Factors influencing the salinity regime of Lake Pontchartrain,Lousiana, a shallow coastal lagoon: Analysis of a long-term data set     

Walter B. Sikora  Björn Kjerfve 《Estuaries and Coasts》1985,8(2):170-180

Lake Pontchartrain., Louisiana is a 1,630 km² shallow brackish lagoon with a mean salinity from 1.2‰ in the west to 5.4‰ in the east., The construction of a 120 km long deep-water connection to the Gulf of Mexico in 1963, was expected to cause a 5‰ increase in lagoon salinity. However, the actual increase was everywhere in the lagoon less than 2‰ Analysis of 31 years of daily salinity and discharge records indicates that discharge is the most important factor controlling salinity variations in Lake Pontchartrain., Seventy-four percent of low-frequency salinity variations are explained by freshwater discharge and the completion of the deep-water canal. Lake Pont.-chartrain experiences annual variations of salinity as high as 8‰ This salinity signal has remained constant since the beginning of the salinity records in 1946. It appears that the deep-water canal is not responsible for observed die-back of freshwater swamps and retreat of lagoon shorelines.  相似文献   

The structural state of iron in oxidized vs. reduced glasses at 1 atm: A57Fe Mössbauer study     

David Virgo  Bjørn O. Mysen 《Physics and Chemistry of Minerals》1985,12(2):65-76

A general model for the structural state of iron in a variety of silicate and aluminosilicate glass compositions in the systems Na₂O-Al₂O₃-SiO₂-Fe-O, CaO-Al₂O₃-SiO₂-Fe-O, and MgO-Al₂O₃-SiO₂-Fe-O is proposed. Quenched melts with variable Al/Si and NBO/T (average number of nonbridging oxygens per tetrahedrally coordinated cation), synthesized over a range of temperatures and values of oxygen fugacity, are analyzed with⁵⁷Fe Mössbauer spectroscopy. For oxidized glasses with Fe³⁺/∑Fe>0.50, the isomer shift for Fe³⁺ is in the range ～0.22–0.33 mm/s and ～0.36 mm/s at 298 K and 77 K, respectively. These values are indicative of tetrahedrally coordinated Fe^3?. This assignment is in agreement with the interpretation of Raman, luminescence, and X-ray,K-edge absorption spectra. The values of the quadrupole splitting are ～0.90 mm/s (298 K and 77 K) in the Na-aluminosilicate glasses and compare with the values of 1.3 mm/s and 1.5 mm/s for the analogous Ca- and Mg-aluminosilicate compositions. The variations in quadrupole splittings for Fe³⁺ are due to differences in the degree of distortion of the tetrahedrally coordinated site in each of the systems. The values of the isomer shifts for Fe²⁺ ions in glasses irrespective of Fe³⁺/∑Fe are in the range 0.90–1.06 mm/s at 298 K and 1.0–1.15 mm/s at 77 K. The corresponding range of values of the quadrupole splitting is 1.75–2.10 mm/s at 298 K and 2.00–2.35 mm/s at 77 K. The temperature dependence of the hyperfine parameters for Fe²⁺ is indicative of noninteracting ions, but the values of the isomer shift are intermediate between those values normally attributable to tetrahedrally and octahedrally coordinated Fe²⁺. The assignment of the isomer-shift values of Fe²⁺ to octahedral coordination is in agreement with the results of other spectral studies. For reduced glasses (Fe³⁺/∑Fe≈<0.50), the value of the isomer shift for Fe³⁺ at both 298 K and 77 K increases and is linearly correlated with decreasing Fe³⁺/∑Fe in the range of \(f_{O_2 } \) between 10^?3 and 10^?6 atm when a single quadrupole-split doublet is assumed to represent the absorption due to ferric iron. The increase in value of the isomer shift with decreasing \(f_{O_2 } \) is consistent with an increase in the proportion of Fe³⁺ ions that are octahedrally coordinated. The concentration of octahedral Fe³⁺ is dependent on the \(T - f_{O_2 } \) conditions, and in the range of log \(f_{O_2 } \) between 10^?2.0 and 10^?5 a significant proportion of the iron may occur as iron-rich structural units with stoichiometry similar to that of inverse spinels such as Fe₃O₄, in addition to isolated Fe²⁺ and Fe³⁺ ions.  相似文献   

Magnetic susceptibility used in mapping of amphibolite facies recrystallisation in basic dykes     

Bjrn Hageskov 《Tectonophysics》1984,108(3-4)

The dense tholeiitic Koster dyke swarm, west Sweden, has undergone progressive deformation under amphibolite facies metamorphic conditions. The varying influence of this event on the dyke rock forms the basis for a regional division of the swarm into three sectors: the sectors of igneous dolerites, partly recrystallised metadolerites, and lineated amphibolites, respectively. Systematic measurements of the magnetic susceptibility in the dykes have demonstrated a correlation between the regional pattern of recrystallisation and the pattern of mean susceptibility given as mean susceptibility per 0.5 km². The transformation of dolerites to metadolerites and finally to lineated amphibolites is accompanied by a marked decrease in the susceptibility, which is related essentially to the degree of alteration of titanomagnetite to sphene + Fe-ions incorporated in the silicates.  相似文献   

Advances in physical geochemistry | S.K. Saxena (Editor), 1982. Vol. 2. I. Ferromagnesian silicates: order-disorder,kinetics, and phase equilibria; II. Melts,fluids, and solid-fluid equilibria; III. Thermodynamic methods and data. Springer-Verlag,New York, 353 pp. (113 figs.), DM94.000, approx. US$41.80 (clothbound)     

Bjørn Mysen 《Earth》1984,20(3):251-252

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Lake Søbygaard: a shallow lake in recovery after a reduction in phosphorus loading     

M. Sc. Søndergaard  E. Jeppesen  O. Sortkjaer 《GeoJournal》1987,14(3):381-384

The development and recovery of a shallow and hypertrophic lake following a reduction in the external phosphorus load has been documented. In spite of this reduction, phosphorus concentrations and phytoplankton biomass in the lake water are still very high. The reason for this development can be explained by three main factors: (1): the sediment has been accumulating a large phosphorus pool which is now causing a high internal phosphorus load, (2) due to the shallow conditions, resuspension of the upper sediment often takes place because of wind action and thereby increases the phosphorus loading from the sediment, (3) the development of a large population of planktivorous fish decreases the zooplankton biomass resulting in the development of a large phytoplankton biomass.  相似文献   

Seismotectonic scheme of Central and Eastern Europe     

Vladimír Schenk  Vít Kárník  Zdeňka Schenková  Reviewer A. Zátopek 《Studia Geophysica et Geodaetica》1982,26(2):132-144

Summary The distribution of earthquake foci in the crust and the upper mantle indicates the position of mobile zones. Comparing epicentral maps of Central and Eastern Europe, known tectonic lines, results of deep seismic sounding and gravimetric survey enables a scheme of potential seismogenic zones, which correspond to active fault zones separating plates and blocks in the area, to be compiled. The level of earthquake activity varies along the investigated boundaries and can be considered as a measure of the intensity of the present geodynamic processes.Paper presented at the joint symposium AlO of the XVIIth General Assembly of the European Seismological Commission and of the 7th Annual Meeting of the European Geophysical Society, Budapest (Hungary), Aug. 21. – 29., 1980.  相似文献   

Time pattern of large earthquake sequences in Europe in 1976–1979     

Vít Kárník  Zdeňka Schenková  Vladimír Schenk  Reviewer K. Pěč 《Studia Geophysica et Geodaetica》1982,26(1):42-58

Summary The time development of three large sequences, Friuli 1976, Thessaloniki 1978 and Monte Negro-Albania 1979, was investigated by analysing the characteristics of the time distribution of magnitudes of the events, M(t), of average magnitudes, (t), and of the number of events, n(t), as well as the strain release curves and the magnitude-frequency relations, N(M). The existence of time gaps and of an anomalous decay of the numbers of shocks before major events, as well as the oscillation of ( const b^–1) may be considered as precursory phenomena. The clustering of events has been tested by the Poisson and negative binomial laws.Communication presented at the XVIIth General Assembly of the European Seismological Commission in Budapest, 21–29 August, 1980 under the title Properties of Seismic Regime and Recent Earthquake Sequences in Europe.  相似文献   

Olivine phenocrysts of Hawaiian olivine tholeiite and oceanite   总被引：4，自引：0，他引：4  

Sven Maaløe  Birger Hansen 《Contributions to Mineralogy and Petrology》1982,81(3):203-211

Olivine phenocrysts of Hawaiian tholeiites display a variety of textures and a variation in composition which is due to supercooled crystallization. The highest forsterite content measured is 91%, and the highest magnesia content estimated for a tholeiitic liquid is 17%, using the olivine geothermometer. The liquid of this composition may be either a primary magma or a primitive magma. It is not yet possible to specify any particular composition range for the primary Hawaiian tholeiites.  相似文献   

Hypersthene-ilmenite(/magnetite) symplectites in coronitic olivine-gabbronorites     

H.P. Zeck  H.H. Shenouda  J.G. Rønsbo  R.P.E. Poorter 《Lithos》1982,15(3):173-182

Symplectitic intergrowths of hypersthene (host) with ilmenite and minor magnetite (vermicules) in a gabbroic sill from the Precambrian of southwest Sweden occur as replacement products of olivine, and are thought to have formed simulataneously with the replacement of nearby crystals of ilmenite and Timagnetite by biotite and hornblende (and spinel). These interrelated replacement processes may have taken place during, or immediately after, the final stages of the magmatic crystallization, at temperatures of about 660–680°C, as part of the inherent metamorphism of the gabbroic rock. Another expression of this metamorphic imprint is the occurrence of two-tiered corona shells of hypersthene/hornblende (+spinel) at the interface of olivine and plagioclase crystals.  相似文献   

The solubility mechanisms of volatiles in silicate melts and their relations to crystal-andesite liquid equilibria     

Bjrn O. Mysen 《Journal of Volcanology and Geothermal Research》1983,18(1-4)

The anionic structure of magmatic liquids has been estimated at 1 atm and at pressures corresponding to those of the upper mantle. These estimates are based predominantly on spectroscopic data on binary metal oxide-silica and ternary metal oxide-silica-alumina melts. Structural information on melt compositions in aluminate-silica joins has been used to provide detailed information on the role of Al³⁺ in natural magma at atmospheric and high pressure.Regardless of pressure, andesitic melts may be described as combinations of chain, sheet, and three-dimensional network units. Nearly all Al³⁺ in the magmatic liquid resides in the three-dimensional network units. This Al³⁺ is locally charge-balanced with Na⁺, K⁺, Ca²⁺, and Mg²⁺. In the latter two cases, Al³⁺ and Si⁴⁺ are ordered, whereas for Na⁺ and K⁺, Si⁴⁺ and Al³⁺ are randomly mixed. Solution of water in natural magma results in the formation of new nonbridging oxygens in addition to OH groups attached to Si⁴⁺ and metal cations.On the basis of determined solution mechanisms of CO₂ and H₂O in silicate melts, thermodynamic properties of HO+CO₂, fluids and hydrous silicate melts and melting phase relations in peridotite-H₂O-CO₂, systems, it is found that natural andesitic magma in equilibrium with spinel Iherzolite in the upper mantle (10–20 kbar) must contain at least 5–7 wt.% H₂O. Andesitic magma with 5–7 wt.% H₂O in solution may be described as a mixture of Al-free three-dimensional units, sheets, and chains with a small proportion (less than 10%) of monomers.  相似文献