Dissolved oxygen as an indicator of bioavailable dissolved organic carbon in groundwater   总被引：1，自引：0，他引：1  

Chapelle FH  Bradley PM  McMahon PB  Kaiser K  Benner R 《Ground water》2012,50(2):230-241

Concentrations of dissolved oxygen (DO) plotted vs. dissolved organic carbon (DOC) in groundwater samples taken from a coastal plain aquifer of South Carolina (SC) showed a statistically significant hyperbolic relationship. In contrast, DO-DOC plots of groundwater samples taken from the eastern San Joaquin Valley of California (CA) showed a random scatter. It was hypothesized that differences in the bioavailability of naturally occurring DOC might contribute to these observations. This hypothesis was examined by comparing nine different biochemical indicators of DOC bioavailability in groundwater sampled from these two systems. Concentrations of DOC, total hydrolysable neutral sugars (THNS), total hydrolysable amino acids (THAA), mole% glycine of THAA, initial bacterial cell counts, bacterial growth rates, and carbon dioxide production/consumption were greater in SC samples relative to CA samples. In contrast, the mole% glucose of THNS and the aromaticity (SUVA(254)) of DOC was greater in CA samples. Each of these indicator parameters were observed to change with depth in the SC system in a manner consistent with active biodegradation. These results are uniformly consistent with the hypothesis that the bioavailability of DOC is greater in SC relative to CA groundwater samples. This, in turn, suggests that the presence/absence of a hyperbolic DO-DOC relationship may be a qualitative indicator of relative DOC bioavailability in groundwater systems.  相似文献   

MTBE, TBA, and TAME Attenuation in Diverse Hyporheic Zones     

by James E. Landmeyer  Paul M. Bradley  Donald A. Trego  Kevin G. Hale  Joseph E. Haas II 《Ground water》2010,48(1):30-41

Groundwater contamination by fuel-related compounds such as the fuel oxygenates methyl tert -butyl ether (MTBE), tert -butyl alcohol (TBA), and tert -amyl methyl ether (TAME) presents a significant issue to managers and consumers of groundwater and surface water that receives groundwater discharge. Four sites were investigated on Long Island, New York, characterized by groundwater contaminated with gasoline and fuel oxygenates that ultimately discharge to fresh, brackish, or saline surface water. For each site, contaminated groundwater discharge zones were delineated using pore water geochemistry data from 15 feet (4.5 m) beneath the bottom of the surface water body in the hyporheic zone and seepage-meter tests were conducted to measure discharge rates. These data when combined indicate that MTBE, TBA, and TAME concentrations in groundwater discharge in a 5-foot (1.5-m) thick section of the hyporheic zone were attenuated between 34% and 95%, in contrast to immeasurable attenuation in the shallow aquifer during contaminant transport between 0.1 and 1.5 miles (0.1 to 2.4 km). The attenuation observed in the hyporheic zone occurred primarily by physical processes such as mixing of groundwater and surface water. Biodegradation also occurred as confirmed in laboratory microcosms by the mineralization of U- ¹⁴C-MTBE and U-¹⁴C-TBA to ¹⁴CO₂ and the novel biodegradation of U- ¹⁴C-TAME to ¹⁴CO₂ under oxic and anoxic conditions. The implication of fuel oxygenate attenuation observed in diverse hyporheic zones suggests an assessment of the hyporheic zone attenuation potential (HZAP) merits inclusion as part of site assessment strategies associated with monitored or engineered attenuation.  相似文献   

Component correlations in structure‐specific seismic loss estimation     

Brendon A. Bradley  Dominic S. Lee 《地震工程与结构动力学》2010,39(3):237-258

This paper addresses correlations between multiple components in structure‐specific seismic loss estimation. To date, the consideration of such correlations has been limited by methodological tractability, increased computational demand, and a paucity of data for their computation. The effect of component correlations, which arises in various forms, is however a significant factor affecting the results of structure‐specific seismic loss estimation and therefore it is prudent that adequate consideration be given to their effect. This paper provides the details of a tractable and computationally efficient seismic loss estimation methodology in which correlations can be considered. Methods to determine the necessary correlations are discussed, particularly those that can be used in the absence of sufficient empirical data, for which values are suggested based on the judgement. The effects of various assumptions regarding correlations are illustrated via application to a case‐study office structure. It is observed that certain correlation assumptions can lead to errors in excess of 50% in the lognormal standard deviation in the loss given intensity and loss hazard relationships, while full consideration of partial correlations is 50 times more computationally expensive than other assumptions. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Diachronous isotopic and sedimentary responses to topographic change as indicators of mid‐Eocene hydrologic reorganization in the western United States     

Malinda L. Kent‐Corson  Andreas Mulch  Stephan A. Graham  Alan R. Carroll  Bradley D. Ritts  C. Page Chamberlain 《Basin Research》2010,22(6):829-845

Early Cenozoic terrestrial deposits in the western United States represent well‐preserved archives of climatic and tectonic processes that together shaped the Earth's surface during the demise of a large continental plateau. This study examines a Cenozoic terrestrial sedimentary sequence in the central part of the Cordilleran orogen (Montana) using sedimentologic and geochemical techniques. At ～49 Ma, we observe rapid major shifts in oxygen, carbon and strontium isotope records that are too large to directly reflect changes in meteoric water composition due to simple orographic rainout. The transition to low‐δ¹⁸O values in pedogenic carbonate in concert with changes in the composition of clastic material at ～49 Ma points to the input of evolved meteoric water to the hydrological cycle due to a change in the source of waters reaching Cordilleran intermontane regions in southwestern Montana. This drainage reorganization coincides with the initiation of magmatism and extension to the west in what is now Montana and Idaho. The sedimentological record shows evidence that depositional gradients increased in the study area ～46 Ma, ～3 Myr after the drainage reorganization occurred. This interval is most likely the time it took for extensional deformation to propagate to the study area itself. Evidence of freshening events in Laramide Basins to the southeast suggests that this drainage reorganization diverted waters to progressively fill these basins and highlights the impact of post‐plateau extension‐related landscape reorganization on river networks and lake dynamics. This study also emphasizes the importance of using multiple tools in deciphering topographic history through the study of terrestrial basin deposits, in that interpretation based on any single method employed would have compromised our ability to successfully identify the regional evolution of topography and drainage networks.  相似文献   

Multidimensional upstream weighting for multiphase transport on general grids     

Eirik Keilegavlen  Jeremy E. Kozdon  Bradley T. Mallison 《Computational Geosciences》2012,16(4):1021-1042

The governing equations for multiphase flow in porous media have a mixed character, with both nearly elliptic and nearly hyperbolic variables. The flux for each phase can be decomposed into two parts: (1) a geometry- and rock-dependent term that resembles a single-phase flux; and (2) a mobility term representing fluid properties and rock–fluid interactions. The first term is commonly discretized by two- or multipoint flux approximations (TPFA and MPFA, respectively). The mobility is usually treated with single-point upstream weighting (SPU), also known as dimensional or donor cell upstream weighting. It is well known that when simulating processes with adverse mobility ratios, SPU suffers from grid orientation effects. An important example of this, which will be considered in this work, is the displacement of a heavy oil by water. For these adverse mobility ratio flows, the governing equations are unstable at the modeling scale, rendering a challenging numerical problem. These challenges must be addressed in order to avoid systematic biasing of simulation results. In this work, we present a framework for multidimensional upstream weighting for multiphase flow with buoyancy on general two-dimensional grids. The methodology is based on a dual grid, and the resulting transport methods are provably monotone. The multidimensional transport methods are coupled with MPFA methods to solve the pressure equation. Both explicit and fully implicit approaches are considered for time integration of the transport equations. The results show considerable reduction of grid orientation effects compared to SPU, and the explicit multidimensional approach allows larger time steps. For the implicit method, the total number of non-linear iterations is also reduced when multidimensional upstream weighting is used.  相似文献   

Submarine Groundwater Discharge-Derived Nutrient Loads to San Francisco Bay: Implications to Future Ecosystem Changes     

Kimberly A. Null  Natasha T. Dimova  Karen L. Knee  Bradley K. Esser  Peter W. Swarzenski  Michael J. Singleton  Mark Stacey  Adina Paytan 《Estuaries and Coasts》2012,35(5):1299-1315

Submarine groundwater discharge (SGD) was quantified at select sites in San Francisco Bay (SFB) from radium (²²³Ra and ²²⁴Ra) and radon (²²²Rn) activities measured in groundwater and surface water using simple mass balance box models. Based on these models, discharge rates in South and Central Bays were 0.3?C7.4?m³?day^?1?m^?1. Although SGD fluxes at the two regions (Central and South Bays) of SFB were of the same order of magnitude, the dissolved inorganic nitrogen (DIN) species associated with SGD were different. In the South Bay, ammonium (NH ₄ ⁺ ) concentrations in groundwater were three-fold higher than in open bay waters, and NH ₄ ⁺ was the primary DIN form discharged by SGD. At the Central Bay site, the primary DIN form in groundwater and associated discharge was nitrate (NO ₃ ^? ). The stable isotope signatures (??¹⁵N_NO3 and ??¹⁸O_NO3) of NO ₃ ^? in the South Bay groundwater and surface waters were both consistent with NO ₃ ^? derived from NH ₄ ⁺ that was isotopically enriched in ¹⁵N by NH ₄ ⁺ volatilization. Based on the calculated SGD fluxes and groundwater nutrient concentrations, nutrient fluxes associated with SGD can account for up to 16?% of DIN and 22?% of DIP in South and Central Bays. The form of DIN contributed to surface waters from SGD may impact the ratio of NO ₃ ^? to NH ₄ ⁺ available to phytoplankton with implications to bay productivity, phytoplankton species distribution, and nutrient uptake rates. This assessment of nutrient delivery via groundwater discharge in SFB may provide vital information for future bay ecological wellbeing and sensitivity to future environmental stressors.  相似文献   

TAZ-level variation in work trip mode choice between 1990 and 2000 and the presence of rail transit     

Bradley W. Lane 《Journal of Geographical Systems》2011,13(2):147-171

Rail transit continues to be a popular alternative for cities as a tool for alleviating automobile congestion and for redeveloping areas into transit and pedestrian-friendly environments. Ideally, rail transit will draw trips away from cars, but the quantitative work that tests this notion has often been either case studies of neighborhoods, in which conclusions are tough to generalize, or citywide comparisons where important spatial variation is lost in aggregation. This study seeks to narrow this gap in the research by using multivariate analysis of covariance to isolate the effect of covariates and cities on changes in work trip mode choice at the traffic analysis zone (TAZ) level for nine cities between 1990 and 2000. The results suggest differences by city in the change at the TAZ level of the proportion of people driving alone and taking transit. Increases in transit usage were associated with cities that built rail transit, while increases in automobile commuting and decreases in transit usage were associated with cities that did not.  相似文献   

Hurricane effects on subtropical pine rocklands of the Florida Keys     

Sonali Saha  Keith Bradley  Michael S. Ross  Phillip Hughes  Thomas Wilmers  Pablo L. Ruiz  Chris Bergh 《Climatic change》2011,107(1-2):169-184

We investigate the effects of Hurricane Wilma??s storm surge (23?C24 October 2005) on the dominant tree Pinus elliottii var densa (South Florida slash pine) and rare plant species in subtropical pine rocklands of the Lower Florida Keys. We examine the role of elevation on species abundance in 1995 (Hurricane Betsy in 1965), 2005 (Hurricane Georges in 1998), and 2008 (Hurricane Wilma in 2005) to investigate if hurricanes influence abundance by eliminating plants at lower elevation on Big Pine Key, the largest island in the Lower Florida Keys. We compare densities before and after Hurricane Wilma over the 2005?C2008 sampling period and examine the role of elevation on changes in pine and rare species densities three years after Hurricane Wilma. We use elevation to assess the impact of hurricanes because elevation determined whether a location was influenced by storm surge (maximum surge of 2 m) in the Lower Florida Keys, where pine rocklands occur at a maximum elevation of 3 m. In 1995 (30 years after a major storm), elevation did not explain the abundance of South Florida slash pine or Chamaecrista lineata, but explained significant variation in abundance of Chamaesyce deltoidea. The latter two species are rare herbaceous plants restricted to pine rocklands. In 2008, 3 years after Hurricane Wilma, the positive relationship between elevation and abundance was strongest for South Florida slash pine, C. deltoidea, and C. lineata. Effects of Hurricane Wilma were not significant for rare species with wider distribution, occurring in plant communities adjacent to pine rocklands and in disturbed rocklands. Our results suggest that hurricanes drive population dynamics of South Florida slash pine and rare species that occur exclusively in pine rocklands at higher elevations. Rare species restricted to pine rocklands showed dramatic declines after Hurricane Wilma and were eliminated at elevations <0.5 m. Widely distributed rare species did not show significant changes in density after Hurricane Wilma. Abundance increased with elevation for South Florida slash pine and C. lineata after the hurricane. In an environment influenced by sea level rise, concrete plans to conserve pine ecosystems are warranted. Results from this study will help define conservation strategies by strengthening predictive understanding of plant responses to disturbance in the backdrop of sea level rise.  相似文献   

A framework for validation of seismic response analyses using seismometer array recordings     

Brendon A. Bradley 《Soil Dynamics and Earthquake Engineering》2011

A framework for the validation of computational models used to predict seismic response based on observations from seismometer arrays is presented. The framework explicitly accounts for the epistemic uncertainty related to the unknown characteristics of the ‘site’ (i.e. the problem under consideration) and constitutive model parameters. A mathematical framework which makes use of multiple prediction–observation pairs is used to improve the statistical significance of inferences regarding the accuracy and precision of the computational methodology and constitutive model. The benefits of such a formal validation framework include: (i) development of consistent methods for determination of constitutive model parameters; (ii) rigorous, objective, and unbiased assessment of the validity of various constitutive models and computational methodologies for various problem types and ground motion intensities; and (iii) an improved understanding of the uncertainties in computational model assumptions, constitutive models and their parameters, relative to other seismic response uncertainties such as ground motion variability. Details regarding the implementation of such a framework to achieve the aforementioned benefits are also addressed.  相似文献   

Reinterpreting the Importance of Oxygen‐Based Biodegradation in Chloroethene‐Contaminated Groundwater     

Paul M. Bradley 《Ground Water Monitoring & Remediation》2011,31(4):50-55

Chlororespiration is common in shallow aquifer systems under conditions nominally identified as anoxic. Consequently, chlororespiration is a key component of remediation at many chloroethene‐contaminated sites. In some instances, limited accumulation of reductive dechlorination daughter products is interpreted as evidence that natural attenuation is not adequate for site remediation. This conclusion is justified when evidence for parent compound (tetrachloroethene, PCE, or trichloroethene, TCE) degradation is lacking. For many chloroethene‐contaminated shallow aquifer systems, however, nonconservative losses of the parent compounds are clear but the mass balance between parent compound attenuation and accumulation of reductive dechlorination daughter products is incomplete. Incomplete mass balance indicates a failure to account for important contaminant attenuation mechanisms and is consistent with contaminant degradation to nondiagnostic mineralization products like CO₂. While anoxic mineralization of chloroethene compounds has been proposed previously, recent results suggest that oxygen‐based mineralization of chloroethenes also can be significant at dissolved oxygen concentrations below the currently accepted field standard for nominally anoxic conditions. Thus, reassessment of the role and potential importance of low concentrations of oxygen in chloroethene biodegradation are needed, because mischaracterization of operant biodegradation processes can lead to expensive and ineffective remedial actions. A modified interpretive framework is provided for assessing the potential for chloroethene biodegradation under different redox conditions and the probable role of oxygen in chloroethene biodegradation.  相似文献