Soluble iron sulfide species in natural waters: Reappraisal of their stoichiometry and stability constants   总被引：4，自引：0，他引：4  

William Davison  Noel Phillips  Brian J. Tabner 《Aquatic Sciences - Research Across Boundaries》1999,61(1):23-43

A wide range of stoichiometries has been previously proposed for soluble iron sulfide species and there is no general agreement on their importance in natural waters. The solubility of Fe(II) in 0.1 M NaClO₄ equilibrated at 20 - 0.1°C with various partial pressures of H₂S (0.1, 0.001, 0.0001, 0.00001 MPa) was measured in the pH range 3.1-7.9. Equilibrium was established within 1-6 h when amorphous FeS was the solid phase. The results could all be fitted using values for the solubility product constant (I = 0) of p*K_s = 3.00 - 0.12 and of the stability constant for a soluble Fe(HS) ₂ species (I = 0) of p#₂ = -6.45 - 0.12 where *K_s = aFe²⁺ · aHS-/aH⁺ and #₂ = aFe(HS) ₂/aFe²⁺ · (aHS^-)². Any soluble species of the form Fe_x (HS) _2x where x = &gif1; would fit the data equally well. Measurements at different partial pressures are inconsistent with labile species of the form Fe_xS_x. There was no evidence for a Fe(HS) ⁺ species. When a solution is saturated with respect to amorphous FeS, Fe(HS) ₂ will only be a significant proportion of Fe(II) when S(-II) is higher than 0.2mmoll^-1. The constants for Fe(HS) ₂ or Fe_x (HS) _2x (x S 2) are consistent with all freshwater data where constant values of measured ion activity products provide no evidence for soluble complex formation. For marine waters with high sulfide concentrations (S 6mmol l^-1), measured concentrations of Fe(II) are consistent with there being negligible soluble iron sulfide. The data are better fitted if the dissolved species are polymeric as predicted concentrations of the monomer Fe(HS) ₂ are significant. These findings suggest that rather than the dissolved species being Fe(HS) ₂, it is probably polymeric, that is Fe_x (HS) _2x (x S 2).  相似文献   

Spectral density regression for bivariate extremes     

Daniela?Castro Camilo  Miguel?de CarvalhoEmail authorView author&#;s OrcID profile 《Stochastic Environmental Research and Risk Assessment (SERRA)》2017,31(7):1603-1613

We introduce a density regression model for the spectral density of a bivariate extreme value distribution, that allows us to assess how extremal dependence can change over a covariate. Inference is performed through a double kernel estimator, which can be seen as an extension of the Nadaraya–Watson estimator where the usual scalar responses are replaced by mean constrained densities on the unit interval. Numerical experiments with the methods illustrate their resilience in a variety of contexts of practical interest. An extreme temperature dataset is used to illustrate our methods.  相似文献   

Floodplain sedimentation and sensitivity: summer 1993 flood,Upper Mississippi River Valley     

Basil Gomez  J. D. Phillips  F. J. Magilligan  L. A. James 《地球表面变化过程与地形》1997,22(10):923-936

Patterns of overbank sedimentation in the vicinity of, and far removed from, levee breaks that occurred in response to the >100 year, summer 1993 flood in the upper Mississippi River valley are elucidated. Two suites of overbank deposits were associated with the failure of artificial levees within a 70 km long study reach. Circumjacent sand deposits are a component of the levee break complex that develops in the immediate vicinity of a break site. As epitomized by the levee break complex at Sny Island, these features consist of an erosional, scoured and/or stripped zone, together with a horseshoe-shaped, depositional zone. At locales farther removed from the break site, the impact of flooding was exclusively depositional and was attributed to the settling of suspended sediment from the water column. The overall picture was one of modest scour at break sites and minimal suspended deposition (<4 mm) at locales farther removed from the breach. Downriver from the confluence with the Missouri River, suspended sediment deposition was of a similar magnitude to that observed within the study reach and levee break complexes exhibited a similar morphology, but scour at break sites was greatly enhanced and the excavated sand formed extensive deposits on the floodplain surface. The different erosional response was probably engendered by the higher sand content and reduced aggregate cohesion of the floodplain soils downriver from the confluence with the Missouri River. A qualitative comparison serves to highlight the influence that the resistance threshold may have on the sensitivity of floodplains bordering large low-gradient rivers to high magnitude floods. © 1997 John Wiley & Sons, Ltd.  相似文献   

A plains ceramic clay source characterization by comparative geochemical and petrographic analyses: Results from the Calhan Paint Mines,Colorado, U.S.A.     

Scott C. Phillips  Maury Morgenstein 《Geoarchaeology》2002,17(6):579-599

The Calhan Paint Mines District, 5EP3258, Colorado, presents exposures of an exceptional clay source. When the area also produced prehistoric Ceramic stage sites, it provided the opportunity for both pottery and potential clay source analysis by optical petrography, X‐ray diffraction, and neutron activation. Although the main purpose of this study is the characterization of the ceramics and outcrop clays, results from a limited number of samples suggest that the colorful clays, the figurative “paints,” of the Calhan Paint Mines were purposely used in prehistoric times as clay source materials for ceramic production. The Calhan Paint Mines are quite possibly the only prehistoric Plains Ceramic stage clay source currently confirmed within the state of Colorado. © 2002 Wiley Periodicals, Inc.  相似文献   

Measurement of the radius of Mercury by radio occultation during the MESSENGER flybys     

Mark E. Perry  Daniel S. Kahan  Olivier S. Barnouin  Carolyn M. Ernst  Sean C. Solomon  Maria T. Zuber  David E. Smith  Roger J. Phillips  Dipak K. Srinivasan  Jürgen Oberst  Sami W. Asmar 《Planetary and Space Science》2011,59(15):1925-1931

The MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft completed three flybys of Mercury in 2008–2009. During the first and third of those flybys, MESSENGER passed behind the planet from the perspective of Earth, occulting the radio-frequency (RF) transmissions. The occultation start and end times, recovered with 0.1 s accuracy or better by fitting edge-diffraction patterns to the RF power history, are used to estimate Mercury's radius at the tangent point of the RF path. To relate the measured radius to the planet shape, we evaluate local topography using images to identify the high-elevation feature that defines the RF path or using altimeter data to quantify surface roughness. Radius measurements are accurate to 150 m, and uncertainty in the average radius of the surrounding terrain, after adjustments are made from the local high at the tangent point of the RF path, is 350 m. The results are consistent with Mercury's equatorial shape as inferred from observations by the Mercury Laser Altimeter and ground-based radar. The three independent estimates of radius from occultation events collectively yield a mean radius for Mercury of 2439.2±0.5 km.  相似文献   

Log‐jams and avulsions in the San Antonio River Delta,Texas     

Jonathan D. Phillips 《地球表面变化过程与地形》2012,37(9):936-950

The San Antonio River Delta (SARD), Texas, has experienced two major avulsions in the past 80 years, and a number of other historical and Holocene channel shifts. The causes and consequences of these avulsions – one of which is ongoing – were examined using a combination of fieldwork, geographic information system (GIS) analysis, and historical information to identify active, semi‐active, and paleochannels and the sequence of shifting flow paths through the delta. The role of deposition patterns and antecedent morphology, large woody debris jams, and tectonic influences were given special attention. Sedimentation in the SARD is exacerbated by tectonic effects. Channel aggradation is ubiquitous, and superelevation of the channel bed above the level of backswamp areas on the floodplain is common. This creates ideal setup conditions for avulsions, and stable, cohesive fine‐grained banks favor avulsions rather than lateral migration. Flood basins between the alluvial ridges associated with the aggraded channels exist, but avulsions occur by re‐occupation of former channels found within or connected to the flood basins. Large woody debris and channel‐blocking log‐jams are common, and sometimes displace flow from the channel, triggering crevasses. However, a large, recurring log‐jam at the site of the ongoing avulsion from the San Antonio River into Elm Bayou is not responsible for the channel shift. Rather, narrow, laterally stable channels resulting from flow splits lead to accumulation of wood. Some aspects of the SARD avulsion regime are typical of other deltas, while others are more novel. These includes avulsions involving tributaries and subchannels within the delta as well as from the dominant channel; tectonic influences on delta backstepping and on channel changes within the delta; avulsions as an indirect trigger for log‐jam formation (as well as vice‐versa); and maintenance of a multi‐channel flow pattern distinct from classic anastamosing or distributary systems. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

Geographical information system approaches for hazard mapping of dilute lahars on Montserrat, West Indies     

A. R. Darnell  J. Barclay  R. A. Herd  J. C. Phillips  A. A. Lovett  P. Cole 《Bulletin of Volcanology》2012,74(6):1337-1353

Many research tools for lahar hazard assessment have proved wholly unsuitable for practical application to an active volcanic system where field measurements are challenging to obtain. Two simple routing models, with minimal data demands and implemented in a geographical information system (GIS), were applied to dilute lahars originating from Soufrière Hills Volcano, Montserrat. Single-direction flow routing by path of steepest descent, commonly used for simulating normal stream-flow, was tested against LAHARZ, an established lahar model calibrated for debris flows, for ability to replicate the main flow routes. Comparing the ways in which these models capture observed changes, and how the different modelled paths deviate can also provide an indication of where dilute lahars, do not follow behaviour expected from single-phase flow models. Data were collected over two field seasons and provide (1) an overview of gross morphological change after one rainy season, (2) details of dominant channels at the time of measurement, and (3) order of magnitude estimates of individual flow volumes. Modelling results suggested both GIS-based predictive tools had associated benefits. Dominant flow routes observed in the field were generally well-predicted using the hydrological approach with a consideration of elevation error, while LAHARZ was comparatively more successful at mapping lahar dispersion and was better suited to long-term hazard assessment. This research suggests that end-member models can have utility for first-order dilute lahar hazard mapping.  相似文献   

Biofilm Detection in a Model Well‐Bore Environment Using Low‐Field NMR          下载免费PDF全文

Catherine M. Kirkland  Randy Hiebert  Adrienne Phillips  Elliot Grunewald  David O. Walsh  Joseph D. Seymour  Sarah L. Codd 《Ground Water Monitoring & Remediation》2015,35(4):36-44

This research addresses the challenges of the lack of non‐invasive methods and poor spatiotemporal resolution associated with monitoring biogeochemical activity central to bioremediation of subsurface contaminants. Remediation efforts often include growth of biofilm to contain or degrade chemical contaminants, such as nitrates, hydrocarbons, heavy metals, and some chlorinated solvents. Previous research indicates that nuclear magnetic resonance (NMR) is sensitive to the biogeochemical processes of biofilm accumulation. The current research focuses on developing methods to use low‐cost NMR technology to support in situ monitoring of biofilm growth and geochemical remediation processes in the subsurface. Biofilm was grown in a lab‐scale radial flow bioreactor designed to model the near wellbore subsurface environment. The Vista Clara Javelin NMR logging device, a slim down‐the‐borehole probe, collected NMR measurements over the course of eight days while biofilm was cultivated in the sand‐packed reactor. Measured NMR mean log T₂ relaxation times decreased from approximately 710 to 389 ms, indicating that the pore environment and bulk fluid properties were changing due to biofilm growth. Destructive sampling employing drop plate microbial population analysis and scanning electron and stereoscopic microscopy confirmed biofilm formation. Our findings demonstrate that the NMR logging tool can detect small to moderate changes in T₂ distribution associated with environmentally relevant quantities of biofilm in quartz sand.  相似文献   

Improved 2-D attenuation analysis for Northern Italy using a merged dataset from selected regional seismic networks     

Paola Morasca  Marco Massa  Enrica Laprocina  Kevin Mayeda  Scott Phillips  Luca Malagnini  Daniele Spallarossa  Giovanni Costa  Paolo Augliera 《Journal of Seismology》2010,14(4):727-738

A merged, high-quality waveform dataset from different seismic networks has been used to improve our understanding of lateral seismic attenuation for Northern Italy. In a previous study on the same region, Morasca et al. (Bull Seismol Soc Am 98:1936–1946, 2008) were able to resolve only a small area due to limited data coverage. For this reason, the interpretation of the attenuation anomalies was difficult given the complexity of the region and the poor resolution of the available data. In order to better understand the lateral changes in the crustal structure and thickness of this region, we selected 770 earthquakes recorded by 54 stations for a total of almost 16,000 waveforms derived from seismic networks operating totally or partially in Northern Italy. Direct S-wave and coda attenuation images were obtained using an amplitude ratio technique that eliminates source terms from the formulation. Both direct and early-coda amplitudes are used as input for the inversions, and the results are compared. Results were obtained for various frequency bands ranging between 0.3 and 25.0 Hz and in all cases show significant improvement with respect to the previous study since the resolved area has been extended and more crossing paths have been used to image smaller scale anomalies. Quality-factor estimates are consistent with the regional tectonic structure exhibiting a general trend of low attenuation under the Po Plain basin and higher values for the Western Alps and Northern Apennines. The interpretation of the results for the Eastern Alps is not simple, possibly because our resolution for this area is still not adequate to resolve small-scale structures.  相似文献   

A comparison of the asymptotic and no-z approximations for galactic dynamos     

Andrew Phillips 《地球物理与天体物理流体动力学》2013,107(1-2):135-150

Abstract

The asymptotic and the no-z approximation methods of solving the axisymmetric mean field αΩ dynamo equation in a galactic disc are compared. The behaviour of the solutions is explored in both the linear and nonlinear regimes for a variety of dynamo parameters and two different rotation curves. The solutions obtained from the two different approaches are found to be in good agreement.  相似文献