Investigation of phase relations in the (Na,K)AlGeO4 system     

J. Barbier  M. E. Fleet 《Physics and Chemistry of Minerals》1988,16(3):276-285

The phase relations in the (Na,K)AlGeO₄ system have been investigated at atmospheric pressure over the temperature range 700–1100° C by X-ray powder diffraction and electron diffraction/microscopy. Four distinct structure-types occur in this system including the beryllonite, nepheline, kalsilite and KAlGeO₄ types in order of increasing KAlGeO₄ content. In contrast to the (Na,K)Al-SiO₄ system, the nepheline structure is only stable over a narrow composition range around 25 percent K at temperatures above approximately 800° C and transforms reconstructively into the beryllonite structure at lower temperatures. The formation of domain microstructures in some K-rich phases has been directly observed by high-resolution electron microscopy and can be associated with the presence of diffuse scattering in their diffraction patterns. The structural trend observed across the (Na,K)AlGeO₄ series as a function of composition can be rationalized to a large extent in terms of the dependence of the framework topology of these tridymite-derivative structures on the size of the alkali atoms.  相似文献   

Mg4Ga8Ge2O20: A new synthetic analog of the mineral sapphirine     

Jacques Barbier 《Physics and Chemistry of Minerals》1990,17(3):246-252

A new sapphirine-analog, Mg₄Ga₈Ge₂O₂₀, has been identified and characterized in the system MgO-Ga₂O₃-GeO₂ in samples quenched from 1400° C, 1 atm. It crystallizes with a triclinic unit-cell and is isostructural with the mineral sapphirine-1Tc, Mg₄Al₈Si₂O₂₀. It is stable over a broad range of stoichiometry associated with the exchange reaction 2 Ga³⁺ = Mg²⁺ }+Ge⁴⁺. TEM examination shows the common occurrence of polysynthetic twinning and suggests the existence of a high-temperature triclinic→monoclinic transition. The observation of sapphirine/spinel intergrowths is consistent with the structural relationships described previously.  相似文献   

L'évaluation quantitative des anomalies géochimiques en sols résiduels: une aide pour le choix des prospects     

Jean Barbier 《Journal of Geochemical Exploration》1989,32(1-3)

Geochemical soil prospecting is carried out before the drilling stage and is therefore a factor in a decision involving quite considerable expense. Hence the need for accurate assessment of the value of anomalies. Two techniques are proposed here.Surface-content curves of anomalies very clearly reveal characteristics such as the sampling grid, background, top and distribution of values. To make decision-making easier, different curves can be drawn on the same diagram for comparison.A calculation of the amount of metal contained in the anomalous zone expressed in tonnes, as proposed by Solovov, is a very interesting idea. Four examples confirm that for a stable metal (Pb) under surface conditions, the figure obtained is of the same order of magnitude as that for the mineralisation at depth. In other words, geochemical sampling of residual soil could be used to calculate the tonnage per metre of depth, in this case at the level z = 0 in relation to the surface.

Résumé

La prospection géochimique en sol s'effectue avant le stade des forages, c'est donc un élément de décision pour des dépenses non négligeables. Une évaluation correct de l'intérêt des anomalies est donc nécessaire; deux techniques sont proposées.Le tracé de courbes teneurs-surfaces anomales permet une très bonne illustration de caractères tels que maille d'échantillonnage, background, top, répartition des teneurs. Les courbes reportées sur un même graphique peuvent être facilement comparées entre elles, ce qui rend plus aisées les décisions.Un calcul en tonnes du métal contenu dans l'anomalie, comme l'a proposé P.A. Solovov, est d'un grand intérêt. On vérifie sur quatre exemples que pour un métal stable dans les conditions superficielles (Pb), l'ordre de grandeur du chiffre obtenu est bien le même que celui de la minéralisation en profondeur. En d'autres termes, l'échantillonnage géochimique en sol résiduel permettrait le calcul du tonnage au mètre d'approfondissement, en l'occurrence au niveau z = 0 par rapport au sol.L'évaluation quantitative des anomalies géochimiques en sols résiduels, peut done constituer un outil important d'aide à la décision pour choisir les meilleurs prospects.  相似文献   

IGU commission of geography of tourism and leisure     

B. Barbier 《GeoJournal》1984,8(3):289-290

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Influence du Bani sur la variabilité saisonnière et interannuelle de la crue du fleuve Niger dans le delta intérieur au Mali     

Aïda Zaré  Gil Mahé  Jean-Emmanuel Paturel  Bruno Barbier 《水文科学杂志》2017,62(16):2737-2752

Le delta intérieur du fleuve Niger est une zone humide sahélienne dont l’inondation dépend de la pluviométrie des bassins supérieurs du fleuve Niger et de son principal affluent, le Bani. La crise climatique qui a débuté en 1970 a très peu influencé les dates de passage des maximums de crue sur le Niger amont et son principal défluent, le Diaka. L’influence par contre est très forte sur le Bani, à la confluence avec le Niger à Mopti et sur le delta aval avec des dates de passages des maximums plus précoces qu’auparavant. Cela est dû à la faiblesse des superficies inondées au cours des années sèches. Pendant les années humides, l’importance des débordements latéraux ralentit la propagation de la crue avec pour conséquence des dates de passages plus tardives des maximums. Par ailleurs pendant les années humides antérieures à 1970 l’importance des débordements latéraux conférait au delta amont un caractère d’autorégulation par écrêtage des crues au niveau de certaines station.  相似文献   

The present and future role of coastal wetland vegetation in protecting shorelines: answering recent challenges to the paradigm   总被引：2，自引：0，他引：2  

Keryn B. Gedan  Matthew L. Kirwan  Eric Wolanski  Edward B. Barbier  Brian R. Silliman 《Climatic change》2011,106(1):7-29

For more than a century, coastal wetlands have been recognized for their ability to stabilize shorelines and protect coastal communities. However, this paradigm has recently been called into question by small-scale experimental evidence. Here, we conduct a literature review and a small meta-analysis of wave attenuation data, and we find overwhelming evidence in support of established theory. Our review suggests that mangrove and salt marsh vegetation afford context-dependent protection from erosion, storm surge, and potentially small tsunami waves. In biophysical models, field tests, and natural experiments, the presence of wetlands reduces wave heights, property damage, and human deaths. Meta-analysis of wave attenuation by vegetated and unvegetated wetland sites highlights the critical role of vegetation in attenuating waves. Although we find coastal wetland vegetation to be an effective shoreline buffer, wetlands cannot protect shorelines in all locations or scenarios; indeed large-scale regional erosion, river meandering, and large tsunami waves and storm surges can overwhelm the attenuation effect of vegetation. However, due to a nonlinear relationship between wave attenuation and wetland size, even small wetlands afford substantial protection from waves. Combining man-made structures with wetlands in ways that mimic nature is likely to increase coastal protection. Oyster domes, for example, can be used in combination with natural wetlands to protect shorelines and restore critical fishery habitat. Finally, coastal wetland vegetation modifies shorelines in ways (e.g. peat accretion) that increase shoreline integrity over long timescales and thus provides a lasting coastal adaptation measure that can protect shorelines against accelerated sea level rise and more frequent storm inundation. We conclude that the shoreline protection paradigm still stands, but that gaps remain in our knowledge about the mechanistic and context-dependent aspects of shoreline protection.  相似文献   

Superficial geochemical dispersion around sulphide deposits: Some examples in France     

J. Barbier  E. Wilhelm 《Journal of Geochemical Exploration》1978,10(1):1-39

Examination of geochemical exploration data accumulated in France over a period of almost 20 years has led to detailed consideration of the relationship between anomalies and mineral deposits.Geochemical anomalies associated with sulphide mineralizations seem to follow several general rules i.e. Ag and Pb are almost systematically present, As is very frequent, while Cu and Sb may also be present. The behaviour of Zn seems to be controlled by the lithological character of the host rock with anomalies in carbonate media even for occurrences without economic interest and an absence of anomalies in non-carbonate media, even for Zn deposits of considerable size. Moreover, the contents of this element are greatly amplified by contamination from old workings. The abundance (or scarcity) of supergene minerals in the occurrences directly influences the nature of the anomalies. Lead anomalies frequently correspond to the presence of Pb oxides such as pyromorphite while Zn anomalies derive from Zn oxides which are much more common in carbonate media (smithsonite-hydrozincite) than in schistose host rock. High Cu and As contents are most frequently linked to the presence of “ferruginous fragments” (gossans) derived from sulphides. As a general rule, the various geochemical peculiarities or associations encountered in soils are very much similar to those of the oxidized part of the deposits.We are therefore led to assume that, contrary to the usual conceptions, superficial dispersion is basically mechanical and that the anomalies detected near mineralizations are due to the presence in the soils of supergene minerals, gossan microfragments and more or less mineralised rock debris, etc. Mechanical migration of this kind can be explained by the existence in France during the Pleistocene of cold climates of the tundra type with associated permafrost. The thawing in summer of the superficial part of the frozen overburden resulted in massive downslope solifluction favoring mechanical migration over distances in the order of 100 m and contributing to the surface dispersal of the mineralizations. These phenomena are extremely important for geochemical exploration because they allow and justify the use of large grids (200 m × 200 m or even 400 m × 400 m) during soil surveys at least at the initial stage of prospecting on areas of several square kilometers.These conclusions are valid not only for France but for all regions with the same paleoclimate. These form a belt bounded to the north by glacial formations linked to ancient inland ice and to the south by the maximum extension of Pleistocene permafrost, including, in particular, the north of the United States and Central Europe. This paleo-climate belt characterized by traces of solifluction constitutes a well-defined unit in which geochemical prospecting has proved itself extremely effective.  相似文献   

Altitude et géochimie des eaux de source,Nord-Ouest du Massif central,France     

Jean Barbier 《Comptes Rendus Geoscience》2005,337(8):763-768

In the northwestern Massif Central (France), groundwater chloride concentrations are inversely correlated with elevation, when nitrate-poor. This can be explained by an evolution of the ratio evapotranspiration/rainfall, or of the rainwater composition. Such a relationship may be used for the detection of denitrification phenomena in groundwaters, or nitrate assimilation in surface waters, or for the computation of evapotranspiration, using the chloride mass balance method. However, the main objective will be the selection of groundwaters free of any chloride-bearing contamination, in order to define the natural groundwater quality background. To cite this article: J. Barbier, C. R. Geoscience 337 (2005).  相似文献   

Zonalités géochimiques et métallogèniques dans le massif de Saint-Sylvestre (Limousin-France)     

J. Barbier 《Mineralium Deposita》1970,5(2):145-156

Résumé Le granite à deux micas de St-Sylvestre présente une succession de faciès que l'on peut attribuer à une zonalité verticale. D'une part, passant graduellement à un ensemble de granite à sillimanite et de granite à andalousite, un faciès non albitisé à albite-oligoclase et muscovite automorphe, riche en K, Fe, Ti, Ca, Ba, Sr, contenant de nombreuses pegmatites potassiques; d'autre part, plusieurs faciès albitisés à plus forte teneur en Si, Na, Sn, Be, Cu, probablement Rb, accompagnés de pegmatites sodolithiques ainsi que de filons quartzeux à wolfram-cassitérite. Les faciès pétrographiques et les minéralisations contemporaines se seraient surimposés à un fond géochimique antérieur, les pegmatites notamment exacerbant les particularités locales du granite.

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About zonality of granitic facies, of geochemistry, and of some mineralisations in the St-Sylvestre massif (Limousin-French Massif Central). The St-Sylvestre two micas granite shows a succession of facies supposedly coming from a vertical zonality: i. e. gradually changing into sillimanite and into andalousite granitic bodies, an unalbitized facies with albite-oligoclase, automorphic muscovite, rich in K, Fe, Ti, Ca, Ba, Sr, witch contains numerous potassic pegmatites, on one hand; and several albitized facies high in Si, Na, Sn, Be, Cu, and probably Rb, along with some sodolithic pegmatites and some quartz filons containing wolfram-cassiterite mineralisations. The petrographic facies and the contemporaceous mineralisations may be the product of a late superimposition to a previous geochemical background, pegmatites being an exaggerated result from local particularities of granite.

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Spinelloid phases in the nickel gallosilicate system     

R. Hammond  J. Barbier 《Physics and Chemistry of Minerals》1991,18(3):184-190

The phase diagram of the NiO-Ga₂O₃- SiO₂ system has been investigated at high temperatures (up to 1550° C) and 1 atm. pressure. The only ternary phases observed in this system are the spinelloid phases I, II, and V, forming on the NiGa₂O₄-Ni₂SiO₄ pseudo-binary join at temperatures above 1400° C. Our results show that phase V is stable at higher temperature than phase I, while phase II may be metastable. The stability of phases I and V has been confirmed by the successful growth of single crystals from a silica-rich flux. Phases I, II, and V have been characterized by powder X-ray diffraction and transmission electron microscopy. The dimensions of their orthorhombic unit-cells are: (I) a= 5.7741(5), b=11.712(1), c=8.2387(9) Å; (II) a= 5.765(1), b= 17.619(3), c= 8.238(2) Å; (V) a= 5.7914(4), b=8.7809(7), c=8.2346(6) Å. High resolution electron microscopy has also revealed the formation of microscopic intergrowths similar to those previously observed for the spinelloid phases of the NiO-Al₂O₃-SiO₂ system.  相似文献