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21.
Coalbed methane (CBM) is a worldwide exploration target of the petroleum industry. In Brazil, the most important coal-bearing succession is associated with the Permian Rio Bonito Formation of the Paraná Basin. The gas-prone areas are located at the southeastern margin of the Paraná Basin and possibly in the offshore region of the northern part of the Pelotas Basin. Coalfields end abruptly at the present day shoreline, a result of rifting of Gondwana and the evolution of the South Atlantic Ocean. All geologic indicators suggest that in pre-rift times the coal seams extended further eastwards, probably now lying deeply buried below the sedimentary succession of the Pelotas Basin. The present paper discusses structural, stratigraphic, seismic and aeromagenetic data that support the preservation of continental crust beneath ocean sediment. If the coal beds had similar lateral extent to known onshore coals, and coal beds extended across the projected extension of the Parana basin, and there was a conservative 5 m of cumulative coal thickness, then a potential methane volume can be estimated for this newly inferred resource. Average onshore coal gas content is 32 scf/ton (1.00 m3/ton). If this is similar in the offshore coal deposits, then the hypothetical methane volume in the offshore area could be in excess of 1.9 × 1012 scf (56 × 109 m3). Metamorphism from dikes associated with rifting are potential complicating factors in these deposits, and since no borehole reaching the deep-lying strata in the offshore area are available, this is a hypothetical gas resource with a certain level of uncertainty which should be tested in the future by drilling a deep borehole.  相似文献   
22.
207Pb/206Pb ages from 420 zircons from 9 upper amphibolite and granulite facies quartzites of the post-1.8 Ga metasedimentary cover from the Occidental and Oriental terranes from the Neoproterozoic central Ribeira belt, in eastern Brazil, are discussed. Ages from the Occidental terrane show that Proterozoic ages predominate with a modal class at 2.1–2.2 Ga and that Archean ages are less common and lie within the 2.5–3.6 Ga range. A wider dispersion on Proterozoic ages down to 1.1 Ga and youngest Neoproterozoic ages (550–700 Ma) were also observed and could be related to the Brasiliano/PanAfrican metamorphic events. The data show that detrital sediments of the Occidental terrane were derived predominantly from erosion of a 1.8–2.2 Ga Paleoproterozoic terrane with a small proportion of a 2.6–3.6 Ga Archean crust. Ages from the Oriental terrane are greatly dispersed, but show a significant proportion of ages between 1.7 and 2.1 Ga, although the great majority are between 0.5 and 1.6 Ga. Only 3 out of 144 grains yield Archean ages, between 2.5 and 2.9 Ga. Based on the greatest errors observed on the data from the Oriental Terrane (100–300 Ma), and a continuum of obtained ages between 2072 Ma (Paleoproterozoic) and 517 Ma (Cambrian), the more plausible interpretation is that the dispersion of ages results from partial resetting of the U–Pb system by Brasiliano metamorphism in Proterozoic–Archean zircons, although a Mesoproterozoic source could not be discarded.  相似文献   
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In the last 20 years the Canary Islands fishing fleet has gone from the privileged position of enjoying abundant catches in the old “Canary Islands-Saharan” fishing grounds to the precarious situation in which it currently finds itself. This paper aims to determine what the future holds for The Canaries fishing sector. Hence, fishing rights and policies are analysed and the special aids received from the EC are compared with those applied in other similar ultraperipheric regions. The adoption of a more interventionist role by the Canary Islands administration may solve at least part of the problem faced by this sector.  相似文献   
25.
Sex‐specific interactions involving competition for space between the dioecious alcyonacean soft coral Sarcophyton glaucum and the scleractinian coral Acropora robusta were assessed experimentally on Bald Rock, central region of the Great Barrier Reef. To examine this, plus inter‐clonal responses, one male colony of S. glaucum, known to produce sarcophytoxide as its predominant complementary (secondary) metabolite, was sectioned, producing 10 clones. The same was done for a female colony. These two sets of clones were then relocated to grids and placed in contact with Acropora clones. Relocated and non‐relocated controls were also monitored. High levels of tissue necrosis were observed in the hard coral under contact conditions with both the male and female clones after 20 days. The development of a protective polysaccharide layer in the alcyonacean was also observed. Differences observed in the concentrations of complementary metabolites within the two different S. glaucum colonies were related to sex. Both under competition and non‐competition conditions, females exhibited significantly higher concentrations of sarcophytoxide than males, and this increased with time. Fatty ester concentration was also higher in females than males, varying significantly through time, and falling dramatically just after spawning. Fatty ester concentrations decreased linearly through time in the male clones. When involved in competition for space, females possessed higher concentrations of fatty esters than males, both at the site of contact and in non‐contact sites, again, decreasing after spawning. No significant changes in sarcophytoxide levels were noted in the parental colonies, but such changes were observed in fatty esters, with the female producing higher concentrations until after spawning. The use of these two variates in the form of a ratio (sarcophytoxide concentration:fatty ester concentration) yielded a variable Rho (ρ) which was a more sensitive indicator of biochemical change than either of its components alone. These two sets of compounds appeared to have a negative association through time and varied highly significantly between sexes. The diterpene sarcophytoxide may be considered an allelopathic or stress metabolite, while the lipids act as energy storage metabolites.  相似文献   
26.
The church of Santa María del Naranco is an important monument from the pre‐Romanesque period of Asturian art. Here we present research that locates the probable source of travertine used in the construction of a vault within this monument. Since the genesis of this travertine is associated with spring activity, and archival evidence suggests that stone procurement during this period tended to be local, we surveyed existing carbonated aquifers within a 5‐km radius of the monument. We identified a spring (Sopeña) with an associated outcrop of discontinuous travertine that appeared to have been quarried in the past. We conducted X‐ray powder diffraction, electron microprobe, and inductively coupled plasma mass spectrometry analyses of samples extracted from the suspected travertine source, an additional more distant travertine quarry for comparison, and the vault. Matching mineralogy and geochemistry indicate that the Sopeña travertine was the probable source of rock material used in the construction of the vault. This study provides insight into local ancient monument construction and can assist in procuring original stone material for historical restoration. © 2010 Wiley Periodicals, Inc.  相似文献   
27.
The diagenetic overprint in rhythmic hemipelagic successions can either enhance or change the original distribution of CaCO3, but it is difficult to evaluate its effect because in most field examples, it is not possible to distinguish between sedimentary and diagenetic features. The rhythmic succession of the Pliensbachian of Asturias (Spain) shows alternation of bioclastic and laminated/burrowed intervals. The original content of carbonate brought by storms from shallow areas was larger in the bioclastic horizons. However, there is a widespread mismatch between facies alternations and the observed lithological rhythms. The diagenetic redistribution of CaCO3 resulted in successive limestone–marl/clay couplets that do not match (either in number or in the location of the boundaries) the sedimentary cycles defined by facies alternations. We conclude that interpreting the limestone–marl rhythms as a direct response to primary changes is highly questionable, unless there is unequivocal proof of a sedimentary origin of the alternation of the two lithologies.  相似文献   
28.
The effect of larval and juvenile predation ofGalaxias maculatus on a natural small-sized zooplankton was studied in a South Andes lake. Field data of zooplankton density and composition were combined with fish gut content analysis during a spring-summer season. Results showed thatGalaxias early stages ingested mostly planktonic preys. A shift was observed in prey electivity: larvae preferred copepod nauplii whereas juveniles preferred cladocerans. Larval predation provokes the failure of the summer cohort of the calanoid copepodBoeckella gracilipes. The effect of juveniles is more undefined, but seems to prevent the reappearance ofCeriodaphnia in the summer plankton.  相似文献   
29.
Stratigraphical-structural units separated by regional unconformities in the Andes of Peru and Chile, display a pattern of low grade burial metamorphism. Each stratigraphical-structural unit shows a particular facies series covering part or all the range between the zeolite and the greenschist facies. These facies series were episodically generated as part of the geological evolution of each unit prior to its own folding. Mineralogical breaks are found to coincide with the regional unconformities and often cases of higher grade assemblages on top of lower grade ones occur. This pattern may be explained by a process of sealing of each unit after its particular metamorphic episode took place. Porosity and permeability conditioning P f, as demonstrated for individual lava flows, are the significant controlling factors in the production of the metamorphic assemblages.  相似文献   
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