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William P Inskeep Richard E Macur Benjamin C Bostick 《Geochimica et cosmochimica acta》2004,68(15):3141-3155
Acid-sulfate-chloride (pH∼3) geothermal springs in Yellowstone National Park (YNP) often contain Fe(II), As(III), and S(-II) at discharge, providing several electron donors for chemolithotrophic metabolism. The microbial populations inhabiting these environments are inextricably linked with geochemical processes controlling the behavior of As and Fe. Consequently, the objectives of the current study were to (i) characterize Fe-rich microbial mats of an ASC thermal spring, (ii) evaluate the composition and structure of As-rich hydrous ferric oxides (HFO) associated with these mats, and (iii) identify microorganisms that are potentially responsible for mat formation via the oxidation of Fe(II) and or As(III). Aqueous and solid phase mat samples obtained from a spring in Norris Basin, YNP (YNP Thermal Inventory NHSP35) were analyzed using a complement of chemical, microscopic and spectroscopic techniques. In addition, molecular analysis (16S rDNA) was used to identify potentially dominant microbial populations within different mat locations. The biomineralization of As-rich HFO occurs in the presence of nearly equimolar aqueous As(III) and As(V) (∼12 μM), and ∼ 48 μM Fe(II), forming sheaths external to microbial cell walls. These solid phases were found to be poorly ordered nanocrystalline HFO containing mole ratios of As(V):Fe(III) of 0.62 ± 0.02. The bonding environment of As(V) and Fe(III) is consistent with adsorption of arsenate on edge and corner positions of Fe(III)-OH octahedra. Numerous archaeal and bacterial sequences were identified (with no closely related cultured relatives), along with several 16S sequences that are closely related to Acidimicrobium, Thiomonas, Metallosphaera and Marinithermus isolates. Several of these cultured relatives have been implicated in Fe(II) and or As(III) oxidation in other low pH, high Fe, and high As environments (e.g. acid-mine drainage). The unique composition and morphologies of the biomineralized phases may be useful as modern-day analogs for identifying microbial life in past Fe-As rich environments. 相似文献
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Geoffrey W. Rodgers John B. Mander J. Geoffrey Chase Rajesh P. Dhakal Nicholas C. Leach Caleb S. Denmead 《地震工程与结构动力学》2008,37(2):207-223
High force‐to‐volume extrusion damping devices can offer significant energy dissipation directly in structural connections and significantly reduce seismic response. Realistic force levels up to 400 kN have been obtained experimentally validating this overall concept. This paper develops spectral‐based design equations for their application. Response spectra analysis for multiple, probabilistically scaled earthquake suites are used to delineate the response reductions due to added extrusion damping. Representative statistics and damping reduction factors are utilized to characterize the modified response in a form suitable for current performance‐based design methods. Multiple equation regression analysis is used to characterize reduction factors in the constant acceleration, constant velocity, and constant displacement regions of the response spectra. With peak device forces of 10% of structural weight, peak damping reduction factors in the constant displacement region of the spectra are approximately 6.5 ×, 4.0 ×, and 2.8 × for the low, medium, and high suites, respectively. At T = 1 s, these values are approximately 3.6 ×, 1.8 ×, and 1.4 ×, respectively. The maximum systematic bias introduced by using empirical equations to approximate damping reduction factors in design analyses is within the range of +10 to ?20%. The seismic demand spectrum approach is shown to be conservative across a majority of the spectrum, except for large added damping between T = 0.8 and 3.5 s, where it slightly underestimates the demand up to a maximum of approximately 10%. Overall, the analysis shows that these devices have significant potential to reduce seismic response and damage at validated prototype device force levels. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献