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41.
42.
We invert ISC PcP and PKP absolute and differential traveltimes in an attempt to infer the long-wavelength topography of the core-mantle boundary (CMB). The data selection and processing methods are described and evaluated. These travel-time data are very noisy and the geographic distribution of the data is highly non-uniform, inhibiting reliable inference of CMB topography. Spatial averaging enhances the coherent component of the residual variance (related to heterogeneity), however, the random component of the variance is much larger than the coherent component. We show that for PcP data the coherent signal due to mantle heterogeneity overshadows that arising from the CMB, and that the effects of mantle heterogeneity are mapped into our inferred CMB solutions. The PcP data are not correlated across the spatial averaging bins and seem to have a strong bias due to small-scale structure and/or noise. The non-uniform geographic sampling of the data plays a role in the mapping of mantle heterogeneity onto the CMB. Spatial patterns of CMB models inferred from different phases do not agree. Amplitudes of seismically inferred CMB undulations vary greatly. The sensitivity of inferred CMB models to the processing, spatial averaging procedure, and inversion techniques are investigated. Topographic amplitudes increase strongly with increasing input residual variance. The power spectrum of inferred topography indicates that there are unmodelled heterogeneities that must be described with spherical harmonics of degree 6 and higher. Based on this work, we conclude that reliable inference of long-wavelength CMB topography is not likely with the current ISC data set or with a spherical harmonic expansion truncated to degree and order 6. 相似文献
43.
Donald C. Thornton Alan R. Bandy Robert G. Ridgeway Arthur R. Driedger III Marija Lalevic 《Journal of Atmospheric Chemistry》1990,11(4):299-308
Stable isotopic dilution was applied to the determination of dimethyl sulfide (DMS) in ambient air at the low part-per-trillion by volume (pptrv) levels. Perdeuterated DMS was used as an internal standard in the gas chromatography/mass spectrometry determination. The isotopically labelled internal standard provided insensitivity to possible losses of DMS in sampling and analysis. The lower limit of detection (LLD) was 1 pptrv with a sample acquisition time of 2 min. 相似文献
44.
Closed form analytic expressions for displacement and stresses at any point of either of the two homogeneous, isotropic, perfectly
elastic half-spaces in welded contact due to very long strike-slip dislocations are obtained. Both cases of vertical and horizontal
strike-slip dislocations are discussed in detail. Variation of the displacement with horizontal distance from the fault and
with vertical distance from the interface for a vertical strike-slip fault is studied numerically. 相似文献
45.
Arthur G. Clem 《Engineering Geology》1985,21(3-4):273-278
Smectite is a mineral, but a mineral with distinct chemical properties. Structural changes in minerals may require millions of years of aging to complete, but a chemical reaction may be completed in only 4 to 5 min.
Some of the problems of smectite seals are described in this paper, together with methods of avoiding these hazards. 相似文献
46.
Arthur P. S. Reymer Alan Matthews Oded Navon 《Contributions to Mineralogy and Petrology》1984,85(4):336-345
Geothermobarometry using continuous equilibria in pelitic rocks of the central and northeastern Wadi Kid areas, Sinai, yields pressure estimates of 320 MPa (3.2 kbar) and temperature estimates of 565° C and >620° C for staurolite-andalusite zone assemblages and anatectic rocks, respectively. This corresponds to geothermal gradients of 47° C/km and 50° C/km. TheseP-T conditions are shown to be compatible with burial under a volcanic cover. The principal heat source for high-grade metamorphism and anatexis is thought to be rising magmatic diapirs. Uplift was relatively slow and the final stages of heating and early stages of cooling probably occurred isobarically. The data imply a high heat flow regime for the Pan-African event in Sinai. 相似文献
47.
ABSTRACT
A flume study was made of fluid flow, boundary skin friction, and sediment transport about an animal-tube mimic. The effect of a tube on momentum transfer depends most strongly on its height. A tube increases the net boundary skin friction locally and tends to promote sediment entrainment near its base. Flow in this region appears to be governed by the same similarity laws that apply to cylinders with much larger body Reynolds number. Particles travelling as suspended load may be deposited immediately downstream of the tube. The net sedimentological effect of any tube (i.e. deposition or scour) will depend both on its height and on the boundary shear stress imposed by the external flow. The near-wake region of a tube is dominated by a strong cross-stream exchange of momentum. Wake perturbations decay downstream seemingly in accordance with similarity laws which also govern mounted, two-dimensional structures. 相似文献
A flume study was made of fluid flow, boundary skin friction, and sediment transport about an animal-tube mimic. The effect of a tube on momentum transfer depends most strongly on its height. A tube increases the net boundary skin friction locally and tends to promote sediment entrainment near its base. Flow in this region appears to be governed by the same similarity laws that apply to cylinders with much larger body Reynolds number. Particles travelling as suspended load may be deposited immediately downstream of the tube. The net sedimentological effect of any tube (i.e. deposition or scour) will depend both on its height and on the boundary shear stress imposed by the external flow. The near-wake region of a tube is dominated by a strong cross-stream exchange of momentum. Wake perturbations decay downstream seemingly in accordance with similarity laws which also govern mounted, two-dimensional structures. 相似文献
48.
The distribution and mode of occurrence of zinc and lead have been examined in glacial soils developed over a complex Precambrian marble-paragneiss terrain in the Adirondack Mountains of New York. Based on distribution within the soil profiles, zinc is enriched in the B1 horizon of soils sampled over marble and lead is generally enriched in the A horizon, particularly in soils developed over paragneiss. Contrast is calculated using
, where
is the mean of nA anomalous and nB background samples, and Sp is the pooled standard deviation) for zinc, lead and cold-extractable heavy metals in soils sampled over marble and paragneiss. The t-values indicate that the B1, soil horizon is the most suitable for sampling on a regular basis, even though lead is most concentrated in the A horizon.The distribution of zinc and lead among exchangeable, organic, iron-manganese oxide, clay, silt and sand fractions of B1 horizons from two anomalous and one background soil indicates that both zinc and lead are tied up principally in iron and manganese oxides. The anomalous samples exhibit zinc enrichment in the Fe-oxide digestion and high Mn/Fe ratios for the Mn-oxide digestion (as well as the total analysis). In terms of total contribution to the sample, significant proportions of zinc in the clastic fraction can be attributed to zinc substitution into clays plus the ineffective removal of Fe-oxides by the ammonium oxalate extraction procedure. Lead, on the other hand, occurs in significant concentrations in clay, silt and sand as well as Fe- and Mn-oxides, probably as a trace constituent in feldspars or adsorbed onto clay surfaces. 相似文献
Full-size image (1K)
49.
Roy F. Spalding A.Douglas Druliner Lowell S. Whiteside Arthur W. Struempler 《Geochimica et cosmochimica acta》1984,48(12):2679-2692
Dissolved U concentrations and activity ratios (ARs) of the U isotopes in the 238U decay series were measured in ground and surface waters as part of an investigation to delineate the water quality in a proposed uranium mining area of northwest Nebraska. In oxidizing groundwaters from 67 wells completed in the Tertiary sediments, increasing U concentrations in the direction of groundwater flow generally were associated with a maturation of the formation water as evidenced by evolutionary trends in major ion character. The increased U levels probably are associated with leaching as shown by the positive correlation between U concentrations and total dissolved solids (TDS) (r = +0.83). The inverse relationships between TDS and U ARs (r = ?0.73) and U levels and ARs (r = 0.72) indicate that the decay of excess U-234 is related to maturation of the formation water and to sediment leaching along the flowpath. The data are described by a model which incorporates etching, decay and recoil and suggests that aquifer residence time can be estimated from the TDS level.The levels of soluble U in a reducing uraniferous hydrogeologic unit near Crawford, Nebraska are affected by the proximity of the sample collection to ore. In groundwater samples having similar chemistries (Na-SO4 + Cl type), similar Ehs, and collected from a close-knit pattern, U concentrations ranged from 0.01 to 2,037 μg l?1 and ARs ranged from 0.75 to 12.6. This high variability in U levels and ARs is indicative of uranium ore in small areal studies where low ARs almost always are associated with high U concentrations. 相似文献
50.
Arthur D. Cohen William Spackman Philip Dolsen 《International Journal of Coal Geology》1984,4(1):73-96
Cores and surface samples of peats from the Everglades—Mangrove region of Southern Florida were analyzed for total sulfur and pyritic sulfur. These values were compared with the petrographic-botanical components of the peats as determined from point-counts of oriented microtome sections. Pyrite occurs as individual euhedral crystals, loosely packed framboids, and lenses or crusts of minute crystals. Framboids and minute crystals are often associated with organic matter and sometimes with bacteria and fungi. Pyrite tends to selectively occur in void spaces in or between peat tissues. In samples containing very small amounts of pyrite, framboidal pyrite is the prevalent form.Marine to brackish peats contain the highest pyrite and total sulfur contents, with brackish peats generally containing more pyrite than marine peats. Pyrite tends to be lower in all peats within 30 cm of the surface, whether marine or brackish.Burial of freshwater peats beneath marine or brackish peats tends to increase the total sulfur and pyritic sulfur in the underlying peats. Burial beneath brackish-water, clay-rich deposits (such as splays) tends to increase total sulfur and pyritic sulfur in the underlying deposits more than burial beneath less clay-rich deposits. 相似文献