Evaluations of heavy metal pollution in sediment and Mullus barbatus from the Izmir Bay (Eastern Aegean) during 1997-2009     

Kucuksezgin F  Kontas A  Uluturhan E 《Marine pollution bulletin》2011,62(7):1562-1571

Izmir Bay is one of the great natural bays of the Mediterranean. The surface sediment and fish samples were collected during 1997-2009. The sediment concentrations of inner bay showed significant enrichments during sampling periods. Outer and middle bays exhibited low levels of metal enrichments except the estuary of Gediz River. The concentrations were generally higher than the background levels from the Mediterranean and Aegean except Cd and Pb levels gradually decreased. Metal EF is used as an index to evaluate anthropogenic influences of metals in sediments. Maximum metal enrichment was found for Hg in the outer bay, while Pb indicated maximum enrichment in the middle-inner bays. Metal levels were evaluated in sediments in accordance with the numerical SQG of the USEPA. The levels of fish tissues were lower than the results reported from polluted areas of the Mediterranean. The highest BAFs were detected for Hg and Cd in fish.  相似文献   

A Comparative Study of Ozonation,Homogeneous Catalytic Ozonation,and Photocatalytic Ozonation for C.I. Reactive Red 194 Azo Dye Degradation     

A. Özlem Yıldırım  Şermin Gül  Orkide Eren  Erdal Kuşvuran 《洁净——土壤、空气、水》2011,39(8):795-805

In this study, the decolorization, dearomatization, and mineralization efficiencies of different advanced oxidation processes (AOPs; namely O₃, O₃/Fe(II), O₃/Fe(II)/UVA, and O₃/TiO₂/UVA) were investigated for the azo dye C.I. Reactive Red 194 (RR194). The effects of pH (3–11), amount of TiO₂ (0.05–1 g/L), and concentration of Fe(II) (0.1–1.6 mM) were investigated for the applied methods. The decolorization and mineralization efficiencies of the photocatalytic ozonation system (O₃/TiO₂/UVA) were increased by decreasing the pH of the dye solution in contrast to the ozonation system (O₃). Decolorization of RR194 was increased in the photocatalytic ozonation system with an increasing amount of catalyst however, a decreasing was occurred for the homogeneous catalytic system (O₃/Fe(II)) when increasing the concentration of catalyst. The decolorization efficiency of the homogeneous catalytic system (O₃/Fe(II)) was enhanced when combined with UVA light. In our study, the most efficient method for dearomatization and mineralization was the O₃/TiO₂/UVA among the applied AOPs.  相似文献   

E1 and E2 transitions for Fe XVI,Co XVII and Ni XVIII     

G. Çelik  Ş. Ateş 《Astrophysics and Space Science》2016,361(7):229

  相似文献   

Evidence of Possible Recharge Zones for Lake Salda (Turkey)     

Hüseyin Çaldırak  Bedri Kurtuluş 《Journal of the Indian Society of Remote Sensing》2018,46(9):1353-1364

This study explores the evidence of recharge locations using hydrogeochemical and physicochemical measurements in an alkaline lake, Lake Salda, in Burdur, Turkey. In-situ measurements have been performed using a conductivity–temperature–depth device to map the physicochemical dynamic of the lake. Water and sediment samples were collected on the surface and floor of the lake. A seismic study was also carried out in order to observe the geometry of the lake floor. In addition, thermal distribution was mapped using the thermal band of Landsat 7 ETM+ and Landsat 8 satellite images. Temperature and specific conductance measurements were mapped using a new technique, Empirical Bayesian Kriging (EBK), from the lake’s surface to the floor. According to interpolation maps obtained from the EBK, possible water inputs were observed close to a fault at the south-eastern part of the lake. The results of thermal band imaging also reveal the probability of a fault effecting the recharge on the surface. The results of water and sediment samples present a richness in Mg²⁺ and Fe²⁺ elements respectively on the floor of the lake. Finally, seismic results show some possible recharge zones on the floor of the lake, and sediment results indicate that there should be peridotite occurrence below the alluvium unit.  相似文献   

Influence of 1 GHz radiation at low specific absorption rate of energy deposition on plant mitotic division process     

M. Răcuciu  C. Iftode  S. Miclăuş 《International Journal of Environmental Science and Technology》2018,15(6):1233-1242

The biological impact of microwaves exposure on biosphere is presently an important research subject. With the significant increase of communications technology use, of industrial and military activities which involve radiofrequency radiation, electromagnetic pollution became very intense in the last years. The aim of the present work was to investigate the genotoxic influence of microwaves on Zea mays seeds. They were exposed in controlled conditions for different durations at 1 GHz continuous wave providing a low specific absorption rate of energy. Post-exposure the mitotic- and chromosomal aberrations indexes were determined. Qualitatively, a wide range of abnormal mitotic stages were detected in cells of exposed seeds in comparison with the control. Quantitatively, slight stimulatory effect on mitotic division process, expressed by an enhanced percentage of dividing cells (increased of 26% for 180 min exposure), for all exposed samples was revealed, while lowered level of induced chromosomal aberrant cells percentage (up to 2.14%) was also found. The aberrations percentage and mitotic index increased in time-dependent manner on exposure dose.  相似文献   

Spatial distribution of some elements and elemental contamination in the sediments of Köyceğiz Lake (SW Turkey)     

Halil İbrahim Gülşen-Rothmund  Özgür Avşar  Ulaş Avşar  Bedri Kurtuluş  Evren Tunca 《Environmental Earth Sciences》2018,77(14):546

Elemental accumulation, distribution and relationship profiles for sediment samples taken at 81 localities in the Köyce?iz Lake were investigated. Spatial distribution maps for ten elements (Cu, Pb, Zn, Ni, Cr, Co, Mn, Mo, Al, Fe) were created using the ordinary kriging interpolation method. Statistical tests revealed that the sediments taken from areas close to the Namnam (NamSM) and Karg?cak (KarSM) stream mouths have the highest element content. In addition, sediments close to NamSM have the highest contamination, according to contamination degree and modified contamination degree values. On the other hand, sediments close to KarSM have the highest value on the pollution load index. The enrichment factor and contamination factor values of Cr and Co, and especially Ni, close to NamSM are striking and have significantly higher values compared to the rest of the lake. There are strong correlations between these three elements, which were also confirmed by cluster analysis. Ni is the element having the highest value on the geoaccumulation index. In addition, according to the toxic unit results, it was found that 84–89% of the element-based toxic effect in the lake is due to Ni alone. According to the mean effect range median quotient values, the sediments of Köyce?iz Lake have a potential to show toxic effects of at least 76% in living organisms, which is due to the high levels of Ni. According to the mean probable effect low quotient value, it has been determined that Köyce?iz Lake is at a “highly impacted” level, which is the worst possible value on the quality scale.  相似文献   

Groundwater potential mapping by combining fuzzy-analytic hierarchy process and GIS in Beyşehir Lake Basin,Turkey     

Erhan Şener  Şehnaz Şener  Ayşen Davraz 《Arabian Journal of Geosciences》2018,11(8):187

Delineation of the groundwater potential zones is one of the most essential process for the sustainable management of the groundwater sources. However, groundwater studies are quite hard and complex for many regions besides consuming time and cost. This study focused on the groundwater potential mapping in Bey?ehir Lake Basin. Mainly, fuzzy-analytic hierarchy process (fuzzy-AHP) integrated with GIS was used to determine potential zones for groundwater. Seven parameters, namely lithology, lineament, drainage density, land use, slope, soil type, and rainfall were evaluated and Groundwater Potential Index (GWPI) was calculated using weight and rating coefficients of each parameter. According to obtained results, GWPI varies from 0.07665 to 0.28243 in the basin. The low, moderate, and high groundwater potential classes were determined with quantile classification method. The groundwater potential map demonstrates that the high groundwater potential area is located around the lake shore, in the alluvium and limestone fields because high permeability rates depend on soil type, low slope, karstic structure, and agricultural activities in these regions. In addition, the distribution of the springs confirms with groundwater potential area determined with this study.  相似文献   

Geochemistry, mineralogy and genesis of pyrophyllite deposits in the Pötürge Region (Malatya, Eastern Turkey)     

F. Öner  A. Taş 《Geochemistry International》2013,51(2):140-154

In the Pötürge (Malatya, Turkey) area pyrophyllite occurrences are common in the shear zones, mostly in the form of lenses along faults. Mineralogical investigations (XRD, FTIR and SEM) revealed that pyrophyllite, kaolinite (dickite) and quartz are present in the form of major phases and muscovite (sericite), kyanite, chlorite, and alunite are only present in the form of minor phases. This study revealed that the existence of the kyanite phase points out to high pressure and temperature conditions which the rocks were underwent. On the other hand, the minerals such as pyrophyllite, kaolinite, and alunite are products of a low degree metamorphism (retrograde). The mineral paragenesis in the pyrophyllite deposits suggests that the formation of minerals took place in two ways: (1) the transformation of kyanite into pyrophyllite and quartz through retrograde metamorphism by a high degree temperature, (2) then pyrophyllite and probably muscovite were transformed into kaolinite and alunite through reactions with relatively low temperature hydrothermal fluids. The geochemical data indicate that during the retrograde metamorphism the elements K, Rb, Sr, Ba, S, and Fe were mobile, the elements Si, Al, P moderately mobile to immobile and the HPS elements (Zr, Ti, and Nb) were immobile. It was shown that the formation of pyrophyllite, kaolinite and alunite was associated with depletion in alkalis, Mg, Fe and enrichment of elements including Sr, Ba, and S. Mineralogical and geochemical data suggest that parent rocks (pre-metamorphism) of the Pötürge pyrophyllite were probably kaolinite, Al-rich clays or bauxites.  相似文献   

Evaluating the anthropogenic and geologic impacts on water quality of the Eğirdir Lake, Turkey     

Şehnaz Şener  Ayşen Davraz  Remzi Karagüzel 《Environmental Earth Sciences》2013,70(6):2527-2544

E?irdir Lake is the second largest fresh water lake with 482 km² surface area of Turkey. The lake is an indispensable water source for our country and region because of available water capacity and usage aims such as drinking-irrigation water, tourism, and fishing. However, especially contaminants located in the E?irdir Lake catchment affect the lake water quality negatively in times. Therefore, determination of the water quality of the lake has quite importance for region human health and sustainable usage of the lake. The major factors that control the quality of the E?irdir Lake water are agricultural activities in the basin, water–rock interaction, and domestic and industrial wastes. This study investigates the anthropogenic and geologic impact originated from pollution sources and water–rock interaction in the lake watershed basin to the E?irdir Lake water quality. For this purpose, geological, hydrogeological, and hydrological properties of the lake basin with point and nonpoint pollution sources were investigated. To determine the water quality of the lake, 48 water samples were collected especially from locations representing effects of pollutants in May and October 2009. The analysis results were compared with maximum permissible limit values recommended by World Health Organization and Turkish drinking water standards. The contents of all chemical and physical parameters are higher in dry periods than wet period, and water pollution was observed at discharge points of the streams into the lake. Also, pH, turbidity, potassium, chemical oxygen demand, ammonium, aluminum, iron, and lead concentrations were found to be above drinking water standards.  相似文献   

Fluid inclusion and sulfur isotope thermometry of the Inkaya (Simav-Kütahya) Cu-Pb-Zn-(Ag) mineralization, NW TURKEY     

Yeşim Özen  Fetullah Arik 《Central European Journal of Geosciences》2013,5(3):435-449

The Inkaya Cu-Pb-Zn-(Ag) mineralization, located about 20 km west of the Simav (Kütahya-Turkey), is situated in the northern part of the Menderes Massif Metamorphics. The mineralization is located along an E-W trending fault in the Cambrian Simav metamorphics consisting of quartz-muscovite schist, quartz-biotite schist, muscovite schist, biotite schist and the Ar?kayas? formation composed of marbles. Mineralized veins are 30–35 cm in width. The primary mineralization is represented by abundant galena, sphalerite, chalcopyrite, pyrite, fahlore and minor amounts of cerussite, anglesite, digenite, enargite, chalcocite, covellite, bornite, limonite, hematite and goethite with gangue quartz. Fluid inclusion studies on the quartz samples collected from the mineralized veins indicate that the temperature range of the fluids is 235°C to 340°C and the salinities are 0.7 to 4.49 wt. % NaCl equivalent. The wide range of homogenization temperatures indicates that two different fluid generations were trapped in quartz. Sulfur isotope studies of the sulfide minerals showed that all of the δ ³⁴S values are between ?2.1 and 2.6 per mil. These values are a typical range for hydrothermal sulfide minerals that have sulfur derived from a magmatic source. Pyrite-galena and pyrite-chalcopyrite sulfur isotope fractionation is consistent with an approach to isotopic equilibrium, and calculated temperatures are 254.6 and 277.4°C for pyrite-galena and 274.7°C for pyrite-chalcopyrite. The microthermometric data and sulfur isotope thermometry indicate the existence of a hydrothermal fluid that circulated along the fault crossing the Simav metamorphics and Ar?kayas? formation. Fluid inclusion and sulfur isotope thermometry can be used in combination with ore petrographical and geological information to provide site-specific targets for meso-hypothermal metal concentrations.  相似文献