissemination of information that is often geographic. Their content often includes references to events occurring at, or affecting specific locations. Within this article we analyze the spatial and temporal characteristics of the twitter feed activity responding to a 5.8 magnitude earthquake which occurred on the East Coast of the United States (US) on August 23, 2011. We argue that these feeds represent a hybrid form of a sensor system that allows for the identification and localization of the impact area of the event. By contrasting this with comparable content collected through the dedicated crowdsourcing ‘Did You Feel It?’ (DYFI) website of the U.S. Geological Survey we assess the potential of the use of harvested social media content for event monitoring. The experiments support the notion that people act as sensors to give us comparable results in a timely manner, and can complement other sources of data to enhance our situational awareness and improve our understanding and response to such events.  相似文献   
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Correlation of geophysical data collected using the NMR method in the Negev Desert, Israel, with hydrogeological data from nearby observation wells is presented. The experiment was conducted near Kibbutz Revivim in the Besor drainage system (Fig. 1). The objective of the survey was to detect groundwater layers in the Quaternary cover filling and Eocene fractured aquifers down to a depth of 100 m. The experiment was performed using a combination of two different geophysical techniques, namely the NMR and time domain electromagnetic (TDEM) methods. The geophysical results were verified by measuring the water level in three observation wells, two of which were drilled several months after the geophysical survey was carried out.The water level measured in these follow-up observation wells shortly after drilling did not coincide with the geophysical data. However, it settled over a period of time and finally stabilized at a depth very similar to that obtained from the NMR measurements. This phenomenon is caused by the fractured nature of the phreatic aquifer. Since the flow of water in such aquifers is confined by the fractures, the appearance of water in the well during or shortly after drilling is determined solely by the intersection of the well and the fracture. Our experiments showed that geophysical measurements in fractured phreatic aquifers may have a distinct advantage over direct borehole measurements, since the former average the depth to the water table over large areas (several thousand square meters) while the latter are limited by the area of the borehole cross-section (several tens of square centimeters).  相似文献   
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A detailed GC/MS study of biological marker compounds in the saturated and aromatic hydrocarbon fractions of oils and asphalts from the Dead Sea area, Israel, provided decisive information to the solution of a long-lasting controversy by showing that the asphalts are products of early generation in an immature stage from the same type of carbonate source rock which generated more mature oils. The asphalts are not biodegraded residues of the oils.Oils from six different wells, and asphalts from wells, outcrops, and a floating block from the Dead Sea all have very similar sterane and triterpane patterns. They all lack rearranged steranes (diasteranes) indicating a carbonate source matrix and compare reasonably well with a sample of Upper Cretaceous bituminous chalk from Nebi Musa. The main difference between the oils and the asphalts is a significantly higher triaromatic to mono- plus triaromatic steroid hydrocarbon ratio in the former. This is explained as a result of rapid subsidence and heating of their source rock close to the deep parts of the Dead Sea graben. The oils thus were generated in the more deeply buried source rock blocks under the graben fill, whereas the asphalts either originate from an immature source rock section closer to the graben rims or represent an earlier phase of generation and expulsion.This study also provides general information on the evolution of biological markers in carbonate source rocks. Low-activation-energy processes, like isomerisation of steranes, appear to occur much faster at low temperatures than in shales. The high sulfur content and less cross-linking of the biogenic organic matter into a complex kerogen structure are suggested to be responsible for this. Care should be taken when using only sterane isomerisation to assess the maturity of hydrocarbons from carbonate rocks and of carbonate-derived oils.  相似文献   
48.
The phosphorus content of marine humic acids (HA) is in the range of 0.1–0.2%. The C/P ratios of the HA are 300 to 400. Marine fulvic acids (FA) contain 0.4–0.8% P and have C/P ratios of 80 to 100. High molecular weight organic matter dissolved in pore waters (DOM) contains 0.5% P and has C/P of 90. The data suggest that during the formation sequence: Plankton → DOM → FA → HA → Kerogen, phosphorus is lost, mainly in the FA → HA (and possibly also in the HA → Kerogen) step. Diagenesis of sedimentary humic acids is accompanied by loss of phosphorus (as well as of nitrogen) to form HA with C/P ratios of 1000.Soil humic substances resemble marine humates in P content (0.3%) and soil FA's are about three to fivefold enriched in P relative to HA. C/P ratios are lower in soil HA (ca. 200) as compared with marine HA. Humic acids from diagenetic products such as peat and lignite are highly depleted in P. Rough calculations indicate that humate bound P may account for 20–50% of the organic phosphorus reservoir in sediments. The chemical speciation of this P is unknown, but lack of correlation with ash, Fe, Ca or Al content (in marine humates, at least) indicates that it is organically bound.  相似文献   
49.
The goodness of fit of the negative binomial and the Poisson distributions to partial duration series of runoff events is tested. The data have been recorded by eight hydrometric stations located on ephemeral rivers in Isreal. For each station, a number of threshold discharges are considered, by that series of nested subsamples are formed. Owing to size limitations, a Chi-square test is conducted on samples associated with low to moderate threshold discharges. Positive results, at a 5% significance level, are obtained in 30 out of the 53 tests of the Poisson distribution, and in 22 out of the 28 tests of the negative binomial distribution. The fit of the Poisson distribution to samples of conventionally recommended sizes (of 2 to 3 events per year) is found positive for five rivers and negative for the three other rivers The fit of the negative binomial distribution to these samples is found positive for six rivers, inconclusive for one river and short of data for the eighth river. Mixed results are obtained as the threshold level is raised. Therefore, no direct extrapolation is possible to samples associated with high thresholds.An indirect extrapolation is drawn through a comparison of the actual properties of the samples with those expected under a perfect fit of the distribution functions. Ranges of such properties are defined with respect to the properties of the tested samples and to the test results. The actual properties of nine of the eleven samples associated with high thresholds (i.e. mean number of events <-0.1year –1) are found within these ranges. This provides a hint for a probable good fit of either distribution, and particularly the negative binomial, to the occurrence frequency of high events.  相似文献   
50.
A comparison is carried out between historical records of the flow measured in Kinneret watershed during and prior to the time of cloud seeding for rainfall enhancement. Precipitation series for the control area of the meteorological experimentation serve as a reference for the comparison. The fluctuations of the flow, which would have occurred unless the effect of the seeding, are estimated by a linear regression on the precipitation as the control. The regression parameters are calibrated separately for the unseeded and for the seeded time series. The model with the parameters calibrated for the unseeded series is applied on the rainfall recorded during the seeded time, and vice versa. The difference between the measured and the computed data is attributed to the effect of cloud seeding. Similar comparisons are carried out with respect to rainfall series recorded at the target area and at the edge of the enhanced area.The results indicate that the flow from the affected sector of the watershed has been enhanced, with respect to the control, by 31×106 m 3/year, at a significance level of 31. This enhancement is 5% of the volume which is generated in that area. The rates found with respect to the rainfall at the edge are higher than those found with respect to the control, while those with respect to the rainfall at the center of the target area are lower.  相似文献   
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