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41.
Fitting the Linear Model of Coregionalization by Generalized Least Squares   总被引:2,自引:0,他引:2  
In geostatistical studies, the fitting of the linear model of coregionalization (LMC) to direct and cross experimental semivariograms is usually performed with a weighted least-squares (WLS) procedure based on the number of pairs of observations at each lag. So far, no study has investigated the efficiency of other least-squares procedures, such as ordinary least squares (OLS), generalized least squares (GLS), and WLS with other weighing functions, in the context of the LMC. In this article, we compare the statistical properties of the sill estimators obtained with eight least-squares procedures for fitting the LMC: OLS, four WLS, and three GLS. The WLS procedures are based on approximations of the variance of semivariogram estimates at each distance lag. The GLS procedures use a variance–covariance matrix of semivariogram estimates that is (i) estimated using the fourth-order moments with sill estimates (GLS1), (ii) calculated using the fourth-order moments with the theoretical sills (GLS2), and (iii) based on an approximation using the correlation between semivariogram estimates in the case of spatial independence of the observations (GLS3). The current algorithm for fitting the LMC by WLS while ensuring the positive semidefiniteness of sill matrix estimates is modified to include any least-squares procedure. A Monte Carlo study is performed for 16 scenarios corresponding to different combinations of the number of variables, number of spatial structures, values of ranges, and scale dependence of the correlations among variables. Simulation results show that the mean square error is accounted for mostly by the variance of the sill estimators instead of their squared bias. Overall, the estimated GLS1 and theoretical GLS2 are the most efficient, followed by the WLS procedure that is based on the number of pairs of observations and the average distance at each lag. On that basis, GLS1 can be recommended for future studies using the LMC.  相似文献   
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Detailed echo‐sounder and acoustic Doppler velocimeter measurements are used to assess the temporal and spatial structure of turbulent flow over a mobile dune in a wide, low‐gradient, alluvial reach of the Green River. Based on the geometric position of the sensor over the bedforms, measurements were taken in the wake, in transitional flow at the bedform crest, and in the internal boundary layer. Spatial distributions of Reynolds shear stress, turbulent kinetic energy, turbulence intensity, and correlation coefficient are qualitatively consistent with those over fixed, two‐dimensional bedforms in laboratory flows. Spectral and cospectral analysis demonstrates that energy levels in the lee of the crest (i.e. wake) are two to four times greater than over the crest itself, with minima over the stoss slope (within the developing internal boundary layer). The frequency structure in the wake is sharply defined with single, dominant peaks. Peak and total spectral and cross‐spectral energies vary over the bedform in a manner consistent with wave‐like perturbations that ‘break’ or ‘roll up’ into vortices that amalgamate, grow in size, and eventually diffuse as they are advected downstream. Fluid oscillations in the lee of the dune demonstrate Strouhal similarity between laboratory and field environments, and correspondence between the peak frequencies of these oscillations and the periodicity of surface boils was observed in the field. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   
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The structural organization of a giant mafic dyke swarm, the Okavango complex, in the northern Karoo Large Igneous Province (LIP) of NE Botswana is detailed. This N110°E-oriented dyke swarm extends for 1500 km with a maximum width of 100 km through Archaean basement terranes and Permo-Jurassic sedimentary sequences. The cornerstone of the study is the quantitative analysis of N>170 (exposed) and N>420 (detected by ground magnetics) dykes evidenced on a ca. 80-km-long section lying in crystalline host-rocks, at high-angle to the densest zone of the swarm (Shashe area). Individual dykes are generally sub-vertical and parallel to the entire swarm. Statistical analysis of width data indicates anomalous dyke frequency (few data <5.0 m) and mean dyke thickness (high value of 17 m) with respect to values classically obtained from other giant swarms. Variations of mean dyke thicknesses from 17 (N110°E swarm) to 27 m (adjoining and coeval N70°E giant swarm) are assigned to the conditions hosting fracture networks dilated as either shear or pure extensional structures, respectively, in response to an inferred NNW–SSE extension. Both fracture patterns are regarded as inherited brittle basement fabrics associated with a previous (Proterozoic) dyking event. The Okavango N110°E dyke swarm is thus a polyphase intrusive system in which total dilation caused by Karoo dykes (estimated frequency of 87%) is 12.2% (6315 m of cumulative dyke width) throughout the 52-km-long projected Shashe section. Assuming that Karoo mafic dyke swarms in NE Botswana follow inherited Proterozoic fractures, as similarly applied for most of the nearly synchronous giant dyke complexes converging towards the Nuanetsi area, leads us to consider that the resulting triple junction-like dyke/fracture pattern is not a definitive proof for a deep mantle plume in the Karoo LIP.  相似文献   
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Wallace (in Thermodynamics of crystals, 1972) developed a theorem, rooted in rigid lattice dynamics, which incorporates intrinsic anharmonic effects in solids. The practical application of this theorem in mineral physics is computationally involved and this is the main reason for the theorem not getting the attention it deserves. Because intrinsic anharmonicity is an important issue at the extreme conditions in planetary mantles, we derived a method which removes the computational obstacles in applying this theorem. We extended the theorem to incorporate details of the phonon spectrum and tested our algorithm on forsterite (Mg2SiO4). Using a least squares inversion technique applied to all available experimental data, we show that it results in an accurate representation of thermodynamic properties and sound wave velocities of Mg2SiO4 in its complete pressure–temperature stability range. We also show that the accuracy of our results is not significantly affected by the use of a different equation of state.  相似文献   
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Noble gases trapped in meteorites are tightly bound in a carbonaceous carrier labeled “phase Q.” Mechanisms having led to their retention in this phase or in its precursors are poorly understood. To test physical adsorption as a way of retaining noble gases into precursors of meteoritic materials, we have performed adsorption experiments for Ar, Kr, and Xe at low pressures (10−4 mbar to 500 mbar) encompassing pressures proposed for the evolving solar nebula. Low-pressure adsorption isotherms were obtained for ferrihydrite and montmorillonite, both phases being present in Orgueil (CI), for terrestrial type III kerogen, the best chemical analog of phase Q studied so far, and for carbon blacks, which are present in phase Q and can be considered as possible precursors.Based on adsorption data obtained at low pressures relevant to the protosolar nebula, we propose that the amount of noble gases that can be adsorbed onto primitive materials is much higher than previously inferred from experiments carried out at higher pressures. The adsorption capacity increases from kerogen, carbon blacks, montmorillonite to ferrihydrite. Because of its low specific surface area, kerogen can hardly account for the noble gas inventory of Q. Carbon blacks in the temperature range 75 K-100 K can adsorb up to two orders of magnitude more noble gases than those found in Q. Irreversible trapping of a few percent of noble gases adsorbed on such materials could represent a viable process for incorporating noble gases in phase Q precursors. This temperature range cannot be ruled out for the zone of accretion of the meteorite precursors according to recent astrophysical models and observations, although it is near the lower end of the temperatures proposed for the evolving solar nebula.  相似文献   
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A simple grid cell‐based distributed hydrologic model was developed to provide spatial information on hydrologic components for determining hydrologically based critical source areas. The model represents the critical process (soil moisture variation) to run‐off generation accounting for both local and global water balance. In this way, it simulates both infiltration excess run‐off and saturation excess run‐off. The model was tested by multisite and multivariable evaluation on the 50‐km2 Little River Experimental Watershed I in Georgia, U.S. and 2 smaller nested subwatersheds. Water balance, hydrograph, and soil moisture were simulated and compared to observed data. For streamflow calibration, the daily Nash‐Sutcliffe coefficient was 0.78 at the watershed outlet and 0.56 and 0.75 at the 2 nested subwatersheds. For the validation period, the Nash‐Sutcliffe coefficients were 0.79 at the watershed outlet and 0.85 and 0.83 at the 2 subwatersheds. The per cent bias was less than 15% for all sites. For soil moisture, the model also predicted the rising and declining trends at 4 of the 5 measurement sites. The spatial distribution of surface run‐off simulated by the model was mainly controlled by local characteristics (precipitation, soil properties, and land cover) on dry days and by global watershed characteristics (relative position within the watershed and hydrologic connectivity) on wet days when saturation excess run‐off was simulated. The spatial details of run‐off generation and travel time along flow paths provided by the model are helpful for watershed managers to further identify critical source areas of non‐point source pollution and develop best management practices.  相似文献   
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We explored the submarine portions of the Enriquillo–Plantain Garden Fault zone (EPGFZ) and the Septentrional–Oriente Fault zone (SOFZ) along the Northern Caribbean plate boundary using high‐resolution multibeam echo‐sounding and shallow seismic reflection. The bathymetric data shed light on poorly documented or previously unknown submarine fault zones running over 200 km between Haiti and Jamaica (EPGFZ) and 300 km between the Dominican Republic and Cuba (SOFZ). The primary plate‐boundary structures are a series of strike‐slip fault segments associated with pressure ridges, restraining bends, step overs and dogleg offsets indicating very active tectonics. Several distinct segments 50–100 km long cut across pre‐existing structures inherited from former tectonic regimes or bypass recent morphologies formed under the current strike‐slip regime. Along the most recent trace of the SOFZ, we measured a strike‐slip offset of 16.5 km, which indicates steady activity for the past ~1.8 Ma if its current GPS‐derived motion of 9.8 ± 2 mm a?1 has remained stable during the entire Quaternary.  相似文献   
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