The use of Na-smectite clay gels for sealing rock fractures is studied in phase 3 of the Strips project. The rheological properties of these gels and the mathematical formulations necessary to simulate the behaviour are presented in this article, including the breakdown of the structure at small strains as well as the flow behaviour of the vibrated and unvibrated gel.
An important conclusion is that the flow properties of an unvibrated gel do not follow Newton's classical viscosity law, while the shear resistance of the gel affected by vibrations is strongly reduced and the flow behaviour is Newtonian. 相似文献
Perch (Perca fluviatilis), were sampled from unpolluted and polluted areas in Swedish coastal waters. The level of aromatic/hydrophobic DNA adducts in liver tissue was analyzed using the nucleas P1 version of the32P-post-labeling assay. The level of total adducts measured in the individual fish from polluted areas was between 6 and 22 nmol of adducts/mol of nucleotides, and in the fish from the reference area between 0.2 and 0.6 nmol of adducts/mol of nucleotides. 相似文献
The short term (2–40 days) dissolution of enstatite, diopside, and tremolite in aqueous solution at low temperatures (20–60°C) and pH 1–6 has been studied in the laboratory by means of chemical analyses of reacting solutions for Ca2+, Mg2+, and Si(OH)4 and by the use of X-ray photoelectron spectroscopy (XPS) for detecting changes in surface chemistry of the minerals. All three minerals were found to release silica at a constant rate (linear kinetics) providing that ultrafine particles, produced by grinding, were removed initially by HF treatment. All three also underwent incongruent dissolution with preferential release of Ca and/or Mg relative to Si from their outermost surfaces. The preferential release of Ca, but not Mg for diopside at pH 6 was found by both XPS and solution chemistry verifying the theoretical prediction of greater mobility of cations located in M2 structural sites. Loss mainly from M2 sites also explains the degree of preferential loss of Mg from enstatite at pH 6; similar structural arguments apply to the loss of Ca and Mg from the surface of tremolite. In the case of diopside and tremolite initial incongruency was followed by essentially congruent cation-plus-silica dissolution indicating rapid formation of a constant-thickness, cation-depleted surface layer. Cation depletion at elevated temperature and low pH (~ 1) for enstatite and diopside was much greater than at low temperature and neutral pH, and continued reaction resulted in the formation of a surface precipitate of pure silica as indicated by solubility calculations, XPS analyses, and scanning electron microscopy.From XPS results at pH 6, model calculations indicate a cation-depleted altered surface layer of only a few atoms thickness in all three minerals. Also, lack of shifts in XPS peak energies for Si, Ca, and Mg, along with undersaturation of solutions with respect to all known Mg and Ca silicate minerals, suggest that cation depletion results from the substitution of hydrogen ion for Ca2+ and/or Mg2+ in a modified silicate structure and not from the precipitation of a new, radically different surface phase. These results, combined with findings of high activation energies for dissolution, a non-linear dependence on aH+ for silica release from enstatite and diopside, and the occurrence of etch pitting, all point to surface chemical reaction and not bulk diffusion (either in solution or through altered surface layers) as the rate controlling mechanism of iron-free pyroxene and amphibole dissolution at earth surface temperatures. 相似文献
The physical properties of bentonite-based buffer materials for nuclear waste repositories have been investigated by a number of different laboratory tests. These tests have yielded a material model that is valid for conditions close to water saturation and is useful for describing: (a) the stress, strain and volume change behaviour; (b) the pore pressure and flow of water; and (c) the thermal and thermomechanical response.
The material model is based on the Drucker-Prager Plasticity model and a Porous Elastic Model. The effective stress concept and Darcy's law are applied and the swelling/consolidation and thermomechanical processes are coupled according to the separate mechanical properties of the pore water, the solids and the clay skeleton. The model can be used by the finite-element program ABAQUS.
The model has been tested in several laboratory and field verification tests. Comparison between measured and calculated behaviour shows that the general behaviour is described properly and several calculations of different scenarios have been made for the Swedish KBS 3 concept. However, certain processes, like the hysteresis effect at consolidation/swelling, the curved stress-strain relation at shearing, and the curved failure envelope, are not modelled in a perfectly accurate way and an improved material model is proposed here. It combines the behaviour of the Cam-clay model on the wet side with the more relevant plastic behaviour of a modified Drucker-Prager model with a curved failure envelope and the possibility to introduce strain softening after failure.
The paper presents some laboratory results that are the basis of the first model. It also shows the application of the model to finite-element calculations of some laboratory tests. Comparisons between the calculations and measured results expose some disadvantages of the model and a concept for an improved model is suggested. 相似文献
Using the UNFCCC as a basis, and the objectives of estimating soil organic carbon (SOC) changes during the period 1900–2100, a spatially explicit database of climate, land cover and soil texture was compiled for a 262,000 km2 region in semi-arid Sudan. The area is characterized by low input cultivation of millet, sorghum and sesamé combined with livestock grazing. By integrating the database with the CENTURY ecosystem model, we were able to estimate historical, current and future pools of SOC as a function of land management and climate.The SOC (upper 20 cm) decrease from 1900 to 2000 was estimated to be 6·8 Mt and the maximum potential carbon sink (SOC increase) for the period 2000 to 2100 was estimated to be 17 Mt. Cropland and grassland lost 293 and 152 t SOC km−2 respectively whereas the savannahs gained 76 t SOC km−2 from 1900 to 2000. The SOC sequestration scenario simulated during 2000–2100 recovered 94, 84 and 75 t km−2 for cropland, grassland and savannah respectively.In addition to climate and soils, cropping intensity, fallow periods, fire frequency and grazing intensity also influence cropland SOC variation. Grassland and savannah SOC variations depend on grazing intensity and fire return interval. Land management may affect future amounts of SOC in semi-arid areas thereby turning them from sources into sinks of carbon. SOC estimates were reasonably consistent with measurements (r2=0·70, n=13). 相似文献
A global and consistent characterization of land use and land change in urban and suburban environments is crucial for many fundamental social and natural science studies and applications. Presented here is a dense sampling method (DSM) that uses satellite scatterometer data to delineate urban and intraurban areas at a posting scale of about 1 km. DSM results are analyzed together with information on population and housing censuses, with Landsat Enhanced Thematic Mapper Plus (ETM+) imagery, and with Defense Meteorological Satellite Program (DMSP) night-light data. The analyses include Dallas-Fort Worth and Phoenix in the United States, Bogotá in Colombia, Dhaka in Bangladesh, Guangzhou in China, and Quito in Ecuador. Results show that scatterometer signatures correspond to buildings and infrastructures in urban and suburban environments. City extents detected by scatterometer data are significantly smaller than city light extents, but not all urban areas are detectable by the current SeaWinds scatterometer on the QuikSCAT satellite. Core commercial and industrial areas with high buildings and large factories are identified as high-backscatter centers. Data from DSM backscatter and DMSP nighttime lights have a good correlation with population density. However, the correlation relations from the two satellite datasets are different for different cities indicating that they contain complementary information. Together with night-light and census data, DSM and satellite scatterometer data provide new observations to study global urban and suburban environments and their changes. Furthermore, the capability of DSM to identify hydrological channels on the Greenland ice sheet and ecological biomes in central Africa demonstrates that DSM can be used to observe persistent structures in natural environments at a km scale, providing contemporaneous data to study human impacts beyond urban and suburban areas. 相似文献
The hydro-mechanical behaviour of a clay-based buffer material for nuclear waste disposal has been investigated in a laboratory program. In this program, the main focus was on the influence of confinement on water uptake and swelling pressure during suction decrease. The laboratory program and some of the results are presented by Dueck [Dueck, A., 2006. Laboratory results from hydro-mechanical tests on a water unsaturated bentonite. submitted for publication.].
The results from the laboratory tests were used to find a relationship between water content, void ratio, swelling pressure and suction. Two equations for swelling pressure represent the outline of the model.
In the first equation, the swelling pressure developed during water uptake is normalised by a pressure corresponding to the swelling pressure at saturation. This is done in order to be independent of void ratio. A relationship between the normalised swelling pressure and the degree of saturation is suggested.
The second equation describes a relationship between the swelling pressure, the water content and the actual suction (or relative humidity). The equation is based on a thermodynamic relationship and includes the retention curve (i.e. water content vs. suction under free swelling conditions).
The model can be used for a state where two of the four variables; water content, void ratio, swelling pressure and suction are known and can thus be useful to evaluate field measurements and model late stages of the wetting process. An example of an application is given. The equations are mainly based on results from tests with increasing degrees of saturation under constant void ratio but are also suggested for use with increasing void ratio. 相似文献
Recently new values of the lithium formation rate in low energy flares have been reported in the literature. These values are applied to the white light flare phenomenon on the Sun. It is found that the formation rate in the chromosphere is much larger than in the upper photosphere and that the ratio between the time integrated flare created abundance and the initial photospheric abundance is modest in the chromosphere and small in the upper photosphere. The yield of Li6 in the upper photosphere is, however, comparable to the upper limit of Li6 there. 相似文献
