Environmental oxidation rate of manganese(II): bacterial catalysis     

Steven Emerson  Susan Kalhorn  Lucinda Jacobs  Bradley M Tebo  Kenneth H Nealson  Reinhardt A Rosson 《Geochimica et cosmochimica acta》1982,46(6):1073-1079

A simple mass balance for dissolved manganese(II) in waters containing low levels of oxygen in Saanich Inlet indicates that the residence time for Mn(II) removal to the solid phase is on the order of a few days. The average oxidation state of Mn in particulate material sampled from the region of Mn removal was 2.3–2.7, and electron micrographs revealed structures characteristic of bacterially formed Mn precipitates. Radiotracer experiments utilizing ⁵⁴Mn(II) indicated that removal of Mn from solution in the region of active uptake was substantially blocked by a poison mixture, demonstrating that Mn(II) binding to particulates is catalyzed by bacteria in this environment.  相似文献   

Improved seismic hazard model with application to probabilistic seismic demand analysis     

Brendon A. Bradley  Rajesh P. Dhakal  Misko Cubrinovski  John B. Mander  Greg A. MacRae 《地震工程与结构动力学》2007,36(14):2211-2225

An improved seismic hazard model for use in performance‐based earthquake engineering is presented. The model is an improved approximation from the so‐called ‘power law’ model, which is linear in log–log space. The mathematics of the model and uncertainty incorporation is briefly discussed. Various means of fitting the approximation to hazard data derived from probabilistic seismic hazard analysis are discussed, including the limitations of the model. Based on these ‘exact’ hazard data for major centres in New Zealand, the parameters for the proposed model are calibrated. To illustrate the significance of the proposed model, a performance‐based assessment is conducted on a typical bridge, via probabilistic seismic demand analysis. The new hazard model is compared to the current power law relationship to illustrate its effects on the risk assessment. The propagation of epistemic uncertainty in the seismic hazard is also considered. To allow further use of the model in conceptual calculations, a semi‐analytical method is proposed to calculate the demand hazard in closed form. For the case study shown, the resulting semi‐analytical closed form solution is shown to be significantly more accurate than the analytical closed‐form solution using the power law hazard model, capturing the ‘exact’ numerical integration solution to within 7% accuracy over the entire range of exceedance rate. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

Evolutionary Timescale of the Pulsating White Dwarf G117-B15A: The Most Stable Optical Clock Known     

Kepler SO  Mukadam A  Winget DE  Nather RE  Metcalfe TS  Reed MD  Kawaler SD  Bradley PA 《The Astrophysical journal》2000,534(2):L185-L188

We observe G117-B15A, the most precise optical clock known, to measure the rate of change of the main pulsation period of this blue-edge DAV white dwarf. Even though the obtained value is only within 1 sigma, P&d2;=&parl0;2.3+/-1.4&parr0;x10-15 s s-1, it is already constraining the evolutionary timescale of this cooling white dwarf star.  相似文献   

Effect of H₂ and Redox Condition on Biotic and Abiotic MTBE Transformation     

P.M. Bradley  F.H. Chapelle  J.E. Landmeyer 《Ground Water Monitoring & Remediation》2006,26(4):74-81

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Using paleoclimate proxy-data to select optimal realisations in an ensemble of simulations of the climate of the past millennium   总被引：1，自引：0，他引：1  

Hugues Goosse  Hans Renssen  Axel Timmermann  Raymond S. Bradley  Michael E. Mann 《Climate Dynamics》2006,27(2-3):165-184

We present and describe in detail the advantages and limitations of a technique that combines in an optimal way model results and proxy-data time series in order to obtain states of the climate system consistent with model physics, reconstruction of past radiative forcing and proxy records. To achieve this goal, we select among an ensemble of simulations covering the last millennium performed with a low-resolution 3-D climate model the ones that minimise a cost function. This cost function measures the misfit between model results and proxy records. In the framework of the tests performed here, an ensemble of 30 to 40 simulations appears sufficient to reach reasonable correlations between model results and reconstructions, in configurations for which a small amount of data is available as well as in data-rich areas. Preliminary applications of the technique show that it can be used to provide reconstructions of past large-scale temperature changes, complementary to the ones obtained by statistical methods. Furthermore, as model results include a representation of atmospheric and oceanic circulations, it can be used to provide insights into some amplification mechanisms responsible for past temperature changes. On the other hand, if the number of proxy records is too low, it could not be used to provide reconstructions of past changes at a regional scale.  相似文献   

An Acoustic-Instrumented Mine for Studying Subsequent Burial     

Bradley  J. Griffin  S. Thiele  M. Richardson  M.D. Thorne  P.D. 《Oceanic Engineering, IEEE Journal of》2007,32(1):64-77

The U.S. Navy is supporting the research to develop and validate stochastic, time-dependent, mine burial prediction models to aid the tactical decision making process. This research requires continuous monitoring of both mine behavior during burial, and the near-field processes responsible for burial. A new instrumented mine has been developed that far exceeds the capabilities of the earlier optically instrumented mine in terms of the burial processes that can be measured. The acoustic-instrumented mine (AIM) utilizes acoustic transducers to measure burial and scour, localized flow rates, and sediment size and concentration in the water column. The AIM also includes sensors for measuring mine orientation and movement, as well as oceanographic information such as significant waveheights, wave period, and water temperature. Four AIMs were constructed and deployed during the Indian Rocks Beach (IRB, FL) and Martha's Vineyard Coastal Observatory (MVCO, Edgartown, MA) mine burial experiments. The results from the field experiments have proven that the sensor suite is viable in providing a wealth of data that are critical in understanding and modeling the complex subsequent burial process.  相似文献   

Constraining Holocene sea‐surface conditions in the south‐western Black Sea using dinoflagellate cysts     

L. R. Bradley  F. Marret  P. J. Mudie  A. E. Aksu  R. N. Hiscott 《第四纪科学杂志》2012,27(8):835-843

This paper presents two dinoflagellate cyst records from the south‐western shelf of the Black Sea. A new site, MAR05‐13, from the Sakarya shelf is described and placed into context with site MAR02‐45, ～250 km distant on the Thracian shelf. The records provide a centennial resolution of surface water conditions in the Holocene. Analysis of the data suggests that the surface salinity of the south‐western shelf increased in a gradual and progressive manner. In the period ～11 000–9000 cal a BP the assemblages suggest surface‐water salinities between 7–13 psu. The initial arrival of euryhaline species, ～8100 cal a BP, is linked to the reconnection of the Black Sea and Marmara Sea. The suggested surface water changes related to the reconnection took approximately 1000 years. Following this initial change in assemblages, a further increase in the number of euryhaline species is noted between 5000 and 4000 cal a BP. This is linked to the establishment of more saline surface‐water conditions, close to present‐day values. The record for MAR05‐13 highlights the complexity of the changes in cyst assemblages during the mid‐Holocene. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

Bounce Rock—A shergottite‐like basalt encountered at Meridiani Planum,Mars     

Jutta ZIPFEL  Bradley L. JOLLIFF  Ralf GELLERT  Kenneth E. HERKENHOFF  Rudolf RIEDER  Robert ANDERSON  James F. BELL III  Johannes BRÜCKNER  Joy A. CRISP  Philip R. CHRISTENSEN  Benton C. CLARK  Paulo A. De SOUZA Jr.  Gerlind DREIBUS  Claude D’USTON  Thanasis ECONOMOU  Steven P. GOREVAN  Brian C. HAHN  Göstar KLINGELHÖFER  Timothy J. McCOY  Harry Y. McSWEEN Jr.  Douglas W. MING  Richard V. MORRIS  Daniel S. RODIONOV  Steven W. SQUYRES  Heinrich WÄNKE  Shawn P. WRIGHT  Michael B. WYATT  Albert S. YEN 《Meteoritics & planetary science》2011,46(1):1-20

Abstract– The Opportunity rover of the Mars Exploration Rover mission encountered an isolated rock fragment with textural, mineralogical, and chemical properties similar to basaltic shergottites. This finding was confirmed by all rover instruments, and a comprehensive study of these results is reported here. Spectra from the miniature thermal emission spectrometer and the Panoramic Camera reveal a pyroxene‐rich mineralogy, which is also evident in Mössbauer spectra and in normative mineralogy derived from bulk chemistry measured by the alpha particle X‐ray spectrometer. The correspondence of Bounce Rock’s chemical composition with the composition of certain basaltic shergottites, especially Elephant Moraine (EET) 79001 lithology B and Queen Alexandra Range (QUE) 94201, is very close, with only Cl, Fe, and Ti exhibiting deviations. Chemical analyses further demonstrate characteristics typical of Mars such as the Fe/Mn ratio and P concentrations. Possible shock features support the idea that Bounce Rock was ejected from an impact crater, most likely in the Meridiani Planum region. Bopolu crater, 19.3 km in diameter, located 75 km to the southwest could be the source crater. To date, no other rocks of this composition have been encountered by any of the rovers on Mars. The finding of Bounce Rock by the Opportunity rover provides further direct evidence for an origin of basaltic shergottite meteorites from Mars.  相似文献   

Persistent organic pollutants and stable isotopes in biopsy samples (2004/2006) from Southern Resident killer whales     

Krahn MM  Hanson MB  Baird RW  Boyer RH  Burrows DG  Emmons CK  Ford JK  Jones LL  Noren DP  Ross PS  Schorr GS  Collier TK 《Marine pollution bulletin》2007,54(12):1903-1911

“Southern Resident” killer whales include three “pods” (J, K and L) that reside primarily in Puget Sound/Georgia Basin during the spring, summer and fall. This population was listed as “endangered” in the US and Canada following a 20% decline between 1996 and 2001. The current study, using blubber/epidermis biopsy samples, contributes contemporary information about potential factors (i.e., levels of pollutants or changes in diet) that could adversely affect Southern Residents. Carbon and nitrogen stable isotopes indicated J- and L-pod consumed prey from similar trophic levels in 2004/2006 and also showed no evidence for a large shift in the trophic level of prey consumed by L-pod between 1996 and 2004/2006. ∑PCBs decreased for Southern Residents biopsied in 2004/2006 compared to 1993–1995. Surprisingly, however, a three-year-old male whale (J39) had the highest concentrations of ∑PBDEs, ∑HCHs and HCB. POP ratio differences between J- and L-pod suggested that they occupy different ranges in winter.  相似文献   

Hydrologic significance of carbon monoxide concentrations in ground water     

Chapelle FH  Bradley PM 《Ground water》2007,45(3):272-280

Dissolved carbon monoxide (CO) is present in ground water produced from a variety of aquifer systems at concentrations ranging from 0.2 to 20 nanomoles per liter (0.0056 to 0.56 microg/L). In two shallow aquifers, one an unconsolidated coastal plain aquifer in Kings Bay, Georgia, and the other a fractured-bedrock aquifer in West Trenton, New Jersey, long-term monitoring showed that CO concentrations varied over time by as much as a factor of 10. Field and laboratory evidence suggests that the delivery of dissolved oxygen to the soil zone and underlying aquifers by periodic recharge events stimulates oxic metabolism and produces transiently high CO concentrations. In between recharge events, the aquifers become anoxic and more substrate limited, CO is consumed as a carbon source, and CO concentrations decrease. According to this model, CO concentrations provide a transient record of oxic metabolism affecting ground water systems after dissolved oxygen has been fully consumed. Because the delivery of oxygen affects the fate and transport of natural and anthropogenic contaminants in ground water, CO concentration changes may be useful for identifying predominantly anoxic ground water systems subject to periodic oxic or microaerophilic conditions.  相似文献