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51.
This study examined commercial talc deposits in the U.S. and their amphibole-asbestos content. The study found that the talc-forming environment directly influenced the amphibole and amphibole-asbestos content of the talc deposit. Large talc districts in the U.S. have mined hydrothermal talcs that replaced dolostone. Hydrothermal talcs, created by siliceous fluids heated by magmas at depth, consistently lack amphiboles as accessory minerals. In contrast, mineable talc deposits that formed by contact or regional metamorphism consistently contain amphiboles, locally as asbestiform varieties. Examples of contact metamorphic deposits occur in Death Valley, California; these talc-tremolite deposits contain accessory amphibole-asbestos. Talc bodies formed by regional metamorphism always contain amphiboles, which display a variety of compositions and habits, including asbestiform. Some industrial mineral deposits are under scrutiny as potential sources of accessory asbestos minerals. Recognizing consistent relations between the talc-forming environment and amphibole-asbestos content may be used in prioritizing remediation or monitoring of abandoned and active talc mines.  相似文献   
52.
Diffusive boundary layers (DBL), sediment oxygen flux, and natural passive flow through model macrofauna burrows were compared in two benthic chambers: one with a conventional rotational stirrer and the other with a two-dimensional flow diffuser system. Oxygen microprobe profiles showed that at similar velocities the mean diffusive boundary layer (DBL) thickness induced by a conventional rotor stirrer (453±118 μm) was not significantly different to that produced by the diffuser system (403±53 μm). The rotor produced twice as much DBL spatial variability (coefficient of variation 27%) as the diffuser (CV 11%). Variability between the rotor system’s DBL transect replicates was also two times greater (average CV of 22%) compared to the diffuser (CV 14%). At equivalent stirring speeds over experimental sediments, mean O2 consumption rates were also not significantly different between the two systems. The diffuser induced consistently greater (16–37%) passive Bernoullian flow through model macrofauna borrows irrespective of the position of inhalant-exhalent openings. The rotor stimulated anomalous burrow flow regimes over a greater area of the chamber floor (36%) compared to the diffuser (23%). Depending on vent orientation the rotor was shown to reverse (exhalent to inhalant) burrow flow regimes in the central 9% of the chamber floor. This artifact of radial pressure and velocity differentials may have severe implications for tube dwelling infauna that rely on unidirectional flow. The diffuser system more closely mimicked natural two-dimensional water flow over the sediment surface and structures therein and is likely to give more representative results when measuring benthic processes within incubation devices.  相似文献   
53.
The quality of lidar and sodar wind estimates is generally judged through comparisons with mast-mounted instruments, and the resulting regressions. Evaluation of the relative merits of lidars versus sodars is complicated by the fact that lidars are generally placed close to a mast whereas sodars are generally placed some distance from a mast so that acoustic reflections off the mast are reduced. This leads to the two technologies, lidar and sodar, not being compared in similar situations. Differences arising from the two geometries can be expected to be larger in complex terrain, where the wind regime can vary significantly spatially. The current work explores these differences in moderately complex terrain. Lidar–mast comparisons are performed with the lidar close to an 80 m mast, and sodar–mast comparisons performed with the sodar 300 m from the mast. Systematic variations in estimated wind speed are found to occur with height, consistent with predictions from a simple flow model. When the lidar was moved to the sodar location, further from the mast, there were significant changes in the estimated wind speeds and a reduction in correlation with the mast-based wind speeds, as expected. However, the correlation between collocated lidar and sodar winds was high. This finding emphasizes that any comparison of two remote sensing instruments needs to be through similar experiments, and that differences in accuracy often reported for the lidar and sodar technologies are likely to be contaminated due to poor comparison configurations. A method was devised to simulate the sodar being collocated with the mast, by using the lidar–sodar measurements and the lidar–mast measurements. It was found that there was then no statistically detectable difference between lidar–mast regressions and sodar–mast regressions for the particular lidar and sodar tested. Both remote sensing instruments were also found to be good estimators of Weibull parameters, as compared with those derived from mast data. The conclusion is that the sodar measured the winds above the sodar with a similar accuracy to the lidar measuring winds above the lidar.  相似文献   
54.
Through the interconnectedness of global business, the local consumption of products and services is intervening in the hydrological cycle throughout the world to an unprecedented extent. In order to address the unsustainable use of global freshwater resources, indicators are needed which make the impacts of production systems and consumption patterns transparent. In this paper, a revised water footprint calculation method, incorporating water stress characterisation factors, is presented and demonstrated for two case study products, Dolmio® pasta sauce and Peanut M&M's® using primary production data. The method offers a simple, yet meaningful way of making quantitative comparisons between products, production systems and services in terms of their potential to contribute to water scarcity. As such, capacity is created for change through public policy as well as corporate and individual action. This revised method represents an alternative to existing volumetric water footprint calculation methods which combine green and blue water consumption from water scarce and water abundant regions such that they give no clear indication about where the actual potential for harm exists.  相似文献   
55.
Profiles of wind and turbulence over an urban area evolve with fetch in response to surface characteristics. Sodar measurements, taken on 22 April 2002 during the Salford Experiment in the UK (Salfex), are here related to upstream terrain. A logarithmic layer up to z = 65m was observed in all half-hour averaged profiles. Above this height the profile showed a different vertical gradient, suggesting a change in surface cover upstream. The drag coefficient varied by a factor of two over only a 20° direction change. Turbulence intensity (σ x ) for each wind component (x) decreased with height, but the ratio suggested an underestimate of σ u compared to previous results. Mean urban and suburban cover fraction within the source area for each height decreased sharply between z = 20 and 50m, increasing slightly above. The near-convergence of cover fractions thus occured for source areas of minimum length ≈ 2,200 m. In comparison, the mean length scale of heterogeneity L P was calculated from surface cover data to be 1,284 m, and the corresponding mean blending height h b was 175 m. Finally, the mean streamline angle, α, was negative and the magnitude decreased with height. An exponential fit to α for z ≤ 65m gave an e-folding height scale of 159 m. A simple relationship between this height scale and L P was assumed, giving L P ≈ 1,080 m, which is in reasonable agreement with the estimate from surface cover type. The results suggest that more emphasis is required on modelling and measuring surface-layer flow over heterogeneous urban canopies.  相似文献   
56.
The frontier for ultraviolet studies of active galactic nuclei is the time domain: in particular, reverberation mapping of the broad emission-line region can lead to determination of the geometry and kinematics of accretion flows and winds as well as accurate measurement of the masses of the central black holes. Here we review progress to date and describe how additional advances can be made with an ultraviolet telescope of modest aperture.  相似文献   
57.
Refractory Ti-bearing minerals in the calcium-, aluminum-rich inclusion (CAI) Inti, recovered from the comet 81P/Wild 2 sample, were examined using analytical (scanning) transmission electron microscopy (STEM) methods including imaging, nanodiffraction, energy-dispersive spectroscopy (EDX) and electron energy loss spectroscopy (EELS). Inti fassaite (Ca(Mg,Ti,Al)(Si,Al)2O6) was found to have a Ti3+/Ti4+ ratio of 2.0 ± 0.2, consistent with fassaite in other solar system CAIs. The oxygen fugacity (logfO2) of formation estimated from this ratio, assuming equilibration among phases at 1509 K, is −19.4 ± 1.3. This value is near the canonical solar nebula value (−18.1 ± 0.3) and in close agreement with that reported for fassaite-bearing Allende CAIs (−19.8 ± 0.9) by other researchers using the same assumptions. Nanocrystals of osbornite (Ti(V)N), 2–40 nm in diameter, are embedded as inclusions within gehlenite, spinel and diopside in Inti. Vanadium is heterogeneously distributed within some osbornite crystals. Compositions range from pure TiN to Ti0.36V0.64N. The possible presence of oxide and carbide in solid solution with the osbornite was evaluated. The osbornite may contain O, but C is not present at detectable levels. The presence of osbornite, likely a refractory early condensate, together with the other refractory minerals in Inti, indicates that the parent comet contains solids that condensed closer to the proto-sun than the distance at which the parent comet itself accreted. The estimated oxygen fugacity and the reported isotopic and chemical compositions are consistent with Inti originating in the inner solar system like other meteoritic CAIs. These results provide insight for evaluating the validity of models of radial mass transport dynamics in the early solar system. The oxidation environments inferred for the Inti mineral assemblage are inconsistent with an X-wind formation scenario. In contrast, radial mixing models that allow accretion of components from different heliocentric distances can satisfy the observations from the cometary CAI Inti.  相似文献   
58.
The Toodoggone district comprises Upper Triassic to Lower Jurassic Hazelton Group Toodoggone Formation volcanic and sedimentary rocks, which unconformably overlie submarine island-arc volcanic and sedimentary rocks of the Lower Permian Asitka Group and Middle Triassic Takla Group, some of which are intruded by Upper Triassic to Lower Jurassic plutons and dikes of the Black Lake suite. Although plutonism occurred episodically from ca. 218 to 191 Ma, the largest porphyry Cu–Au ± Mo systems formed from ca. 202 to 197 Ma, with minor mineralization occurring from ca. 197 to 194 Ma. Porphyry-style mineralization is hosted by small-volume (<1 km3), single-phase, porphyritic igneous stocks or dikes that have high-K calc-alkaline compositions and are comparable with volcanic-arc granites. The Fin porphyry Cu–Au–Mo deposit is anomalous in that it is 16 m.y. older than any other porphyry Cu–Au ± Mo occurrence in the district and has lower REEs. All porphyry systems are spatially restricted to exposed Asitka and Takla Group basement rocks, and rarely, the lowest member of the Hazelton Group (i.e., the ca. 201 Ma Duncan Member). The basement rocks to intrusions are best exposed in the southern half of the district, where high rates of erosion and uplift have resulted in their preferential exposure. In contrast, low- and high-sulfidation epithermal systems are more numerous in the northern half of the district, where the overlying Hazelton Group rocks dominate exposures. Cogenetic porphyry systems might also exist in the northern areas; however, if they are present, they are likely to be buried deeply beneath Hazelton Group rocks. High-sulfidation epithermal systems formed at ca. 201 to 182 Ma, whereas low-sulfidation systems were active at ca. 192 to 162 Ma. Amongst the studied epithermal systems, the Baker low-sulfidation epithermal deposit displays the strongest demonstrable genetic link with magmatic fluids; fluid inclusion studies demonstrate that its ore fluids were hot (>468°C), saline, and deposited metals at deep crustal depths (>2 km). Sulfur, C, O, and Pb isotope data confirm the involvement of a magmatic fluid, but also suggest that the ore fluid interacted with Asitka and Takla Group country rocks prior to metal deposition. In contrast, in the Shasta, Lawyers, and Griz-Sickle low-sulfidation epithermal systems, there is no clear association with magmatic fluids. Instead, their fluid inclusion data indicate the involvement of low-temperature (175 to 335°C), low-salinity (1 to 11 equiv. wt.% NaCl) fluids that deposited metals at shallow depths (<850 m). Their isotope (i.e., O, H, Pb) data suggest interaction between meteoric and/or metamorphic ore fluids with basement country rocks.  相似文献   
59.
60.
Permian to Cretaceous mélange of the McHugh Complex on the Kenai Peninsula, south-central Alaska includes blocks and belts of graywacke, argillite, limestone, chert, basalt, gabbro, and ultramafic rocks, intruded by a variety of igneous rocks. An oceanic plate stratigraphy is repeated hundreds of times across the map area, but most structures at the outcrop scale extend lithological layering. Strong rheological units occur as blocks within a matrix that flowed around the competent blocks during deformation, forming broken formation and mélange. Deformation was noncoaxial, and disruption of primary layering was a consequence of general strain driven by plate convergence in a relatively narrow zone between the overriding accretionary wedge and the downgoing, generally thinly sedimented oceanic plate. Soft-sediment deformation processes do not appear to have played a major role in the formation of the mélange. A model for deformation at the toe of the wedge is proposed in which layers oriented at low angles to σ1 are contracted in both the brittle and ductile regimes, layers at 30–45° to σ1 are extended in the brittle regime and contracted in the ductile regime, and layers at angles greater than 45° to σ1 are extended in both the brittle and ductile regimes. Imbrication in thrust duplexes occurs at deeper levels within the wedge. Many structures within mélange of the McHugh Complex are asymmetric and record kinematic information consistent with the inferred structural setting in an accretionary wedge. A displacement field for the McHugh Complex on the lower Kenai Peninsula includes three belts: an inboard belt of Late Triassic rocks records west-to-east-directed slip of hanging walls, a central belt of predominantly Early Jurassic rocks records north–south directed displacements, and Early Cretaceous rocks in an outboard belt preserve southwest–northeast directed slip vectors. Although precise ages of accretion are unknown, slip directions are compatible with inferred plate motions during the general time frame of accretion of the McHugh Complex. The slip vectors are interpreted to preserve the convergence directions between the overriding and underriding plates, which became more oblique with time. They are not considered indicative of strain partitioning into belts of orogen-parallel and orogen-perpendicular displacements, because the kinematic data are derived from the earliest preserved structures, whereas fabrics related to strain partitioning would be expected to be superimposed on earlier accretion-related fabrics.  相似文献   
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