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191.
Disk-integrated and disk-resolved measurements of Mercury’s surface obtained by both the Mercury Dual Imaging System (MDIS) and the Mercury Atmospheric and Surface Composition Spectrometer (MASCS) onboard the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft were analyzed and compared with previous ground-based observations of Mercury at 11 wavelengths. The spectra show no definitive absorption features and display a red spectral slope (increasing reflectance with increasing wavelength) typical of space-weathered rocky surfaces. The MDIS spectra show evidence of phase reddening, which is not observed in the MASCS spectra. The MDIS spectra are commensurate with ground-based observations to within 10%, whereas the MASCS spectra display greater discrepancies with ground-based observations at near-infrared wavelengths. The derived photometric calibrations provide corrections within 10% for observations taken at phase angles less than ∼100°. The derived photometric properties are indicative of a more compact regolith than that of the lunar surface or of average S-type asteroids. The photometric roughness of the surface is also much smoother than the Moon’s. The calculated geometric albedo (reflectance at zero phase) is higher than lunar values. The lower reflectance of immature units on Mercury compared with immature units on the Moon, in conjunction with the higher geometric albedo, is indicative of more complicated grain structures within Mercury’s regolith.  相似文献   
192.
El Teniente porphyry copper deposit, the world’s greatest intrusion-related Cu–Mo ore body, is hosted within basaltic–andesitic volcanic and gabbroic rocks (mafic complex). This ore body is strongly affected by multiple events of alteration/mineralization with pervasive potassic and chloritic alteration and coetaneous with associated copper mineralization. We present paleomagnetic results obtained from oriented samples at four locations within the mine and from two drill cores, 200 and 400 m long, respectively. Samples are representative of all the main hydrothermally altered rock units, with emphasis on the mafic host rock and dacitic (Teniente dacite porphyry) and dioritic porphyry intrusions. Magnetic experiments [hysteresis loop, isothermal remanent magnetization (IRM), kT curves, thermal, and alternating field demagnetization] show the presence of prevailing magnetite. Microscope and SEM observations show two families of magnetite, (a) large multidomain magnetite grains, associated with biotite and chlorite of various different hydrothermal alteration events, and (b) abundant small to medium grain-size magnetite (<10 μm) contained within plagioclase, either related to an early Na–Ca–Fe alteration or included within plagioclase during magmatic crystal growth. While the Teniente dacite porphyry and the quartz diorite–tonalite have low magnetic susceptibility (<0.0005 SI) and low natural remanent magnetization (NRM, 10−4–10−3 Am−1), the mineralized mafic host rocks have usually high susceptibility (>0.01 and up to 0.2 SI) with NRM in the range 0.1–2 Am−1. Most mafic complex rock samples have univectorial magnetizations during alternating field or thermal demagnetization. Within the mine, the magnetic polarity is spatially distributed. In the northern part of the deposit, the Teniente dacite porphyry, the associated hydrothermal breccias, and the hosting mafic complex record a reverse polarity magnetization, also observed in the El Teniente sub-6 mine sector immediately to the east and southeast. In the eastern part of the deposit, a normal polarity is observed for samples of the mafic complex from the two long drill cores. There is no evidence for superimposed magnetizations of opposite polarities in samples of the mafic complex. Anhysteretic remanent magnetization (ARM) in a DC field of 40 μT and NRM have similar magnitude and comparable behavior upon alternating field demagnetization. The well-defined strong remanent magnetizations associated with high unblocking temperatures (>500°C) indicate an acquisition of remanent magnetization during mineralization by circulating high temperature fluids related with ore deposition. Paleomagnetic results and the recorded polarity zonation suggest multiple mineralization events occurred at El Teniente, each one with its own evolution stages, superimposed within the district. These results indicate that a simplified broad four-stage model for El Teniente, as presented and overly employed by many authors, divided in (1) late magmatic, (2) main hydrothermal, (3) late hydrothermal, and (4) posthumous stage, does not recognize various short-lived single mineralization events, some superimposed and some distinctly separated in time and space. There is no paleomagnetic evidence for post-mineralization deformation  相似文献   
193.
Jarosite phases are common minerals in acidic, sulfate-rich environments. Here, we report heat capacities (C p) and standard entropies (S°) for a number of jarosite samples. Most samples are close to the nominal composition AFe3(SO4)2(OH)6, where A = K, Na, Rb, and NH4. One of the samples has a significant number of defects on the Fe sites and is called the defect jarosite; others are referred to as A-jarosite. The samples, their compositions, and the entropies at T = 298.15 K are:
Sample Chemical composition S o/(J mol−1 K−1)
K-jarosite K0.92(H3O)0.08Fe2.97(SO4)2(OH)5.90(H2O)0.10 427.4 ± 0.7
Na-jarosite Na0.95(H3O)0.05Fe3.00(SO4)2(OH)6.00 436.4 ± 4.4
Rb-jarosite RbFe2.98(SO4)2(OH)5.95(H2O)0.05 411.9 ± 4.1
NH4-jarosite (NH4)0.87(H3O)0.13Fe3.00(SO4)2(OH)6.00 447.2 ± 4.5
Defect jarosite K0.94(H3O)0.06Fe2.34(SO4)2(OH)4.01(H2O)1.99 412.7 ± 4.1
There are additional configurational entropies of 13.14 and 8.23 J mol−1 K−1 in defect and NH4-jarosite, respectively. A detailed analysis of the synchrotron X-ray diffraction patterns showed a large anisotropic peak broadening for defect and NH4-jarosite. The fits to the low-temperature (approx. <12 K) C p data showed that our samples can be divided into two groups. The first group is populated by the K-, Na-, Rb-, and NH4-jarosite samples, antiferromagnetic at low temperatures. The second group contains the H3O-jarosite (studied previously) and the defect jarosite. H3O- and defect jarosite are spin glasses and their low-T C p was fit with the expression C p = γT + ΣB j T j , where j = (3, 5, 7, 9). The linear term is typical for spin glasses and the sum represents the lattice contribution to C p. Surprisingly, the C p of the K-, Na-, Rb-, and NH4-jarosite samples, which are usually considered to be antiferromagnetic at low temperatures, also contains a large linear term. This finding suggests that even these phases do not order completely, but have a partial spin-glass character below their Néel transition temperature.  相似文献   
194.
A controlled release of CO2 was conducted at a field site in Bozeman, Montana, USA in July of 2008 in a multi-laboratory study of near surface transport and detection technologies. The development of a subsurface CO2 plume near the middle packer section of the horizontal release was studied using soil-gas and surface flux measurements of CO2. A perfluorocarbon tracer was added to the CO2 released from this section of the horizontal well, and the development of atmospheric plumes of the tracer was studied under various meteorological conditions using horizontal and vertical grids of monitors containing sorbent material to collect the tracer. This study demonstrated the feasibility of using remote sensing for the ultra low level detection of atmospheric plumes of tracers as means to monitor the near surface leakage of sequestered CO2.  相似文献   
195.
Hydrologically driven mass wasting in the form of landslides on steep slopes is a worldwide occurrence. High-profile events in, for example, Brazil, Chile, the Philippines, Puerto Rico, and Venezuela during the last three decades all clearly illustrate, based upon significant losses of life and property, that hydrologically driven slope instability in developed (urban) areas can be a major geologic/environmental hazard. The focus of this study is the 1973 hydrologically driven Lerida Court landslide in Portola Valley, CA, USA. Physics-based hydrologic-response simulation, with the comprehensive Integrated Hydrology Model, was employed to forensically estimate the spatiotemporal pore pressure distributions for the Lerida Court site. Slope stability, driven by the simulated pore pressure dynamics, was estimated for the Lerida Court site with the infinite slope/Factor of Safety approach. The pore pressure dynamics for the Lerida Court site were reasonably captured by the hydrologic-response simulation. The estimated time of slope failure for the Lerida Court site compares well with field observations. A recommendation is made that hydrologically driven slope stability estimates including variably saturated subsurface flow be standard protocol for development sites in steep urban settings.  相似文献   
196.
Assessments of phytoplankton diversity in Sabah waters, North Borneo, have primarily relied on morphology-based identification, which has inherent biases and can be time-consuming. Next-Generation Sequencing (NGS) technology has been shown to be capable of overcoming several limitations of morphology-based methods. Samples were collected from the Sepanggar Bay over the course of the year 2018 in different monsoon seasons. Morphology-based identification and NGS sequencing of the V8–V9 region of the 18S LSU rDNA were used to investigate the diversity of the phytoplankton community. Microscopy and NGS showed complementary results with more diatom taxa detected by microscopy whereas NGS detected smaller and rarer taxa. The harmful algal genera in the study site comprised of Skeletonema, Margalefidinium, Pyrodinium, Takayama, and Alexandrium as detected by NGS. This study showed that that an integrative approach of both morphological and molecular techniques could provide more comprehensive information about the phytoplankton community as the approach captured quantitative variability as well as the diversity of phytoplankton species.  相似文献   
197.
A variety of proposed activities to mitigate greenhouse gas emissions will impact on scarce water resources, which are coming under increasing pressure in many countries due to population growth and shifting weather patterns. However, the integrated analysis of water and carbon impacts has been given limited attention in greenhouse mitigation planning. In this Australian case study, we analyse a suite of 74 mitigation measures ranked as highest priority by one influential analysis, and we find that they have highly variable consequences for water quantity. We find: (1) The largest impacts result from land-based sequestration, which has the potential to intercept large quantities of water and reduce catchment yields, estimated to exceed 100 Mm3/MtCO2-e of carbon mitigated (100,000 l per tonne CO2-e). (2) Moderate impacts result from some renewable power options, including solar thermal power with a water cost estimated at nearly 4 Mm3/MtCO2-e. However, the water impacts of solar thermal power facilities could be reduced by designing them to use existing power-related water supplies or to use air or salt-water cooling. (3) Wind power, biogas, solar photovoltaics, energy efficiency and operational improvements to existing power sources can reduce water demand through offsetting the water used to cool thermal power generation, with minor savings estimated at 2 Mm3/MtCO2-e and amounting to nearly 100 Mm3 of water saved in Australia per annum in 2020. This integrated analysis significantly changes the attractiveness of some mitigation options, compared to the case where water impacts are not considered.  相似文献   
198.
Natural variability of summer rainfall over China in HadCM3   总被引:1,自引:0,他引:1  
Summer rainfall over China has shown decadal variability in the past half century, which has resulted in major north–south shifts in rainfall with important implications for flooding and water resource management. This study has demonstrated how multi-century climate model simulations can be used to explore interdecadal natural variability in the climate system in order to address important questions around recent changes in Chinese summer rainfall, and whether or not anthropogenic climate change is playing a role. Using a 1,000-year simulation of HadCM3 with constant pre-industrial external forcing, the dominant modes of total and interdecadal natural variability in Chinese summer rainfall have been analysed. It has been shown that these modes are comparable in magnitude and in temporal and spatial characteristics to those observed in the latter part of the twentieth century. However, despite 1,000 years of model simulation it has not been possible to demonstrate that these modes are related to similar variations in the global circulation and surface temperature forcing occurring during the latter half of the twentieth century. This may be in part due to model biases. Consequently, recent changes in the spatial distribution of Chinese summer rainfall cannot be attributed solely to natural variability, nor has it been possible to eliminate the likelihood that anthropogenic climate change has been the driving factor. It is more likely that both play a role.  相似文献   
199.
四川盆地震旦系灯影组葡萄状白云岩成因   总被引:1,自引:1,他引:0       下载免费PDF全文
四川盆地震旦系灯影组发育巨厚的白云岩,其中灯影组二段和四段发育大量具有各种形态的葡萄状白云岩,其直径最长可达75cm,有的平行于层面,有的穿层。剖面资料表明,葡萄状白云岩发育多期等厚环边胶结物,中部残留大量未充填的不规则洞穴,这成为与岩溶喀斯特作用相关的地下溶蚀作用的证据。围岩泥晶白云石为早期海水中原生结晶的产物,后来的胶结物可划分为4期: (1)自泥晶化白云石(部分样品中可见)作为最早的一期胶结物,由于各种生物化学作用和生物作用的影响而紧贴着围岩发育;(2)第2期胶结物纤维状白云石可能为海水中直接沉淀的产物,经历后期成岩作用后,具有完全有序的结构,晶胞参数接近理想值;(3)细—中晶白云石为第3期胶结物,包含纤维状白云石溶蚀残余,形成于构造抬升之后的近地表大气淡水环境;(4)第4期胶结物中—粗晶白云石为埋藏环境下直接结晶的产物,充填了孔洞中心,残留部分未充填孔洞。灯影组受到了岩溶喀斯特作用、胶结作用以及白云石化作用等成岩作用的影响,其中与葡萄状白云岩有关的岩溶喀斯特作用对于灯影组储集层的发育至关重要。对灯影组葡萄状白云岩的研究,不仅有助于深入探讨灯影组储集层成因和演化及灯影组白云岩的成因,而且有助于指导四川盆地前寒武系油气勘探。  相似文献   
200.
Numerous approaches exist for the prediction of the settlement improvement offered by the vibro-replacement technique in weak or marginal soil deposits. The majority of the settlement prediction methods are based on the unit cell assumption, with a small number based on plane strain or homogenisation techniques. In this paper, a comprehensive review and assessment of the more popular settlement prediction methods is carried out with a view to establishing which method(s) is/are in best agreement with finite element predictions from a series of PLAXIS 2D axisymmetric analyses on an end-bearing column. The Hardening Soil Model in PLAXIS 2D has been used to model the behaviour of both the granular column material and the treated soft clay soil. This study has shown that purely elastic settlement prediction methods overestimate the settlement improvement for large modular ratios, while the methods based on elastic–plastic theory are in better agreement with finite element predictions at higher modular ratios. In addition, a parameter sensitivity study has been carried out to establish the influence of a range of different design parameters on predictions obtained using a selection of elastic–plastic methods.  相似文献   
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