Characterization of sediments in an abandoned mining area; a case study of Mansfeld region,Germany   总被引：1，自引：0，他引：1  

Rainer?WennrichEmail author  Jürgen?Mattusch  Peter?Morgenstern  Klaus?Freyer  Hanns-Christian?Treutler  Hans-Joachim?St?rk  Lutz?Brüggemann  Albrecht?Paschke  Birgit?Daus  Holger?Weiss 《Environmental Geology》2004,45(6):818-833

The distribution of selected heavy metals, including some radionuclides, metalloids and non-metals was determined in stream sediments in a region influenced by abandoned copper mining and ore processing activities. A considerable amount of the ore processing waste with a very complex composition and highly elevated concentrations of zinc, sulfur, lead, copper, arsenic, and a lot of other elements in the range between 100 and 1,000 mg/kg (Sb, Mn, Ni, Cr, Cd, Hg, and Ag) was piled up on mine dumps. The dispersion of the pollutants originating from this source and their environmental impact were investigated. Both, sediments and original waste material were studied to indicate the pathways and the mobilization behavior of different pollutants. For this purpose, the process of the elution of pollutants by application of different fractionation schemes was studied. The capabilities of different analytical techniques are shown for the analysis of solid samples (X-ray fluorescence spectrometry, Gamma-spectrometry) and liquid ones (ICP-atomic emission spectrometry, ICP-mass spectrometry and different techniques of atomic absorption). Additionally, the coupling of ion chromatography and ICP-MS detection was used to study the distribution of arsenic species in the sediment cores of a lake which acts as a natural sink for the region.  相似文献   

Hydrocarbon contamination in mussels from Guanabara Bay     

Azevedo LA  de Andrade Brüning IM  Moreira I 《Marine pollution bulletin》2004,49(11-12):1120-1122

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Neoproterozoic to Early-Palaeozoic magmatic evolution in the Gondwana-derived Austroalpine basement to the south of the Tauern Window (Eastern Alps)   总被引：1，自引：0，他引：1  

Bernhard?SchulzEmail author  Klaus?Bombach  Sabine?Pawlig  Helene?Br?tz 《International Journal of Earth Sciences》2004,93(5):824-843

In the Austroalpine Basement to the south of the Tauern Window, distinct suites of metabasites occur with orthogneisses in pre-Early-Ordovician units. Tholeiitic and alkaline within-plate basalt-type metabasites are associated with acid meta-porphyroids in the post-Early-Ordovician Thurntaler Phyllite Group. According to their correlated trace element abundances, metabasite zircons crystallized with their host rocks. Protolith Pb–Pb zircon ages, whole-rock Ta/Yb–Th/Yb and oxygen, Sr, Nd isotope data define two principal evolution lines. An older evolution at elevated Th/Yb typical of subduction-related magmatism, started by 590-Ma N-MORB-type and 550–530 Ma volcanic arc basalt type basic suites, which mainly involved depleted mantle sources. It finished with mainly crustal-source 470–450-Ma acid magmatites. An other evolution line by tholeiitic and 430-Ma alkaline within-plate basalt-type suites in both pre- and post-Early-Ordovician units is characterized by an intraplate mantle metasomatism and enrichment trend along multicomponent sources. These magmatic evolution lines can be related to a plate tectonic scenario that involved terranes in a progressively mature Neoproterozoic to Ordovician active margin, and a subsequent Palaeo-Tethys passive margin along the north Gondwanan periphery.  相似文献   

Different age response of zircon and monazite during the tectono-metamorphic evolution of a high grade paragneiss from the Ruhla Crystalline Complex,central Germany   总被引：5，自引：0，他引：5  

Armin?ZehEmail author  Ian?S.?Williams  Helene?Br?tz  Ian?L.?Millar 《Contributions to Mineralogy and Petrology》2003,145(6):691-706

Results of TIMS, SIMS and SEM analyses show that zircon and monazite in a high-grade paragneiss of the Ruhla Crystalline Complex, central Germany, were formed and/or altered during different stages of a tectono-metamorphic history between Early Devonian and Permian times. Detrital zircon cores of >460 Ma place an older limit on the age of anatexis, and show that the paragneiss sequence contains rocks at least as young as early Cambrian. Metamorphic zircon growth commenced at ~365 Ma, peaking at ~360–355 Ma at the same time that granite dykes were emplaced. In contrast, monazite in the paragneiss preserves little record of the metamorphic peak. Most monazite grains grew or were recrystallised in the Lower Carboniferous at ~339 Ma, contemporaneous with the emplacement of voluminous diorite and granite bodies. These intrusions and related tectonics caused some of the high-U zircon overgrowths to undergo moderate to severe Pb loss. A second Pb loss event, between 300 and 280 Ma, can be related to Late Carboniferous/Early Permian large-scale block faulting.Editorial responsibility: J. Hoefs  相似文献   

Special Contribution: ALP 2002 Seismic Experiment     

Brückl  E.  Bodoky  T.  Hegedüs  E.  Hrubcová  P.  Gosar  A.  Grad  M.  Guterch  A.  Hajnal  Z.  Keller  G.R.  Špičák  A.  Sumanovac  F.  Thybo  H.  Weber  F. 《Studia Geophysica et Geodaetica》2003,47(3):671-679

Studia Geophysica et Geodaetica -  相似文献   

Special Contribution: CELEBRATION 2000 Seismic Experiment     

Guterch  A.  Grad  M.  Keller  G.R.  Posgay  K.  Vozár  J.  Špičák  A.  Brückl  E.  Hajnal  Z.  Thybo  H.  Selvi  O. 《Studia Geophysica et Geodaetica》2003,47(3):659-669

Studia Geophysica et Geodaetica -  相似文献   

Impact des crues sur les bilans sédimentaires de chenaux secondaires de la Loire moyenne (France)     

Stéphane Rodrigues  Jean-Gabriel Bréhéret  Florentina Moatar  Jean-Jacques Macaire 《Comptes Rendus Geoscience》2005,337(5):487-495

Volumes of sediments eroded and deposited during floods were quantified in a vegetated secondary channel of the Loire River at the study site of Bréhémont (France). The topographic survey highlights the temporal variability in filling of secondary channels. Upstream riffle of secondary channels governs sedimentary supply. In these channels, sediments show a by-passing in the lower parts and an accretion in the higher vegetated areas. The asymmetrical morphology is reinforced during both intense and moderate floods. Sedimentary accretion in the vegetated areas leads progressively to channel narrowing. To cite this article: S. Rodrigues et al., C. R. Geoscience 337 (2005).  相似文献   

Size-Resolved Aerosol Characterization for a Polluted Episode at the IfT Research Station Melpitz in Autumn 1997     

A. Plewka  T. Gnauk  E. Brüggemann  C. Neusüss  H. Herrmann 《Journal of Atmospheric Chemistry》2004,48(2):131-156

Inorganic ions, organic carbon (OC), elemental carbon (EC) and a variety of organic single species in airborne particles have been determined at the research station of the Leibniz – Institut für Troposphärenforschung (IfT) in Melpitz (Germany) in autumn 1997.Samples of eight selected measurement events were divided in two groups in order to investigate differences in the chemical composition of particles originating from southwesterly (SW – developed EU countries) or from easterly directions (E – less developed eastern countries). Differences between these two groups were tested statistically by Student's t-test.Five stage cascade impactor samples show nitrate as most abundant in the accumulation mode in the SW group. EC and sulphate show the most abundant mass fractions in the E group. That can be considered as a consequence of domestic coal heating and coal-fired power plant emissions in the region of westerly Poland, northern Czech Republic and easterly Germany. Higher nitrate concentrations in the SW group can be explained by stronger NO _x emissions caused by the leeward plume of the conurbation of Leipzig, as well as by the still higher traffic density in western Germany.The methane sulphonic acid (MSA) mass fraction was higher for SW air masses in accumulation mode particles, probably indicating marine origin. Succinic acid also showed higher mass fractions for the SW group. This could be caused by primary emission in automobile exhaust gases and photochemical formation during transport from SW. Indeed, during SW sampling, solar radiation intensity was higher than during E sampling.The observed differences in the particle composition are an expression of the still existing technology gradient in Europe. Future campaigns could show the development to a joint economy with smaller differences in anthropogenic emissions.  相似文献   

Mixing Ratios and Photostationary State of NO and NO2 Observed During the POPCORN Field Campaign at a Rural Site in Germany     

F. Rohrer  D. Brüning  E. S. Grobler  M. Weber  D. H. Ehhalt  R. Neubert  W. Schüßler  I. Levin 《Journal of Atmospheric Chemistry》1998,31(1-2):119-137

Ambient mixing ratios of NO, NO2, and O3 were determined together with the photolysis frequency of NO2, JNO2, at a rural, agricultural site in Germany. The data were collected during the POPCORN-campaign from August 1 to August 24, 1994, in a maize field 6 m above ground. The medians of the NO, NO2, and O3 mixing ratios between 10:00 and 14:00 UT were 0.25, 1.09, and 45 ppbv, respectively. The corresponding median of JNO2 was 6.0 · 10–3 s–1. NOx = NO + NO2 showed a strong diurnal variation with maximum mixing ratios at night, suggestive of a strong local surface source of NO, probably by microbial activity in the soil. The estimated average emission rate was 40 ng(N) m–2 s–1 of NOx, the major part of it probably in the form of NO. The available measurements allowed the estimation of the local NOx budget. At night the budget is almost closed and the measured NOx mixing ratios can be explained by the local source, local dry deposition of NO2, formation of NO3 and N2O5, and vertical exchange of air across the nocturnal inversion. During day-time, the local surface source of NO is not sufficient to explain the measured mixing ratios, and horizontal advection of NOx to the site must be included. The NO2/NO ratio during the morning und late afternoon is lower than predicted from the photostationary state owing to the local NO surface source, but is regulary higher during the hours around noon. For noon, August 10, 1994, the NO2/NO ratio was used to derive the momentary lower limit for the concentration of the peroxy-radicals of 2.2 · 109 cm–3 (86 pptv).  相似文献   

Development of a chemistry module for GCMs: first results of a multiannual integration     

B. Steil  M. Dameris  C. Brühl  P. J. Crutzen  V. Grewe  M. Ponater  R. Sausen 《Annales Geophysicae》1998,16(2):205-228

The comprehensive chemistry module CHEM has been developed for application in general circulation models (GCMs) describing tropospheric and stratospheric chemistry, including photochemical reactions and heterogeneous reactions on sulphate aerosols and polar stratospheric clouds. It has been coupled to the spectral atmospheric GCM ECHAM3. The model configuration used in the current study has been run in an –off-line mode, i.e. the calculated chemical species do not affect the radiative forcing of the dynamic fields. First results of a 15-year model integration indicate that the model ECHAM3/CHEM runs are numerically efficient and stable, i.e. that no model drift can be detected in dynamic and chemical parameters. The model reproduces the main features regarding ozone, in particular intra- and interannual variability. The ozone columns are somewhat higher than observed (approximately 10%), while the amplitude of the annual cycle is in agreement with observations. A comparison with HALOE data reveals, however, a serious model deficiency regarding lower-stratosphere dynamics at high latitudes. Contrary to what is concluded by observations, the lower stratosphere is characterized by slight upward motions in the polar regions, so that some of the mentioned good agreements must be considered as fortuitous. Nevertheless, ECHAM3/CHEM well describes the chemical processes leading to ozone reduction. It has been shown that the mean fraction of the northern hemisphere, which is covered by polar stratospheric clouds (PSCs) as well as the temporal appearance of PSCs in the model, is in fair agreement with observations. The model results show an activation of chlorine inside the polar vortex which is stronger in the southern than in the northern winter hemisphere, yielding an ozone hole over the Antarctic; this hole, however, is also caused to a substantial degree by the dynamics. Interhemispheric differences concerning reformation of chlorine reservoir species HCl and ClONO₂ in spring have also been well reproduced by the model.  相似文献