Gold scavenged by bismuth melts: An example from Alpine shear-remobilizates in the Highiş Massif, Romania     

C. L. Ciobanu  N. J. Cook  F. Damian  G. Damian 《Mineralogy and Petrology》2006,87(3-4):351-384

Summary Gold mineralization occurs in the Şoimuş Ilii vein, the main Cu prospect in the Highiş Massif, Western Apuseni Mts., Romania. The Highiş Massif is part of the Highiş Biharia Shear Zone, a 320–300 Ma Variscan greenschist belt, with a 114–100 Ma Alpine overprint. In Highiş, phyllonites enclose an igneous core consisting of an Early Permian basic complex intruded by Middle Permian granitoids. The vein is hosted within basalt hornfels at its contact with the 264 Ma Jernova granite. Gold is not only present as native gold, but also as jonassonite (ideally AuBi₅S₄). The latter occurs as inclusions 1–30 μm in size in chalcopyrite; microanalysis gives the empirical formulae Au_1.02(Pb_0.47Bi_4.51)_4.98S_4. The two Au minerals are spatially associated with Bi–(Pb) sulfosalts (oversubstituted bismuthinite, cosalite) and sulfotellurides/selenides (ingodite, ikunolite and laitakarite) in blebs/patches, mainly hosted in chalcopyrite. This Au–Bi–Te association overprints an earlier, chalcopyrite-quartz assemblage, occurring as trails along discrete zones of brecciation that crosscut former mineral boundaries. Curvilinear and cuspate boundary textures within the blebs/patches suggest deposition in a molten form. Mineral associations in combination with phase relations indicate that the Au–Bi–Te association formed as a result of melting of pre-existing native Bi (and possibly sulfosalts) at 400 °C under sulfidation conditions. These melts incorporated Au, Pb, Te and S as they moved in the vein during shearing and were locked within dilational sites. Native Bi occurs as coarse aggregates along vein margins, but in the Au–Bi–Te association, it is present only as small droplets in shear gashes, never together with other Bi- and Au-minerals. The Bi-derived melts are part of an internal remobilizate which also includes chlorite and adularia. Minerals in the system Au–Bi–Te were deposited from a neutral low reducing fluid during Alpine shearing in the Early Cretaceous. The fluid also assisted solid-state mobilisation of chalcopyrite and cobaltite. This study illustrates the significant potential of Bi, a low melting-point chalcophile element (LMCE), to act as Au scavenger at temperatures as low as 400 °C.  相似文献   

Tethyan, Mediterranean, and Pacific analogues for the Neoproterozoic–Paleozoic birth and development of peri-Gondwanan terranes and their transfer to Laurentia and Laurussia     

J.Duncan Keppie  R.Damian Nance  J.Brendan Murphy  J. Dostal 《Tectonophysics》2003,365(1-4):195

Modern Tethyan, Mediterranean, and Pacific analogues are considered for several Appalachian, Caledonian, and Variscan terranes (Carolina, West and East Avalonia, Oaxaquia, Chortis, Maya, Suwannee, and Cadomia) that originated along the northern margin of Neoproterozoic Gondwana. These terranes record a protracted geological history that includes: (1) 1 Ga (Carolina, Avalonia, Oaxaquia, Chortis, and Suwannee) or 2 Ga (Cadomia) basement; (2) 750–600 Ma arc magmatism that diachronously switched to rift magmatism between 590 and 540 Ma, accompanied by development of rift basins and core complexes, in the absence of collisional orogenesis; (3) latest Neoproterozoic–Cambrian separation of Avalonia and Carolina from Gondwana leading to faunal endemism and the development of bordering passive margins; (4) Ordovician transport of Avalonia and Carolina across Iapetus terminating in Late Ordovician–Early Silurian accretion to the eastern Laurentian margin followed by dispersion along this margin; (5) Siluro-Devonian transfer of Cadomia across the Rheic Ocean; and (6) Permo-Carboniferous transfer of Oaxaquia, Chortis, Maya, and Suwannee during the amalgamation of Pangea. Three potential models are provided by more recent tectonic analogues: (1) an “accordion” model based on the orthogonal opening and closing of Alpine Tethys and the Mediterranean; (2) a “bulldozer” model based on forward-modelling of Australia during which oceanic plateaus are dispersed along the Australian plate margin; and (3) a “Baja” model based on the Pacific margin of North America where the diachronous replacement of subduction by transform faulting as a result of ridge–trench collision has been followed by rifting and the transfer of Baja California to the Pacific Plate. Future transport and accretion along the western Laurentian margin may mimic that of Baja British Columbia. Present geological data for Avalonia and Carolina favour a transition from a “Baja” model to a “bulldozer” model. By analogy with the eastern Pacific, we name the oceanic plates off northern Gondwana: Merlin (≡Farallon), Morgana (≡Pacific), and Mordred (≡Kula). If Neoproterozoic subduction was towards Gondwana, application of this combined model requires a total rotation of East Avalonia and Carolina through 180° either during separation (using a western Transverse Ranges model), during accretion (using a Baja British Columbia “train wreck” model), or during dispersion (using an Australia “bulldozer” model). On the other hand, Siluro-Devonian orthogonal transfer (“accordion” model) from northern Africa to southern Laurussia followed by a Carboniferous “Baja” model appears to best fit the existing data for Cadomia. Finally, Oaxaquia, Chortis, Maya, and Suwannee appear to have been transported along the margin of Gondwana until it collided with southern Laurentia on whose margin they were stranded following the breakup of Pangea. Forward modeling of a closing Mediterranean followed by breakup on the African margin may provide a modern analogue. These actualistic models differ in their dictates on the initial distribution of the peri-Gondwanan terranes and can be tested by comparing features of the modern analogues with their ancient tectonic counterparts.  相似文献   

The oxidation states of copper and iron in mineral sulfides, and the oxides formed on initial exposure of chalcopyrite and bornite to air     

Siew Wei Goh  Robert N. Lamb  Damian Moran 《Geochimica et cosmochimica acta》2006,70(9):2210-2228

Metal L_2,3, sulfur K and oxygen K near-edge X-ray absorption fine structure (NEXAFS) spectra for chalcopyrite, bornite, chalcocite, covellite, pyrrhotite and pyrite have been determined from single-piece natural mineral specimens in order to assess claims that chalcopyrite should be regarded as Cu^IIFe^IIS₂ rather than Cu^IFe^IIIS₂, and that copper oxide species are the principal initial oxidation products on chalcopyrite and bornite exposed to air. Spectra were obtained using both fluorescence and electron yields to obtain information representative of the bulk as well as the surface. Where appropriate, NEXAFS spectra have been interpreted by comparison with the densities of unfilled states and simulated spectra derived from ab initio calculations using primarily the FEFF8 code and to a lesser extent WIEN2k. Metal 2p and S 2p photoelectron spectra excited by monochromatised Al K_α X-rays were determined for each of the surfaces characterised by NEXAFS spectroscopy. The X-ray excited Cu LMM Auger spectrum was also determined for each copper-containing sulfide. FEFF8 calculations were able to simulate the experimental NEXAFS spectra quite well in most cases. For covellite and chalcocite, it was found that FEFF8 did not provide a good simulation of the Cu L₃-edge spectra, but WIEN2k simulations were in close agreement with the experimental spectra. Largely on the basis of these simulations, it was concluded that there was no convincing evidence for chalcopyrite to be represented as Cu^IIFe^IIS₂, and no strong argument for some of the Cu in either bornite or covellite to be regarded as Cu(II). The ab initio calculations for chalcopyrite and bornite indicated that the density of Cu d-states immediately above the Fermi level was sufficient to account for the Cu L₃-edge absorption spectrum, however these incompletely filled Cu d-states should not be interpreted as indicating some Cu(II) in the sulfide structure. It was also concluded that the X-ray absorption spectra were quite consistent with the initial oxidation products on chalcopyrite and bornite surfaces being iron oxide species, and inconsistent with the concomitant formation of copper-oxygen species.  相似文献   

Observations and implications of damage from the magnitude Mw 6.3 Christchurch, New Zealand earthquake of 22 February 2011   总被引：1，自引：1，他引：0  

Sean Wilkinson  Damian Grant  Elizabeth Williams  Sara Paganoni  Stuart Fraser  David Boon  Anna Mason  Matthew Free 《Bulletin of Earthquake Engineering》2013,11(1):107-140

This paper describes the observations made by a reconnaissance team following the 22nd February 2011, M_w 6.3, Christchurch, New Zealand earthquake (GNS Science, 2011). The team comprised of members of the UK based Earthquake Engineering Field Investigation Team who spent 5 days collecting observations on damage resulting from the earthquake. Although the magnitude of this earthquake was not particularly high (M_w 6.3), the shallow focus and close proximity resulted in locally very high ground motions, widespread damage and 182 fatalities. The earthquake is also particularly notable for the widespread liquefaction it caused, landslides and rockfalls in the hills south of Christchurch, and the significant damage suffered by unreinforced masonry and historic structures. Over wide areas of central Christchurch, recorded accelerations were in excess of those required by the current New Zealand seismic loadings standard (NZS1170.5:2004: Standards New Zealand 2004) and therefore the earthquake presented a valuable opportunity to assess performance of modern buildings under code-level ground acceleration.  相似文献   

Potential geodynamic relationships between the development of peripheral orogens along the northern margin of Gondwana and the amalgamation of West Gondwana     

J. Brendan Murphy  Sergei Pisarevsky  R. Damian Nance 《Mineralogy and Petrology》2013,107(5):635-650

The Neoproterozoic-Early Cambrian evolution of peri-Gondwanan terranes (e.g. Avalonia, Carolinia, Cadomia) along the northern (Amazonia, West Africa) margin of Gondwana provides insights into the amalgamation of West Gondwana. The main phase of tectonothermal activity occurred between ca. 640–540 Ma and produced voluminous arc-related igneous and sedimentary successions related to subduction beneath the northern Gondwana margin. Subduction was not terminated by continental collision so that these terranes continued to face an open ocean into the Cambrian. Prior to the main phase of tectonothermal activity, Sm-Nd isotopic studies suggest that the basement of Avalonia, Carolinia and part of Cadomia was juvenile lithosphere generated between 0.8 and 1.1 Ga within the peri-Rodinian (Mirovoi) ocean. Vestiges of primitive 760–670 Ma arcs developed upon this lithosphere are preserved. Juvenile lithosphere generated between 0.8 and 1.1 Ga also underlies arcs formed in the Brazilide Ocean between the converging Congo/São Francisco and West Africa/Amazonia cratons (e.g. the Tocantins province of Brazil). Together, these juvenile arc assemblages with similar isotopic characteristics may reflect subduction in the Mirovoi and Brazilide oceans as a compensation for the ongoing breakup of Rodinia and the generation of the Paleopacific. Unlike the peri-Gondwanan terranes, however, arc magmatism in the Brazilide Ocean was terminated by continent-continent collisions and the resulting orogens became located within the interior of an amalgamated West Gondwana. Accretion of juvenile peri-Gondwanan terranes to the northern Gondwanan margin occurred in a piecemeal fashion between 650 and 600 Ma, after which subduction stepped outboard to produce the relatively mature and voluminous main arc phase along the periphery of West Gondwana. This accretionary event may be a far-field response to the breakup of Rodinia. The geodynamic relationship between the closure of the Brazilide Ocean, the collision between the Congo/São Francisco and Amazonia/West Africa cratons, and the tectonic evolution of the peri-Gondwanan terranes may be broadly analogous to the Mesozoic-Cenozoic closure of the Tethys Ocean, the collision between India and Asia beginning at ca. 50 Ma, and the tectonic evolution of the western Pacific Ocean.  相似文献   

Effects of soil surface components on soil hydrological behaviour in a dry Mediterranean environment (Southern Spain)   总被引：2，自引：0，他引：2  

Jose Damian Ruiz Sinoga  Juan Francisco Martinez Murillo 《Geomorphology》2009,108(3-4):234-245

Various researchers have studied the spatial pattern of soil surface components such as vegetation, rock fragments, bare soil, litter and surface crusts, as a key factor of hydrological behaviour in Mediterranean settings with heterogeneous patches of vegetation cover and strong human impact. The studies indicate that there is a mosaic of patches that generate run-off or infiltrate overland flow, distributed in various ways along hillslopes. Few of these studies, however, have looked at areas underlain by metamorphic rocks such as phyllites or schists. This study analysed the temporal and spatial variability of the effects of soil surface components on hydrological processes in a small dry Mediterranean catchment underlain by metamorphic rocks. A systematic sampling of multiple sites throughout a hydrological year was carried out.We related the hydrological behaviour of soil surface components to 1) their position along the hillslope, 2) the distance of existing vegetation tussocks from the line of run-off, 3) rainfall intensity and 4) the main physical/chemical soil properties affecting infiltration processes. Statistical analysis was used to check the validity of the relationships. The results show that soil surface components have highly variable effects, in both space and time, on soil hydrological behaviour. These effects particularly depend on the location along the line of maximum slope and the intensity of preceding rainfall, whose interaction defines soil hydrological status. These results are similar to those for other Mediterranean settings with different lithology, in that the succession of contributing patches are hydrologically interconnected along a hillslope. The variables used and the grouping of explanatory variables through principal component analyses were found to be suitable for discussing the spatial distribution of soil surface components in the hydrologically dynamic environment of the study area.  相似文献   

Variations of phytoplankton productivity and biomass over an annual cycle in Saanich Inlet,a British Columbia fjord     

Damian S. Grundle  David A. Timothy  Diana E. Varela 《Continental Shelf Research》2009

Saanich Inlet is a highly productive temperate fjord with the capability to record inter-annual patterns of water-column primary production in undisturbed laminated sediments. We investigated spatial and temporal variations in primary productivity, total and size-fractionated phytoplankton chl a, dissolved nutrients, temperature and salinity at the head and mouth of Saanich Inlet from May 2005 to November 2006. New primary productivity was also measured from May to October 2006. During the growing season (spring, summer and fall), primary productivity was 1.5 times higher at the mouth than at the head of Saanich Inlet and, averaged across stations, total productivity was 460 g C m⁻² y⁻¹. Average new productivity was 53% and 58% of total primary productivity at the head and mouth of the inlet, respectively, and during the growing season micro-phytoplankton (>20 μm; mainly diatoms) was the most abundant size-class of phytoplankton. These rates of primary production are as high as or higher than those measured in other fjords, possibly because of a tidally-driven fortnightly gravity exchange that supplies nutrients to surface waters that enhance biological production when nutrients would otherwise be limiting. This exchange delivers nutrients at least as far inland as the head station, while nutrients associated with an eddy near the mouth may be the cause of even higher productivity there. We discuss the impact of these nutrient sources to Saanich Inlet on the records of paleoproduction generated from two Ocean Drilling Program cores extracted from this fjord, and suggest that the fortnightly exchange buffers variations in nutrient supply occurring on sub-decadal or decadal scales.  相似文献   

“Miles wide and miles deep” – Exploring the depth and breadth of geoscience during the first ten years of Geoscience Frontiers     

Christopher J. Spencer  Nick M.W. Roberts  R. Damian Nance 《地学前缘(英文版)》2019,10(3):1219-1221

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'Anywhere you can talk about how you feel is better': Young people's experiences of sexual health messages     

Tara M. Coleman  Robin A. Kearns  Damian C. A. Collins 《New Zealand geographer》2010,66(1):61-73

Despite increased sexuality education in New Zealand, concern remains about high rates of sexually transmitted infection and unplanned pregnancy among young people. To understand this 'gap', we consider what high school students learn about sexual health, and where they learn it. Narrative evidence reveals the negative, risk-oriented nature of sexual health messages at school and at home. In these power-laden places, little information is imparted about several key issues, including emotions. Students are aware of such absences, and articulate a desire for more open discussions of sexual health and sexuality, as is possible in informal settings occupied by friends.  相似文献   

Merging circulations on Jupiter: Observed differences between cyclonic and anticyclonic mergers     

John H. Rogers  Hans-Jörg Mettig  Antonio Cidadão  P. Clay Sherrod  Damian Peach 《Icarus》2006,185(1):244-257

The dynamics of mergers of large circulations in Jupiter's atmosphere may permit different models of the atmosphere to be tested. We report well-resolved observations of such events at visible wavelengths: three anticyclonic and three cyclonic events. A merger of anticyclonic white ovals in the South South Temperate domain (2002 March) is compared with the previously reported merger of ovals BE and FA in the South Temperate domain (2000 March). In each case, the two similar-sized ovals converged rapidly once they were separated by less than the sum of their diameters; they orbited around each other anticyclonically during the merger; the merged oval initially had the same rapid drift as the western parent; and, in an unexpected similarity, a cyclonic oval emerged westward from the point of merger. Evidence suggests that a merger of smaller ovals in the North North Temperate domain (2002 February) had similar dynamics. In contrast, mergers of cyclonic ovals in the North Equatorial Belt (‘barges’: 2001 November, 2005 May) proceeded in a different manner. The two parent barges showed no consistent acceleration towards each other as they converged; on contact there was no obvious sign of mutual circulation, and the low-albedo regions had almost passed each other before they finally merged; and the resulting barge had a drift rate intermediate between the two parents, and a length that was greater than either parent. Again, a third such event involving a smaller barge (2002 December) showed many of the same characteristics. These observations define different dynamical behaviour during anticyclonic and cyclonic mergers.  相似文献