Soluble organic compounds in fog and cloud droplets: what have we learned over the past few years?     

Sandro Fuzzi  Maria Cristina Facchini  Stefano Decesari  Emanuela Matta  Mihaiela Mircea 《Atmospheric Research》2002,64(1-4)

We have recently set up a new procedure for characterising the water soluble organic compounds (WSOC) in fog water, for which information is still rather limited. Fog samples collected during the 1998–1999 fall–winter season in the Po Valley (Italy) were analysed following this procedure, which allows a quantitative determination of three main classes of organic compounds (neutral species, mono- and di-carboxylic acids, polycarboxylic acids), together accounting for ca. 85% of the total WSOC. This procedure also provides information on the main chemical characteristics of these three classes of compounds (functional groups, aliphatic vs. aromatic character, etc.). The enhanced chemical knowledge on fog/cloud chemical composition opens new scenarios as far as chemical and microphysical processes in clouds and fogs are concerned.  相似文献   

Tectonic evolution of the Lachlan Fold Belt, southeastern Australia: constraints from coupled numerical models of crustal deformation and surface erosion driven by subduction of the underlying mantle     

Jean Braun  Cristina Pauselli 《Physics of the Earth and Planetary Interiors》2004,141(4):281-301

We have used a coupled thermo-mechanical finite-element (FE) model of crustal deformation driven by mantle/oceanic subduction to demonstrate that the tectonic evolution of the Lachlan Fold Belt (LFB) during the Mid-Palaeozoic (Late Ordovician to Early Carboniferous) can be linked to continuous subduction along a single subduction zone. This contrasts with most models proposed to date which assume that separate subduction zones were active beneath the western, central and eastern sections of the Lachlan Orogen. We demonstrate how the existing data on the structural, volcanic and erosional evolution of the Lachlan Fold Belt can be accounted for by our model. We focus particularly on the timing of fault movement in the various sectors of the orogen. We demonstrate that the presence of the weak basal decollement on which most of the Lachlan Fold Belt is constructed effectively decouples crustal structures from those in the underlying mantle. The patterns of faulting in the upper crust appears therefore to be controlled by lateral strength contrasts inherited from previous orogenic events rather than the location of one or several subduction zones. The model also predicts that the uplift and deep exhumation of the Wagga-Omeo Metamorphic Belt (WOMB) is associated with the advection of this terrane above the subduction point and is the only tectonic event that gives us direct constraints on the location of the subduction zone. We also discuss the implications of our model for the nature of the basement underlying the present-day orogen.  相似文献   

Near-vertical seismic reflection image using a novel acquisition technique across the Vrancea Zone and Foscani Basin, south-eastern Carpathians (Romania)     

I. Panea  R. Stephenson  C. Knapp  V. Mocanu  G. Drijkoningen  L. Matenco  J. Knapp  K. Prodehl 《Tectonophysics》2005,410(1-4):293-309

The DACIA PLAN (Danube and Carpathian Integrated Action on Process in the Lithosphere and Neotectonics) deep seismic sounding survey was performed in August–September 2001 in south-eastern Romania, at the same time as the regional deep refraction seismic survey VRANCEA 2001. The main goal of the experiment was to obtain new information on the deep structure of the external Carpathians nappes and the architecture of Tertiary/Quaternary basins developed within and adjacent to the seismically-active Vrancea zone, including the Focsani Basin. The seismic reflection line had a WNW–ESE orientation, running from internal East Carpathians units, across the mountainous south-eastern Carpathians, and the foreland Focsani Basin towards the Danube Delta. There were 131 shot points along the profile, with about 1 km spacing, and data were recorded with stand-alone RefTek-125s (also known as “Texans”), supplied by the University Texas at El Paso and the PASSCAL Institute. The entire line was recorded in three deployments, using about 340 receivers in the first deployment and 640 receivers in each of the other two deployments. The resulting deep seismic reflection stacks, processed to 20 s along the entire profile and to 10 s in the eastern Focsani Basin, are presented here. The regional architecture of the latter, interpreted in the context of abundant independent constraint from exploration seismic and subsurface data, is well imaged. Image quality within and beneath the thrust belt is of much poorer quality. Nevertheless, there is good evidence to suggest that a thick (10 km) sedimentary basin having the structure of a graben and of indeterminate age underlies the westernmost part of the Focsani Basin, in the depth range 10–25 km. Most of the crustal depth seismicity observed in the Vrancea zone (as opposed to the more intense upper mantle seismicity) appears to be associated with this sedimentary basin. The sedimentary successions within this basin and other horizons visible further to the west, beneath the Carpathian nappes, suggest that the geometry of the Neogene and recent uplift observed in the Vrancea zone, likely coupled with contemporaneous rapid subsidence in the foreland, is detached from deeper levels of the crust at about 10 km depth. The Moho lies at a depth of about 40 km along the profile, its poor expression in the reflection stack being strengthened by independent estimates from the refraction data. Given the apparent thickness of the (meta)sedimentary supracrustal units, the crystalline crust beneath this area is quite thin (< 20 km) supporting the hypothesis that there may have been delamination of (lower) continental crust in this area involved in the evolution of the seismic Vrancea zone.  相似文献   

Kamafugitic diatremes: their textures and field relationships with examples from the Goiás alkaline province, Brazil     

Tereza Cristina Junqueira-Brod  Jos Carlos Gaspar  Jos Affonso Brod  Camilla Vasconcelos Kafino 《Journal of South American Earth Sciences》2005,18(3-4):337-353

Kamafugitic rocks intruded the Precambrian basement and Phanerozoic sediments at the northeast border of the Paraná basin as part of the Late Cretaceous Goiás alkaline province (GAP). Plutonic complexes dominate the north of the province, whereas lavas and pyroclastic rocks prevail in the south. The central GAP is characterized by kamafugitic diatremes, which may crop out continuously for up to 850 m and consist of a central breccia body, surrounded and overlain by lava flows and crosscut by dykes. The breccias contain some special spheroidal juvenile fragments—namely, accretionary and armored lapilli, frozen droplets, spinning droplets, and wrapped fragments—whose textural and mineralogical aspects are described in detail. Irregularly shaped tuff pockets that occur within the breccias contain textures and structures similar to those of subaerial surge deposits and formed in confined, high gas to solid+liquid ratio domains in the conduit. Diatreme emplacement affected the country rock through thermal metamorphism, development of columnar jointing, and formation of peperite-like mixtures. There is no evidence of phreatomagmatic activity in the diatremes, and CO₂, rather than H₂O, seems to have been the major volatile component of the kamafugitic magmas. This finding implies that features such as accretionary lapilli and peperites are not exclusively associated with H₂O-dominated processes.  相似文献   

The supergene origin of ruthenian hexaferrum in Ni‐laterites          下载免费PDF全文

Thomas Aiglsperger  Joaquín A. Proenza  Salvador Galí  Jordi Rius  Francisco Longo  Cristina Domènech 《地学学报》2017,29(2):106-116

For two decades, the nature of Fe‐rich, oxygen‐bearing, Ru–Os compounds found in the supergene environment has been debated. Ru–Os–Fe‐oxides and nano‐intergrowths of ruthenium with magnetite have been proposed. We applied FE‐SEM, EMPA, μ‐Raman spectroscopy and synchrotron tts‐μXRD to Ru–Os–Fe compounds recovered from Ni‐laterites from the Dominican Republic. The results demonstrate that a significant portion of Fe exists in a common structure with the Ru–Os alloy, that is, ruthenian hexaferrum. This mineral occurs both as nanoparticles and as micrometric patches within a matrix of Fe‐oxide(s). Our data suggest that supergene ruthenian hexaferrum with a (Ru_0.4(Os,Ir)_0.1Fe_0.5)_?1.0 stoichiometry represents the most advanced weathering product of primary laurite within Ni‐laterites from the Dominican Republic.  相似文献   

Multispecies dendroclimatic reconstructions of summer temperature in the European Alps enhanced by trees highly sensitive to temperature     

Giovanni Leonelli  Anna Coppola  Carlo Baroni  Maria Cristina Salvatore  Maurizio Maugeri  Michele Brunetti  Manuela Pelfini 《Climatic change》2016,137(1-2):275-291

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Provenance of Holocene beach sand in the Western Iberian margin: the use of the Kolmogorov–Smirnov test for the deciphering of sediment recycling in a modern coastal system          下载免费PDF全文

Manuel Francisco Pereira  Luís Albardeiro  Cristina Gama  Martim Chichorro  Mandy Hofmann  Ulf Linnemann 《Sedimentology》2016,63(5):1149-1167

Detrital zircons from Holocene beach sand and igneous zircons from the Cretaceous syenite forming Cape Sines (Western Iberian margin) were dated using laser ablation – inductively coupled plasma – mass spectrometry. The U–Pb ages obtained were used for comparison with previous radiometric data from Carboniferous greywacke, Pliocene–Pleistocene sand and Cretaceous syenite forming the sea cliff at Cape Sines and the contiguous coast. New U–Pb dating of igneous morphologically simple and complex zircons from the syenite of the Sines pluton suggests that the history of zircon crystallization was more extensive (ca 87 to 74 Ma), in contrast to the findings of previous geochronology studies (ca 76 to 74 Ma). The U–Pb ages obtained in Holocene sand revealed a wide interval, ranging from the Cretaceous to the Archean, with predominance of Cretaceous (37%), Palaeozoic (35%) and Neoproterozoic (19%) detrital‐zircon ages. The paucity of round to sub‐rounded grains seems to indicate a short transportation history for most of the Cretaceous zircons (ca 95 to 73 Ma) which are more abundant in the beach sand that was sampled south of Cape Sines. Comparative analysis using the Kolmogorov–Smirnov statistical method, analysing sub‐populations separately, suggests that the zircon populations of the Carboniferous and Cretaceous rocks forming the sea cliff were reproduced faithfully in Quaternary sand, indicating sediment recycling. The similarity of the pre‐Cretaceous ages (>ca 280 Ma) of detrital zircons found in Holocene sand, as compared with Carboniferous greywacke and Pliocene–Pleistocene sand, provides support for the hypothesis that detritus was reworked into the beach from older sedimentary rocks exposed along the sea cliff. The largest percentage of Cretaceous zircons (<ca 95 Ma) found in Holocene sand, as compared with Pliocene–Pleistocene sand (secondary recycled source), suggests that the Sines pluton was the one of the primary sources that became progressively more exposed to erosion during Quaternary uplift. This work highlights the application of the Kolmogorov–Smirnov method in comparison of zircon age populations used to identify provenance and sediment recycling in modern and ancient detrital sedimentary sequences.  相似文献   

Magma mixing induced by particle settling     

Christian J. Renggli  Sebastian Wiesmaier  Cristina P. De Campos  Kai-Uwe Hess  Donald B. Dingwell 《Contributions to Mineralogy and Petrology》2016,171(11):96

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Longleaf Pine (Pinus palustris Mill.) Morphology and Climate/Growth Responses Along a Physiographic Gradient in North Carolina     

Thomas W. Patterson  Lindsay W. Cummings  Paul A. Knapp 《The Professional geographer》2016,68(2):238-248

Geographic differences in tree morphology and climate and growth responses of longleaf pine have been documented, yet how these differences vary at a larger scale has not. In this study, we documented changes in tree morphology and climate and radial growth responses of six longleaf pine (Pinus palustris Mill.) stands in three physiographic regions in North Carolina. We sampled from more than fifteen trees per stand and compared site- and regional-level total and latewood ring width values to temperature, precipitation, and drought. All morphological characteristics expressed a strong west–east gradient. Climate and radial growth response was strongest for the Sandhills region and then Piedmont and Coastal Plain regions. The distinct morphological characteristic gradient did not covary with climate and radial growth response, suggesting that additional environmental influences affect needle length, trunk diameter, and height.  相似文献   

Biosorption with autochthonous and allochthonous fungal biomasses for bioremediation and detoxification of landfill leachate     

Valeria Tigini  Giovanna Cristina Varese 《Environmental Earth Sciences》2018,77(9):342

Landfill leachates are not adequately treated in traditional wastewater treatment plants, on account of their problematic peculiarities: i.e., dark colour, high concentration of recalcitrant pollutants and COD, and high toxicity. In this work, 19 biomasses (15 autochthonous and 4 allochthonous) were exploited in biosorption treatment for the remediation of a leachate (influent) and the effluent coming from the biological oxidation with activated sludge and nitrification–denitrification treatment. The effects of the initial pH, the biomass amount, and the medium for the biomass pre-culture were considered. The best configuration was: pH 5, 5 g L^??1 biomass cultivated on STY medium. Eventually, the two most effective biomasses, Cunninghamella bertholletiae MUT 2861 and Aspergillus fumigatus MUT 4050, were used in consecutive 2 h cycles in a batch biosorption experiment. The effectiveness of the treatment decreased in subsequent cycles in terms of decolourisation (31–15%). COD, Cl^?, SO₄^2?, total N, and toxicity were removed mainly in the second cycle of treatment (up to ??36, ??12, ??15, ??17 and ??49%, respectively). The results suggest that the effluent toxicity was basically due to uncoloured substances, which were mainly removed after coloured molecules.  相似文献