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101.
Study of 10 volatile elements (and non-volatile Co) in co-existing light and dark portions of 5 gas-rich chondrites indicates patterns of distinct but non-uniform enrichment of volatile elements. Only Cs is enriched in all samples; Hi and Tl enrichments covary. The observed enrichments are inconsistent with prior suggestions of admixture of C1 or C2 chondritic matter, whether pristine or partly devolatilized, but suggest that both light and dark portions of each chondrite represents a compositionally more extended sampling of parental nebular material than hitherto known. 相似文献
102.
103.
Steven D. Bussey Paul M. Taufen Bart J. Suchomel Malcolm Ward 《Journal of Geochemical Exploration》1993,47(1-3)
The Bell Springs deposit is a bulk-tonnage, low-grade gold deposit, formed in a hot-spring environment, that is hosted by middle Miocene weakly peralkaline, high-silica rhyolite ash flows and rheomorphic tuffs. Ore grade mineralization over about 460 × 460 m was controlled by northeast- and northwest-trending structures. Sixty-nine soil samples collected along a traverse across the Bell Springs deposit, screened into six mesh size fractions, +10, −10+35, −35+80, −80+120, −120+200, and −200, were treated by low-detection-limit acid digestion/organic extraction procedures, and analyzed by ICP or graphite furnace techniques for Au, Ag, As, Bi, Cd, Cu, Ga, Hg, Mo, Pb, Sb, Se, Te, Tl, and Zn. Twenty-five stream-sediment samples were collected from a drainage crossing mineralization and from a nearby tributary. Sediment size fractions of −200 mesh and −10+200 mesh were analyzed by the same procedures used for soils. In addition, analyses of bulk leachable gold via cyanide leach method (BLEG) was done on bulk −10 mesh sediments.Anomalous Au, Ag, As, Sb, and Mo in all soil size fractions revealed the underlying ore. Areas with anomalous Sb and As were about three times larger than areas with anomalous Au and Ag. Analyses of fine-fractions of stream sediments provided the best-defined Au anomalies in drainages. A multi-element factor calculated by multiplying Au, As, Sb, and Mo reinforced anomalous Au in drainages and correlated well with Bell Springs mineralization. 相似文献
104.
Stabilizing greenhouse gas concentrations at low levels: an assessment of reduction strategies and costs 总被引：2，自引：8，他引：2
Detlef P. van Vuuren Michel G. J. den Elzen Paul L. Lucas Bas Eickhout Bart J. Strengers Bas van Ruijven Steven Wonink Roy van Houdt 《Climatic change》2007,81(2):119-159
On the basis of the IPCC B2, A1b and B1 baseline scenarios, mitigation scenarios were developed that stabilize greenhouse
gas concentrations at 650, 550 and 450 and – subject to specific assumptions – 400 ppm CO2-eq. The analysis takes into account a large number of reduction options, such as reductions of non-CO2 gases, carbon plantations and measures in the energy system. The study shows stabilization as low as 450 ppm CO2-eq. to be technically feasible, even given relatively high baseline scenarios. To achieve these lower concentration levels,
global emissions need to peak within the first two decades. The net present value of abatement costs for the B2 baseline scenario
(a medium scenario) increases from 0.2% of cumulative GDP to 1.1% as the shift is made from 650 to 450 ppm. On the other hand,
the probability of meeting a two-degree target increases from 0%–10% to 20%–70%. The mitigation scenarios lead to lower emissions
of regional air pollutants but also to increased land use. The uncertainty in the cost estimates is at least in the order
of 50%, with the most important uncertainties including land-use emissions, the potential for bio-energy and the contribution
of energy efficiency. Furthermore, creating the right socio-economic and political conditions for mitigation is more important
than any of the technical constraints. 相似文献
105.
Talebi Hassan Mueller Ute Peeters Luk J. M. Otto Alex de Caritat Patrice Tolosana-Delgado Raimon van den Boogaart K. Gerald 《Mathematical Geosciences》2022,54(3):593-621
Mathematical Geosciences - Mineral deposits are metal enrichment anomalies, occurring as local manifestations of the interplay between various geological processes that operate at a wide range of... 相似文献
106.
In solution thermodynamics, and more recently in surface chemistry, it is well established that relationships can be found between the free energies of formation of aqueous or surface metal complexes and thermodynamic properties of the metal ions or ligands. Such systematic dependencies are commonly termed linear free energy relationships (LFER). A 2 site protolysis non-electrostatic surface complexation and cation exchange (2SPNE SC/CE) model has been used to model “in house” and literature sorption edge data for eleven elements: Mn(II), Co(II), Ni(II), Zn(II), Cd(II), Eu(III), Am(III), Sn(IV), Th(IV), Np(V) and U(VI) to provide surface complexation constants for the strong sites on montmorillonite. Modelling a further 4 sets of sorption isotherms for Ni(II), Zn(II), Eu(III) and U(VI) provided complexation constants for the weak sites. The protolysis constants and site capacities derived for the 2SPNE SC/CE model in previous work were fixed in all of the calculations. Cation exchange was modelled simultaneously to provide selectivity coefficients. Good correlations between the logarithms of strong SKx−1 and weak W1Kx−1 site binding constants on montmorillonite and the logarithm of the aqueous hydrolysis constants OHKx were found which could be described by the following equations: Strong (≡SSOH) sites:
SlogKX−1=8.1±0.3+(0.90±0.02)logOHKX 相似文献
107.
Earlier studies suggest that once population growth and market integration reach a certain critical level, traditional practices of work sharing tend to degenerate or disappear altogether. Work sharing has, however, survived to date in small-scale fisheries in Kerala, India. Artisanal fishermen strongly favor the system, for ethical reasons as well as for their personal benefit. Besides, boat owners appear not to be hindered by the system. Contrary to observations in crop production, work sharing has not inhibited the introduction of modern technologies like motorization. 相似文献
108.
Effective governance for competitive regions in Europe: the difficult case of the Randstad 总被引：1，自引：0，他引：1
Europe has come to recognize that its regions have a major role to play in achieving its cohesion and competitiveness objectives. EU policies and Structural Fund principles are therefore increasingly geared towards enhancing regional capacities. Regions across Europe are responding, with varying results so far. The Randstad, in the Netherlands, presents itself as a ‘far from best’ example. Despite continued and serious attempts to strengthen capacities and institutions, the region still lacks effective governance. This paper explores the question why it is next to impossible to establish a framework for effective governance in the Randstad and distils some lessons for other regions in Europe. 相似文献
109.
Bart E. van Dongen Helen A.L. Rowland Andrew G. Gault David A. Polya Charlotte Bryant Richard D. Pancost 《Applied Geochemistry》2008
The presence of elevated As in ground waters exploited for drinking water and irrigation in South-East Asia is causing serious impacts on human health. A key mechanism that causes the mobilization of As in these waters is microbially mediated reductive transformation of As-bearing Fe(III) hydrated oxides and the role of degradable organic matter (OM) in this process is widely recognized. A number of different types of OM that drive As release in these aquifers have been suggested, including petroleum derived hydrocarbons naturally seeping into shallow sediments from deeper thermally mature source rocks. However, the amount of information on the characteristics of the OM in South-East Asian aquifers is limited. Here the organic geochemical analyses of the saturated hydrocarbon fractions and radiocarbon analysis, of two additional sites in SE Asia are reported. The results show that the OM in a given sedimentary horizon likely derives from multiple sources including naturally occurring petroleum. The importance of naturally occurring petroleum as one of the sources was clearly indicated by the n-alkane CPI of approximately 1, the presence of an unresolved complex mixture, and hopane (dominated by 17α(H),21β(H) hopanes) and sterane distribution patterns. The results also indicate that the OM in these aquifers varies tremendously in content, character and potential bioavailability. Furthermore, the presence of petroleum derived OM in sediments at both sites doubles the number of locations where their presence has been observed in association with As-rich, shallow aquifers, suggesting that the role of petroleum derived OM in microbially mediated As release might occur over a wider range of geographical locations than previously thought. 相似文献
110.
A new anisotropic poroelastic damage model is proposed for saturated brittle porous materials. The model is formulated in the framework of the continuum damage mechanics. A second‐rank symmetric tensor is used to characterize material damage due to oriented microcracks. The classic Biot poroelastic theory is then extended to include poroelastic damage coupling. Both the deterioration of elastic properties and poroelastic coefficients is taken into account. A suitable procedure for determination of model parameters from standard laboratory tests is presented. The validity of the model is tested through comparison between numerical predictions and experimental data in various loading conditions. The overall performance of the model is evaluated. The choice of relevant effective stress for the microcrack propagation criterion in saturated cohesive geomaterials is discussed. Copyright © 2000 John Wiley & Sons, Ltd. 相似文献