Preface to stable isotopes in hydrological studies in the tropics: Ecohydrological perspectives in a changing climate     

Ricardo Snchez‐Murillo  Ana M. Durn‐Quesada 《水文研究》2019,33(16):2160-2165

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Spatially distributed tracer‐aided modelling to explore water and isotope transport,storage and mixing in a pristine,humid tropical catchment          下载免费PDF全文

Joni Dehaspe  Christian Birkel  Doerthe Tetzlaff  Ricardo Sánchez‐Murillo  Ana María Durán‐Quesada  Chris Soulsby 《水文研究》2018,32(21):3206-3224

Rapidly transforming headwater catchments in the humid tropics provide important resources for drinking water, irrigation, hydropower, and ecosystem connectivity. However, such resources for downstream use remain unstudied. To improve understanding of the behaviour and influence of pristine rainforests on water and tracer fluxes, we adapted the relatively parsimonious, spatially distributed tracer‐aided rainfall–runoff (STARR) model using event‐based stable isotope data for the 3.2‐km² San Lorencito catchment in Costa Rica. STARR was used to simulate rainforest interception of water and stable isotopes, which showed a significant isotopic enrichment in throughfall compared with gross rainfall. Acceptable concurrent simulations of discharge (Kling–Gupta efficiency [KGE] ~0.8) and stable isotopes in stream water (KGE ~0.6) at high spatial (10 m) and temporal (hourly) resolution indicated a rapidly responding system. Around 90% of average annual streamflow (2,099 mm) was composed of quick, near‐surface runoff components, whereas only ~10% originated from groundwater in deeper layers. Simulated actual evapotranspiration (ET) from interception and soil storage were low (~420 mm/year) due to high relative humidity (average 96%) and cloud cover limiting radiation inputs. Modelling suggested a highly variable groundwater storage (~10 to 500 mm) in this steep, fractured volcanic catchment that sustains dry season baseflows. This groundwater is concentrated in riparian areas as an alluvial–colluvial aquifer connected to the stream. This was supported by rainfall–runoff isotope simulations, showing a “flashy” stream response to rainfall with only a moderate damping effect and a constant isotope signature from deeper groundwater (~400‐mm additional mixing volume) during baseflow. The work serves as a first attempt to apply a spatially distributed tracer‐aided model to a tropical rainforest environment exploring the hydrological functioning of a steep, fractured‐volcanic catchment. We also highlight limitations and propose a roadmap for future data collection and spatially distributed tracer‐aided model development in tropical headwater catchments.  相似文献   

Magnetic properties as indicators of pedogenic and pyrogenic processes at the Upper Paleolithic site of Kostenki 14     

Anastasiia Kurgaeva  Sergey Sedov  Sol Moreno-Roso  Hermenegildo Barceinas Cruz  Beatriz Ortega Guerrero  Elizabeth Solleiro-Rebolledo  Andrei Sinitsyn 《Geoarchaeology》2024,39(2):143-167

In geoarchaeological studies, there is an issue with distinguishing between natural and anthropogenic signals in pedological paleoarchives. With the pedostratigraphy of the Upper Paleolithic site of Kostenki 14, this issue is reflected by problems with the determination of features of pedogenic and pyrogenic processes. This issue was addressed by means of a thorough analysis of the magnetic properties of paleosols accompanied by micromorphological observations. Most of the humic samples were shown to be a result of pedogenesis, but two samples (a Paleolithic hearth sample and a sample from paleosol IIc) had features of intensely burnt material. The difference in the typical intensity of large-scale (natural or human-induced) and local-scale anthropogenic fire allowed for suggesting that the magnetic properties of the burnt sample were the result of an anthropogenically controlled fire event, that is, a hearth. This study shows that the magnetic properties of paleosols can be used to differentiate anthropogenic activity, in particular—burning, from pedogenic processes. This indicator is especially helpful in finding disturbed combustion features when the hearth structure is lost. This methodology used to demonstrate the local human-induced pyrogenic effect at the Upper Paleolithic site can contribute to the discussion of the niche construction effect of human activities in the Pleistocene.  相似文献   

Biocrust landscape-scale spatial distribution is strongly controlled by terrain attributes: Topographic thresholds for colonization in a semiarid badland system     

Emilio Rodríguez-Caballero  José Raúl Román  Sonia Chamizo  Beatriz Roncero Ramos  Yolanda Cantón 《地球表面变化过程与地形》2019,44(14):2771-2779

Biological soil crust, or biocrust communities, are the dominating life form in many extreme habitats, such as arid and semiarid badlands, where water scarcity and highly erodible substrates limit vegetation cover. While climate, soil and biotic factors have been described as environmental filters influencing biocrust distribution in such biomes, little is known about the effect of terrain attributes on creating specific microhabitats that promote or restrict biocrust colonization. This study aimed to identify the main terrain attributes controlling biocrust distribution in the driest badland system in Europe, the Tabernas Badlands (SE Spain). To do this, we analysed the influence of different terrain attributes related to landscape stability and microclimate formation on the spatial distribution of lichen and cyanobacteria, using field measurements and topographical information from a LiDAR survey. Our results showed that the spatial distribution of cyanobacteria-dominated biocrusts, which are physiologically and morphologically adapted to extreme drought and high UVA radiation, was mostly associated with areas of high potential incoming solar radiation. The exception was bare south-aspect hillslopes with very high sediment transport potential, where bare physically crusted soils were the dominant ground cover. Lichen-dominated biocrusts, in contrast, colonized near the top of north-aspect hillslopes, characterized by low potential incoming solar radiation and potential evapotranspiration, and their cover decreased downstream, as conditions became good enough for vascular plants. © 2019 John Wiley & Sons, Ltd. © 2019 John Wiley & Sons, Ltd.  相似文献   

Optimization of dissolved urea measurements in coastal waters with the combination of a single reagent and high temperature     

Md. Shafiul Alam  Beatriz E. Casareto  Yoshimi Suzuki  Rumana Sultana  Toshiyuki Suzuki 《Journal of Oceanography》2017,73(2):249-258

Urea is an unstable and intermediate organic nitrogenous compound present in coastal environments and is derived from the excretion of some aquatic organisms and wastewater discharges. Urea plays an important role in the nitrogen cycle, where it is utilized by algae, including diatoms. However, there are very limited relevant data on the production, consumption, and degradation of urea because of the lack of appropriate measurement techniques. The conventional method is based on the formation of a colored product when urea reacts with diacetyl monoxime in a sulfuric acid solution. We examined the optimal conditions for the formation of the colored product; specifically, we evaluated different temperatures (22–80 °C), reaction times, mixing ratios of color reagents, and sample storage times. Application of the single mixed color-developing reagent (COLDER) at 70 °C resulted in the optimal formation of the colored product within a short reaction time of 60 min. This method was then used to measure dissolved urea in different coastal environments. The concentrations detected were as follows: 0.65–0.72, 0.49–0.58, and 1.09–2.28 µM urea-N at coral reef, seagrass, and mangrove sites, respectively. Our results showed high precision (SD = 0.02, CV = 1.2%), a low detection limit (0.03 µM urea-N), and a high recovery rate (94–99%). In summary, this high-temperature procedure for urea measurements should be valuable for obtaining high-precision data that can further the understanding of urea dynamics and its role in coastal ecosystems.  相似文献   

Foraminifera as indicators of marine pollutant contamination on the inner continental shelf of southern Brazil   总被引：1，自引：0，他引：1  

Eichler PP  Eichler BB  Gupta BS  Rodrigues AR 《Marine pollution bulletin》2012,64(1):22-30

Analyses of living foraminiferal and environmental parameters near an outfall at Mar Grosso Beach (Laguna, SC, Brazil) demonstrate its usefulness as indicators of domestic sewage pollution. The low species diversity may be due to sand accumulation in the central part. Higher diversity was noted closer to the mouth of Laguna estuarine system where reduced salinity and higher temperatures indicate freshwater influence, suggesting a relationship between increased diversity and greater availability of terrestrial food. On the basis of foraminiferal diversity and average coliform count the higher values are closer to the mouth of the estuarine system and under the influence of the outfall. Due to the effect of local hydrodynamics, the particulate organic waste derived from the outfall does not settle down locally, and thus, do not accumulate nearby. Our hypothesis is that the fine material derived from the outfall is accumulating on the southwestern and northwestern parts of the beach.  相似文献   

Distinguishing the Regional Atmospheric Controls on Precipitation Isotopic Variability in the Central-Southeast Portion of Brazil     

Vinícius dos SANTOS  Peter MARSHALL FLEMING  Luís HENRIQUE MANCINI  Stela DALVA SANTOS COTA  Graziele Beatriz de LIMA  Rafaela RODRIGUES GOMES  Roberto Eduardo KIRCHHEIM  Ricardo SANCHéZ-MURILLO  Didier GASTMANS 《大气科学进展》2022,39(10):1693-1708

Precipitation isotope ratios (O and H) record the history of water phase transitions and fractionation processes during moisture transport and rainfall formation. Here, we evaluated the isotopic composition of precipitation over the central-southeastern region of Brazil at different timescales. Monthly isotopic compositions were associated with classical effects (rainfall amount, seasonality, and continentality), demonstrating the importance of vapor recirculation processes and different regional atmospheric systems (South American Convergence Zone-SACZ and Cold Fronts-CF). While moisture recycling and regional atmospheric processes may also be observed on a daily timescale, classical effects such as the amount effect were not strongly correlated (δ¹⁸O-precipitation rate r ≤ –0.37). Daily variability revealed specific climatic features, such as δ¹⁸O depleted values (~ –6‰ to –8‰) during the wet season were associated with strong convective activity and large moisture availability. Daily isotopic analysis revealed the role of different moisture sources and transport effects. Isotope ratios combined with d-excess explain how atmospheric recirculation processes interact with convective activity during rainfall formation processes. Our findings provide a new understanding of rainfall sampling timescales and highlight the importance of water isotopes to decipher key hydrometeorological processes in a complex spatial and temporal context in central-southeastern Brazil.  相似文献   

Occurrence of perfluorinated compounds in water, sediment and mussels from the Cantabrian Sea (North Spain)   总被引：1，自引：0，他引：1  

Gómez C  Vicente J  Echavarri-Erasun B  Porte C  Lacorte S 《Marine pollution bulletin》2011,62(5):948-955

Perfluorinated compounds (PFCs) have emerged as significant global environmental pollutants with persistent, bioaccumulative and toxic properties. The aim of this study was to determine the occurrence of PFCs in water (wastewater, submarine emissaries and port-waters), sediment and transplanted mussels in estuarine areas of high urban and industrial impact from Northern Spain. Five PFCs of industrial use were studied: perfluorooctanesulfonate, perfluorohexanesulfonate, perfluorobutanesulfonate, perfluorooctanoate acid and perfluorononanoate acid. After selective extraction, samples were analyzed by Ultra Performance Liquid Chromatography coupled to tandem mass spectrometry. ΣPFCs ranged from 0.06 to 10.9 ng/L in water, with higher levels in wastewater treatment plants effluents and port waters than in submarine emissaries. Little accumulation was observed in sediments and mussels with ΣPFCs ranging from 0.01-0.13 ng/g dw and 0.01-0.06 ng/g ww, respectively. Most ubiquitous compounds were PFOS and PFOA. Mass fluxes of PFCs to the Cantabrian Sea are estimated and the impact to the coastal ecosystem is discussed.  相似文献   

Geological evolution of the West Luzon Basin (South China Sea,Philippines)     

Jashar?ArfaiEmail author  Dieter?Franke  Christoph?Gaedicke  Rüdiger?Lutz  Michael?Schnabel  Stefan?Ladage  Kai?Berglar  Mario?Aurelio  Jennie?Montano  Nicole?Pellejera 《Marine Geophysical Researches》2011,32(3):349-362

Interpretation of deep 2-D multi-channel seismic data sheds insights into the geological evolution of the West Luzon Basin, Philippines. This basin is a sediment-filled trough that is located between the island of Luzon and the outer arc high of the west Luzon subduction zone. High-amplitude, low-frequency reflection bands mark the acoustic basement. The basement, at about 6 s (TWT), is dissected by normal faults with some of them being inverted in a later phase of deformation. The sedimentary successions, overlying the basement are stratified with partly chaotic structures and discontinuous reflectors. Five regional unconformities separate major stratigraphic units. Grid calculations of our seismic data reveal variations in the sedimentation pattern of the basin with a shift of the deposition centre from east to west and backwards during formation. A distinct bottom-simulating reflector is commonly observed. Because the northern boundary of the continental fragments to the South of the West Luzon Basin is unclear we speculate that the basin may be (partly) underlain by continental crust. The continental crust was affected by rifting prior to and during the opening of the South China Sea and the basin was overprinted at a later stage by a forearc structural setting when subduction was initiated.  相似文献   

The continent-ocean transition at the southeastern margin of the South China Sea   总被引：2，自引：0，他引：2  

D. Franke  U. BarckhausenN. Baristeas  M. EngelsS. Ladage  R. LutzJ. Montano  N. PellejeraE.G. Ramos  M. Schnabel 《Marine and Petroleum Geology》2011,28(6):1187-1204

The South China Sea formed by magma-poor, or intermediate volcanic rifting in the Paleogene. We investigate the structure of the continent-ocean transition (COT) at its southern margin, off NW Palawan between the continental blocks of Reed Bank and the islands of Palawan and Calamian. Several surveys, recorded by the BGR from 1979 to 2008, established a comprehensive database of regional seismic lines, accompanied with magnetic and gravity profiles.We interpret two major rifted basins, extending in the NE direction across the shelf and slope, separated by a structural high of non volcanic origin.The continent-ocean transition is interpreted at the seaward limit of the continental crust, when magnetic spreading anomalies terminate some 80-100 km farther north. The area in between displays extensive volcanism - as manifest by extrusions that occasionally reach and cut the seafloor, by dykes, and by presumed basaltic lava flows - occurring after break-up.The COT is highly variable along the NW Palawan slope: One type shows a distinct outer ridge at the COT with a steep modern seafloor relief. The other type is characterised by rotated fault blocks, bounded by listric normal faults ramping down to a common detachment surface. Half-grabens developed above a strongly eroded pre-rift basement. The seafloor relief is smooth across this other type of COT.We suggest the pre-rift lithospheric configuration had major influence on the formation of the COT, besides transfer zones. Volcanic domains, confined to the north of competent crustal blocks correlate with the style of the COT.Gravity modelling revealed an extremely thinned crust across the shelf. We propose a depth-dependent extension model with crust being decoupled from mantle lithosphere, explaining the discrepancy of subsidence observed across the South China Sea region.  相似文献