Effectiveness of Monitored Natural Attenuation (MNA) as a Groundwater Remedy for Arsenic in Phosphatic Wastes     

Brad A. Bessinger  Remy J.-C. Hennet 《Ground Water Monitoring & Remediation》2019,39(4):52-68

A study was conducted to evaluate monitored natural attenuation (MNA) as a remedy for arsenic in groundwater at a former phosphate mining and manufacturing facility. The mineralogy, speciation, and lability of arsenic in phosphatic wastes present in soils were characterized using sequential extraction procedures, leaching experiments, batch adsorption tests, and microchemical speciation analysis. A PHREEQC-based reactive transport model was also parameterized using these laboratory results, and it was used to evaluate the importance of identified attenuation mechanisms on arsenic concentrations along a vertical flow path from a shallow, alluvial aquifer to the underlying Floridan aquifer. Arsenic was found to occur in several chemical forms in phosphatic wastes, including unstable sulfide minerals, adsorbed surface complexes, and relatively insoluble phosphate and oxide minerals. Most arsenic was associated with stable minerals. The reactive transport model predicted that historical leaching of solid-phase waste materials in soils would not have generated enough arsenic to explain the concentrations observed in downgradient groundwater; instead, the source of arsenic to groundwater was likely acidic and saline process water that infiltrated though unlined ponds and ditches during historical manufacturing operations. A key factor affecting the long-term effectiveness of natural attenuation of arsenic in groundwater is the occurrence and stability of iron oxyhydroxides in aquifer sediments. According to laboratory and reactive transport model results, sufficient levels were found to be present at the site to effectively limit arsenic migration at concentrations exceeding drinking water standards in the future in the Floridan aquifer. This study presents the geochemical evaluations that are needed to satisfy EPA guidelines on determining whether or not MNA is an acceptable remedy for a site. It specifically details the characterization and modeling that were used to demonstrate effectiveness at a site where MNA was ultimately selected as the remedy for arsenic in groundwater.  相似文献   

High-precision 40Ar/39Ar sanidine geochronology of ignimbrites in the Mogollon-Datil volcanic field,southwestern New Mexico   总被引：1，自引：0，他引：1  

William C McIntosh  John F Sutter  Charles E Chapin  Laura L Kedzie 《Bulletin of Volcanology》1990,52(8):584-601

⁴⁰Ar/³⁹Ar age spectra have been obtained from 85 sanidine separates from 36 ignimbrites and one rhyolitic lava in the latest Eocene-Oligocene Mogollon-Datil volcanic field of southwestern New Mexico. Of the 97 measured age spectra, 94 yield weighted-mean plateau ages each giving single-spectrum 1 precision of±0.25%–0.4% (±0.07–0.14 Ma). Replicate plateau age determinations for eight different samples show within-sample 1 precisions averaging ±0.25%. Plateau ages from multiple (n=3–8) samples of individual ignimbrites show 1 within-unit precision of ±0.1%–0.4% (±0.04–0.13 Ma). This within-unit precision represents a several-fold improvement over published K-Ar data for the same ignimbrites, and is similar to the range of precisions reported from single-crystal laser fusion studies. A further indication of the high precision of unit-mean ⁴⁰Ar/³⁰Ar ages is their close agreement with independently established stratigraphic order. Two samples failed to meet plateau criteria, apparently due to geologic contamination by older feldspars. Effects of minor contamination are shown by six other samples, which yielded slightly anomalous plateau ages. ⁴⁰Ar/³⁹Ar plateau ages permit resolution of units differing in age by 0.5% (0.15 Ma) or less. This high resolution, combined with paleomagnetic studies, has helped to correlate ignimbrites among isolated ranges and has allowed development of an integrated timestratigraphic framework for the volcanic field. Mogollon-Datil ignimbrites range in age from 36.2 to 24.3 Ma. Ignimbrite activity was strongly episodic, being confined to four brief (<2.6 m.y.) eruptive episodes separated by 1–3 m.y. gaps. Ignimbrite activity generally tended to migrate from the southeast toward the north and west.  相似文献   

The Early-Middle Pleistocene Transition： characterization and proposed guide for the defining boundary   总被引：1，自引：0，他引：1  

Martin J. Head Brad Pillans Sarah A. Farquhar 《《幕》》2008,31(2):255-259

The mid-Pleistocene transition （MPT, c. 1.2 to 0.5 Ma） records fundamental changes in Earth＇s climate state, where low-amplitude 41-kyr obliquity-dominated cycles gave way progressively to the high-amplitude, quasiperiodic （c. 100-kyr） fluctuations that characterize the later Pleistocene and Holocene. We use wavelet analysis on the LR04 δ^l8O benthic foraminiferal stack to confirm low-frequency power as early as 1.25-1.20 Ma, determine the persistence of obliquity-dominated cyclicity through and beyond the MPT, and reveal new levels of complexity in climate evolution.  相似文献   

Atmospheric forcing, larval drift, and recruitment of capelin (Mallotus villosus)     

Dalley  Edgar L.; Anderson  John T.; deYoung  Brad 《ICES Journal of Marine Science》2002,59(5):929-941

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The Landsat Global Archive: a valuable global resource     

Kamlesh Lulla  M. Duane Nellis  Brad Rundquist 《国际地球制图》2013,28(4)

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China-Brazil Earth Resources Satellite Collaboration is a success     

Kamlesh Lulla  M. Duane Nellis  Brad Rundquist 《国际地球制图》2013,28(5)

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Celebrating fifty years of NASA and Earth observations from space. Part IV: Global water cycle and water resources research     

Kamlesh Lulla  M. Duane Nellis  Brad Rundquist 《国际地球制图》2013,28(4)

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Multiple P–T–d–t paths reveal the evolution of the final Nuna assembly in northeast Australia     

Silvia Volante  Amaury Pourteau  William J. Collins  Eleanore Blereau  Zheng-Xiang Li  Matthijs Smit  Noreen J. Evans  Adam R. Nordsvan  Chris J. Spencer  Brad J. McDonald  Jiangyu Li  Christina Günter 《Journal of Metamorphic Geology》2020,38(6):593-627

The final assembly of the Mesoproterozoic supercontinent Nuna was marked by the collision of Laurentia and Australia at 1.60 Ga, which is recorded in the Georgetown Inlier of NE Australia. Here, we decipher the metamorphic evolution of this final Nuna collisional event using petrostructural analysis, major and trace element compositions of key minerals, thermodynamic modelling, and multi-method geochronology. The Georgetown Inlier is characterised by deformed and metamorphosed 1.70–1.62 Ga sedimentary and mafic rocks, which were intruded by c. 1.56 Ga old S-type granites. Garnet Lu–Hf and monazite U–Pb isotopic analyses distinguish two major metamorphic events (M1 at c. 1.60 Ga and M2 at c. 1.55 Ga), which allows at least two composite fabrics to be identified at the regional scale—c. 1.60 Ga S1 (consisting in fabrics S1a and S1b) and c. 1.55 Ga S2 (including fabrics S2a and S2b). Also, three tectono-metamorphic domains are distinguished: (a) the western domain, with S1 defined by low-P (LP) greenschist facies assemblages; (b) the central domain, where S1 fabric is preserved as medium-P (MP) amphibolite facies relicts, and locally as inclusion trails in garnet wrapped by the regionally dominant low-P amphibolite facies S2 fabric; and (c) the eastern domain dominated by upper amphibolite to granulite facies S2 foliation. In the central domain, 1.60 Ga MP–medium-T (MT) metamorphism (M1) developed within the staurolite–garnet stability field, with conditions ranging from 530–550°C at 6–7 kbar (garnet cores) to 620–650°C at 8–9 kbar (garnet rims), and it is associated with S1 fabric. The onset of 1.55 Ga LP–high-T (HT) metamorphism (M2) is marked by replacement of staurolite by andalusite (M2a/D2a), which was subsequently pseudomorphed by sillimanite (M2b/D2b) where granite and migmatite are abundant. P–T conditions ranged from 600 to 680°C and 4–6 kbar for the M2b sillimanite stage. 1.60 Ga garnet relicts within the S2 foliation highlight the progressive obliteration of the S1 fabric by regional S2 in the central zone during peak M2 metamorphism. In the eastern migmatitic complex, partial melting of paragneiss and amphibolite occurred syn- to post- S2, at 730–770°C and 6–8 kbar, and at 750–790°C and 6 kbar, respectively. The pressure–temperature–deformation–time paths reconstructed for the Georgetown Inlier suggest a c. 1.60 Ga M1/D1 event recorded under greenschist facies conditions in the western domain and under medium-P and medium-T conditions in the central domain. This event was followed by the regional 1.56–1.54 Ga low-P and high-T phase (M2/D2), extensively recorded in the central and eastern domains. Decompression between these two metamorphic events is ascribed to an episode of exhumation. The two-stage evolution supports the previous hypothesis that the Georgetown Inlier preserves continental collisional and subsequent thermal perturbation associated with granite emplacement.  相似文献   

Using local infrasound arrays to detect plunging snow avalanches along the Milford Road,New Zealand (Aotearoa)     

Watson  Leighton M.  Carpenter  Brad  Thompson  Kevin  Johnson  Jeffrey B. 《Natural Hazards》2022,111(1):949-972

Natural Hazards - Snow avalanches pose a hazard in alpine environments. There is a need to improve monitoring capabilities in order to reliably detect and locate avalanche activity, which will help...  相似文献   

Geostatistical Rock Physics Inversion for Predicting the Spatial Distribution of Porosity and Saturation in the Critical Zone     

Grana  Dario  Parsekian  Andrew D.  Flinchum  Brady A.  Callahan  Russell P.  Smeltz  Natalie Y.  Li  Ang  Hayes  Jorden L.  Carr  Brad J.  Singha  Kamini  Riebe  Clifford S.  Holbrook  W. Steven 《Mathematical Geosciences》2022,54(8):1315-1345

Mathematical Geosciences - Understanding the subsurface structure and function in the near-surface groundwater system, including fluid flow, geomechanical, and weathering processes, requires...  相似文献