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51.
激光剥蚀-等离子体质谱技术及其在地球化学宇宙化学和环境研究中的应用 总被引：1，自引：0，他引：1
JOCHUM Klaus Peter STOLL Brigitte FRIEDRICH Jon M AMINI Marghaleray BECKER Stefan DüCKING Marc EBEL Denton S ENZWEILER Jacinta 胡明月 KUZMIN Dmitry MERTZ KRAUS Regina MüLLER Werner E G REGNERY Julia SOBOLEV Alexander 王晓红 詹秀春 《岩矿测试》2009,28(1):53-68
激光剥蚀-等离子体质谱(LA-ICPMS)已成为地球化学、宇宙化学和环境研究领域元素和同位素原位分析最重要的技术之一。文章介绍了多种类型的质谱仪及其使用的激光器。用途最广的LA-ICPMS仪器之一是单接收器扇形磁场质谱仪,配有Nd:YAG激光剥蚀系统(激光波长分为193 nm和213 nm两种),MPI Mainz实验室使用的就是这套系统,文章对此作一详细介绍。文中阐述了数据优化技术及其多种校正过程;介绍LA-ICPMS在痕量元素和同位素分析领域的一些应用,包括参考物质的研制,Hawaiian玄武岩、Martian陨石、生物骨针和珊瑚虫中痕量元素分析及熔融包裹体和富钙-铝碳质球粒陨石中的铅和锶同位素测量。 相似文献
52.
Groundwater recharge estimation in arid hardrock‐alluvium aquifers using combined water‐table fluctuation and groundwater balance approaches 
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下载免费PDF全文 Azizallah Izady Osman A.E. Abdalla Ata Joodavi Akbar Karimi Mingjie Chen Andrew Tompson 《水文研究》2017,31(19):3437-3451
This paper proposes an approach to estimate groundwater recharge using an optimization‐based water‐table fluctuation method combined with a groundwater balance model in an arid hardrock‐alluvium region, located at the Oman–United Arab Emirates border. We introduce an “effective hardrock thickness” term to identify the percentage of the considered hardrock thickness in which effective groundwater flow takes place. The proposed method is based upon a Thiessen polygon zoning approach. The method includes subpolygons to represent specific geologic units and to enhance the confidence of the estimated groundwater recharge. Two linear and 1 nonlinear submodels were developed to evaluate the model components for the calibration (October 1996 to September 2008) and validation (October 2008 to September 2013) periods. Long‐term annual groundwater recharge from rainfall and return flow over the model domain are estimated as 24.62 and 5.71 Mm3, respectively, while the effective groundwater flow circulation is found to occur in the upper 7% of the known hardrock thickness (42 m), confirming conclusions of previous field studies. Considering a total difference in groundwater levels between eastern and western points of the study area of the order of 220 m and a 12‐year monthly calibration period, a weighted root mean squared error in predicted groundwater elevation of 2.75 m is considered quite reasonable for the study area characterized by remarkable geological and hydrogeological diversity. The proposed approach provides an efficient and robust method to estimate groundwater recharge in regions with a complex geological setting in which interaction between fractured and porous media cannot be easily assessed. 相似文献
53.
The flare index of the current solar cycle 22 is analysed to detect intermediate-term periodicities from Sep. 1, 1986 to Dec. 31, 1991. Power spectral analysis of the time series of solar flare index data reveals a periodicity around 73 and 53 days. We find that a periodicity of 73 days was in operation from 1988 November to the end of 1991 December. We also find that when the 73-day periodicity or the 154-day periodicity is in operation, the flare index is well correlated with the relative sunspot numbers. As a conclusion, we do not expect to see a resumption of the 154-day or 73-day periodicity, but we do expect only one of the periodicity near the integral multiples of 25d.8 in the next solar cycles. 相似文献
54.
Tamer Ataç 《Astrophysics and Space Science》1991,181(1):157-159
This Letter is based on analysis of data on Sudden Ionospheric Disturbances (SID) listed inSolar Geophysical Data. The mean durations of 1272 SIDs taken from the SGD lists were calculated with respect to their associated X-ray flares. In general, all of our calculated mean durations showed a large scatter in the mean values. The comparison of our values by the estimated Solar Geophysical Data Center SID durations indicated an apparent discrepancy in the mean duration relative to that estimated by SGD for the case of low levels of SID importance. In our opinion this apparent discrepancy suggests a need for a correction in SGD's assumptions in the importance range from –1 to +1. 相似文献
55.
Zafer Ekinci Enes ŞayanAyşe Vildan Beşe Osman Nuri Ata 《International Journal of Mineral Processing》2007
In this study, the boric acid extraction from colemanite ore in aqueous media saturated by CO2 and SO2 gases was studied and the effects of relevant parameters, namely; reaction temperature, solid-to-liquid ratio, mean particle size, stirring speed and reaction time have been investigated on the boric acid extraction from colemanite ore by using the fractional factorial design and central composite design methods. The chosen experimental parameter levels were as follows: reaction temperature, 11.4–58.6 °C; solid-to-liquid ratio, 0.0685–0.1315 g/mL; mean particle size, 0.2835–3 mm; stirring speed, 107–893 rpm; reaction time, 7.125–22.875 min. A model has been developed between the boric acid extraction efficiency from colemanite ore and relevant parameters by means of variance analysis by using the matlab computer software and the obtained model was used to determine optimum conditions. The optimum conditions were found to be as follows: reaction temperature, 41 °C; solid-to-liquid ratio, 0.0685 g/mL; mean particle size, 0.2835 mm; stirring speed, 266 rpm; reaction time, 7 min. The calculated boric acid extraction efficiency from colemanite ore was approximately 99.9% under the optimum conditions. 相似文献
56.
S. P. SCHWENZER J. FRITZ D. STÖFFLER M. TRIELOFF M. AMINI A. GRESHAKE S. HERRMANN K. HERWIG K. P. JOCHUM R. K. MOHAPATRA B. STOLL U. OTT 《Meteoritics & planetary science》2008,43(11):1841-1859
Abstract— Noble gas data from Martian meteorites have provided key constraints about their origin and evolution, and their parent body. These meteorites have witnessed varying shock metamorphic overprinting (at least 5 to 14 GPa for the nakhlites and up to 45–55 GPa (e.g., the lherzolitic shergottite Allan Hills [ALH] A77005), solar heating, cosmic‐ray exposure, and weathering both on Mars and Earth. Influences on the helium budgets of Martian meteorites were evaluated by using a new data set and literature data. Concentrations of 3He, 4He, U, and Th are measured and shock pressures for same sample aliquots of 13 Martian meteorites were determined to asses a possible relationship between shock pressure and helium concentration. Partitioning of 4He into cosmogenic and radiogenic components was performed using the lowest 4He/3He ratio we measured on mineral separates (4He/3He = 4.1, pyroxene of ALHA77005). Our study revealed significant losses of radiogenic 4He. Systematics of cosmogenic 3He and neon led to the conclusion that solar radiation heating during transfer from Mars to Earth and terrestrial weathering can be ruled out as major causes of the observed losses of radiogenic helium in bulk meteorites. For bulk rock we observed a correlation of shock pressure and radiogenic 4He loss, ranging between ?20% for Chassigny and other moderately shocked Martian meteorites up to total loss for meteorites shocked above 40 GPa. A steep increase of loss occurs around 30 GPa, the pressure at which plagioclase transforms to maskelynite. This correlation suggests significant 4He loss induced by shock metamorphism. Noble gas loss in rocks is seen as diffusion due to (1) the temperature increase during shock loading (shock temperature) and (2) the remaining waste heat after adiabatic unloading (post shock temperature). Modeling of 4He diffusion in the main U, Th carrier phase apatite showed that post‐shock temperatures of ?300 °C are necessary to explain observed losses. This temperature corresponds to the post‐shock temperature calculated for bulk rocks shocked at about 40 GPa. From our investigation, data survey, and modeling, we conclude that the shock event during launch of the meteorites is the principal cause for 4He loss. 相似文献
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58.
An explicit model management framework is introduced for predictive Groundwater Levels(GWL),particularly suitable to Observation Wells(OWs)with sparse and possibly heterogeneous data.The framework implements Multiple Models(MM)under the architecture of organising them at levels,as follows:(i)Level 0:treat heterogeneity in the data,e.g.Self-Organised Mapping(SOM)to classify the OWs;and decide on model structure,e.g.formulate a grey box model to predict GWLs.(ii)Level 1:construct MMs,e.g.two Fuzzy Logic(FL)and one Neurofuzzy(NF)models.(iii)Level 2:formulate strategies to combine the MM at Level 1,for which the paper uses Artificial Neural Networks(Strategy 1)and simple averaging(Strategy 2).Whilst the above model management strategy is novel,a critical view is presented,according to which modelling practices are:Inclusive Multiple Modelling(IMM)practices contrasted with existing practices,branded by the paper as Exclusionary Multiple Modelling(EMM).Scientific thinking over IMMs is captured as a framework with four dimensions:Model Reuse(MR),Hierarchical Recursion(HR),Elastic Learning Environment(ELE)and Goal Orientation(GO)and these together make the acronym of RHEO.Therefore,IMM-RHEO is piloted in the aquifer of Tabriz Plain with sparse and possibly heterogeneous data.The results provide some evidence that(i)IMM at two levels improves on the accuracy of individual models;and(ii)model combinations in IMM practices bring‘model-learning’into fashion for learning with the goal to explain baseline conditions and impacts of subsequent management changes. 相似文献
59.
Ata Amini Pezhman Taherei Ghazvinei Mitra Javan Bahram Saghafian 《Arabian Journal of Geosciences》2014,7(8):3271-3279
Recently, water and soil resource competition and environmental degradation due to inadequate management practices have been increased and pose difficult problems for resource managers. Numerous watershed practices currently being implemented for runoff storage and flood control purposes have improved hydrologic conditions in watersheds and enhanced the establishment of riparian vegetation. The assessment of proposed management options increases management efficiency. The purpose of this study is to assess the impact of watershed managements on runoff storage and peak flow, and determine the land use and cover dynamics that it has induced in Gav-Darreh watershed, Kurdistan, Iran. The watershed area is 6.27 km2 which has been subjected to non-structural and structural measures. The implemented management practices and its impact on land use and cover were assessed by integrating field observation and geographic information systems (GIS). The data were used to derive the volume of retained water and determine reduction in peak flow. The hydrology of the watershed was modeled using the Hydrologic Engineering Center–Hydrologic Modeling System (HEC–HMS) model, and watershed changes were quantified through field work. Actual storms were used to calibrate and validate HEC–HMS rainfall–runoff model. The calibrated HEC–HMS model was used to simulate pre- and post-management conditions in the watershed. The results derived from field observation and HEC–HMS model showed that the practices had significant impacts on the runoff storage and peak flow reduction. 相似文献
60.
The periodic analyses of solar flare data have been carried out by different authors for about three decades. Controversial
results appear as depending on the analysis techniques and investigated time periods. Considering that different authors applied
different methods to different data sets, it seems necessary to reanalyze the periodicity of solar flare index with a unified
method. In this study we used two new methods to investigate the periodic behavior of solar flare index data, first for individual
cycles 21, 22 and 23, and then for all of them. We used i) the multi taper method with red- and white-noise approximations, and ii) the Morlet wavelet transform for periodicity analysis. Apart from the solar rotation periodicity of about 27 days which
is of obvious significance and is found in all examined cycles with at least a 90% significance level, we obtained the following
prominent periods: 152 days for cycle 21, 73 days for cycle 22, and 62 days for cycle 23. Finally, we compare our results
with the ones previously found. We emphasize the fact that a lesser number of periodicities is found in the range of low frequencies
(long periods) while the higher frequencies show a greater number of periodicities. This result might be useful for better
predictions of the solar cycles. 相似文献