Diffusion and partition coefficients of minor and trace elements in San Carlos olivine at 1,300°C with some geochemical implications     

Carl Spandler  Hugh St.C. O’Neill 《Contributions to Mineralogy and Petrology》2010,159(6):791-818

Lattice diffusion coefficients have been determined for 19 elements (Li, Be, Na, Ca, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Zn, Y, Zr, Eu, Gd, Lu and Hf) in a single crystal of San Carlos olivine as a function of crystallographic orientation, at 1,300°C, 1 bar and fO₂ = 10^−8.3 bars, by equilibration with a synthetic silicate melt. Results for Li, Na, V, Cr, Fe and Zn are from diffusion of these elements out of the olivine, starting from their indigenous concentrations; those for all other elements are from diffusion into the olivine, from the silicate melt reservoir. Our 25-day experiment produced diffusion profiles 50 to > 700 μm in length, which are sufficiently long that precise analyses could be achieved by scanning laser ablation inductively coupled plasma mass spectrometry, even at concentration levels well below 1 μg g⁻¹. For the divalent cations Ca, Mn, Fe and Ni, profiles were also obtained by electron microprobe analysis. The results of the two methods agree well with each other, and are consistent with divalent cation diffusion coefficients previously determined using different experimental methodologies. Olivine/melt partition coefficients retrieved from the data are also consistent with other published partitioning data, indicating that element incorporation and transport in olivine in our experiment occurred via mechanisms appropriate to natural conditions. Most of the examined trace elements diffuse through olivine at similar rates to the major octahedral cations Fe and Mg, showing that cation charge and radius have little direct influence on diffusion rates. Aluminium and P remain low and constant in the olivine, implying negligible transport at our analytical scale, hence Al and P diffusion rates that are at least two orders of magnitude slower than the other cations studied here. All determined element diffusivities are anisotropic, with diffusion fastest along the [001] axis, except Y and the REEs, which diffuse isotropically. The results suggest that element diffusivity in olivine is largely controlled by cation site preference, charge balance mechanisms and point-defect concentrations. Elements that are present on multiple cation sites in olivine (e.g. Be and Ti) and trivalent elements that are charge-balanced by octahedral site vacancies tend to diffuse at relatively fast rates.  相似文献   

Inelastic buckling of thick-walled circular conical shells under external hydrostatic pressure   总被引：1，自引：0，他引：1  

Carl T. F. Ross  David Sawkins  Terry Johns 《Ocean Engineering》1999,26(12):1506

The paper reports on a theoretical and an experimental study into the collapse of three thick-walled circular conical shells, which were tested to failure under external hydrostatic pressure. All three vessels failed by plastic non-symmetric bifurcation buckling. Two theoretical analyses were carried out, both based on the finite element method. One of the theoretical analyses was based on inelastic non-symmetric bifurcation buckling and the other analysis was based on plastic axisymmetric buckling. Both of these theoretical analysis and the experimental observations appeared to indicate that there is a link between plastic non-symmetric bifurcation buckling and plastic axisymmetric buckling.  相似文献   

Submarine Sand Resources, Southeastern Virginia-Contributions from Year 9 and Year 10 of Virginia's Continental Margins Program     

Carl H. Hobbs  C. Scott Hardaway  C. R. Berquist 《Marine Georesources & Geotechnology》1999,17(2):155-163

Virginia's year 9 and year 10 funds from the Continental Shelf Program were used to supplement other work funded by the Minerals Management Service in an ongoing Cooperative Agreement focused on the area offshore of southeastern Virginia. Year 9 and year 10 funds facilitated interpretation of subbottom profiles and the analysis of sediment samples from cores and grabs. On Virginia's sediment-starved continental shelf, deposits of material potentially suitable for use as beach nourishment or, perhaps, as construction aggregate occur in three stratigraphic settings, each with specific characteristics of morphology, grain-size gradients, likelihood of discovery, and physical ease of exploitation. All must be verified with a careful program of coring. Modern shoals generally are easier to identify, prove, and access than either filled channels or lenticular facies. Shoals usually are identifiable on nautical charts and characteristically have a definite lower boundarythat can be seen in subbottom profiles. In most cases, the base of the shoal coincides with the level of the surrounding sea floor. Filled channels are readily identifiable on subbottom profiles but may have a narrow, sinuous form and steep lateral gradients in sediment properties. Buried lenticular facies of good-quality sand usually are found only fortuitously. As the lateral and often vertical gradients in geotechnical properties usually are low, the lenticular facies can be mined with a lesser concern for the consequences of violating the deposit's limits than with the other two types of deposit. There are three types of filled paleochannels in the study area. (1) Relatively near-surface, generally small, roughly shore normal channels most likely mark the migration of tidal inlets across the shelf during the most recent transgression. (2) Small, relatively wide and relatively shallow generally shore parallel channels may be filled back-barrier or lagoonal channels. (3) Larger channels trending across the shelf probably result from riverine flow. The complexity of the seismostratigraphy of the Quaternary deposits on south eastern Virginia's inner continental shelf is a result of series of high-frequency (fifth-order, 10-20,000 y), low-amplitude (20-30 m) variations in sea level that occurred during the last highstand, roughly 80,000 to 130,000 BP. The evidence of the small oscillations in sea level is best seen in the regions that were between the shoreline and wave base, today's inner shelf; however, the very low rates of deposition on the shelf make it difficult to correlate specific reflectors or beds or, at times, to distinguish between fifth-and fourth-order changes. Results for the continuing studies already have been used in the determination to mine several hundred thousand cubic meters of sand from Sandbridge Shoal for use on a Navy-owned facility and in consideration of mining greater quantities of sand from Sandbridge and other shoals for use in local beach nourishment and hurricane protection efforts.  相似文献   

Upscaling site‐scale ecohydraulic models to inform salmonid population‐level life cycle modeling and restoration actions – Lessons from the Columbia River Basin          下载免费PDF全文

Joseph M. Wheaton  Nicolaas Bouwes  Peter Mchugh  Carl Saunders  Sara Bangen  Phillip Bailey  Matt Nahorniak  Eric Wall  Chris Jordan 《地球表面变化过程与地形》2018,43(1):21-44

With high‐resolution topography and imagery in fluvial environments, the potential to quantify physical fish habitat at the reach scale has never been better. Increased availability of hydraulic, temperature and food availability data and models have given rise to a host of species and life stage specific ecohydraulic fish habitat models ranging from simple, empirical habitat suitability curve driven models, to fuzzy inference systems to fully mechanistic bioenergetic models. However, few examples exist where such information has been upscaled appropriately to evaluate entire fish populations. We present a framework for applying such ecohydraulic models from over 905 sites in 12 sub‐watersheds of the Columbia River Basin (USA), to assess status and trends in anadromous salmon populations. We automated the simulation of computational engines to drive the hydraulics, and subsequent ecohydraulic models using cloud computing for over 2075 visits from 2011 to 2015 at 905 sites. We also characterize each site's geomorphic reach type, habitat condition, geomorphic unit assemblage, primary production potential and thermal regime. We then independently produce drainage network‐scale models to estimate these same parameters from coarser, remotely sensed data available across entire populations within the Columbia River Basin. These variables give us a basis for imputation of reach‐scale capacity estimates across drainage networks. Combining capacity estimates with survival estimates from mark–recapture monitoring allows a more robust quantification of capacity for freshwater life stages (i.e. adult spawning, juvenile rearing) of the anadromous life cycle. We use these data to drive life cycle models of populations, which not only include the freshwater life stages but also the marine and migration life stages through the hydropower system. More fundamentally, we can begin to look at more realistic, spatially explicit, tributary habitat restoration scenarios to examine whether the enormous financial investment on such restoration actions can help recover these populations or prevent their extinction. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   

Upward continuation of Dome-C airborne gravity and comparison with GOCE gradients at orbit altitude in east Antarctica     

Hasan Yildiz  Rene Forsberg  Carl Christian Tscherning  Daniel Steinhage  Graeme Eagles  Johannes Bouman 《Studia Geophysica et Geodaetica》2017,61(1):53-68

An airborne gravity campaign was carried out at the Dome-C survey area in East Antarctica between the 17th and 22nd of January 2013, in order to provide data for an experiment to validate GOCE satellite gravity gradients. After typical filtering for airborne gravity data, the cross-over error statistics for the few crossing points are 11.3 mGal root mean square (rms) error, corresponding to an rms line error of 8.0 mGal. This number is relatively large due to the rough flight conditions, short lines and field handling procedures used. Comparison of the airborne gravity data with GOCE RL4 spherical harmonic models confirmed the quality of the airborne data and that they contain more high-frequency signal than the global models. First, the airborne gravity data were upward continued to GOCE altitude to predict gravity gradients in the local North-East-Up reference frame. In this step, the least squares collocation using the ITGGRACE2010S field to degree and order 90 as reference field, which is subtracted from both the airborne gravity and GOCE gravity gradients, was applied. Then, the predicted gradients were rotated to the gradiometer reference frame using level 1 attitude quaternion data. The validation with the airborne gravity data was limited to the accurate gradient anomalies (T_XX, T_YY, T_ZZ and T_XZ) where the long-wavelength information of the GOCE gradients has been replaced with GOCO03s signal to avoid contamination with GOCE gradient errors at these wavelengths. The comparison shows standard deviations between the predicted and GOCE gradient anomalies T_XX, T_YY, T_ZZ and T_XZ of 9.9, 11.5, 11.6 and 10.4 mE, respectively. A more precise airborne gravity survey of the southern polar gap which is not observed by GOCE would thus provide gradient predictions at a better accuracy, complementing the GOCE coverage in this region.  相似文献   

40Ar/39Ar ages of L4, H5, EL6, and feldspathic ureilitic clasts from the Almahata Sitta polymict ureilite (asteroid 2008 TC3)     

Brent D. Turrin  Fara Lindsay  Jeremy S. Delaney  Jisun Park  Gregory F. Herzog  Carl Swisher Jr  Cyrena A. Goodrich 《Meteoritics & planetary science》2023,58(3):304-327

The Almahata Sitta (AhS) meteorite consists of disaggregated clasts from the impact of the polymict asteroid 2008 TC₃, including ureilitic (70%–80%) and diverse non-ureilitic materials. We determined the ⁴⁰Ar/³⁹Ar release patterns for 16 AhS samples (3–1500 μg) taken from three chondritic clasts, AhS 100 (L4), AhS 25 (H5), and MS-D (EL6), as well as a clast of ureilitic trachyandesite MS-MU-011, also known as ALM-A, which is probably a sample of the crust of the ureilite parent body (UPB). Based on our analyses, best estimates of the ⁴⁰Ar/³⁹Ar ages (Ma) of the chondritic clasts are 4535 ± 10 (L4), 4537–4555 with a younger age preferred (H5), and 4513 ± 17 (EL6). The ages for the L4 and the H5 clasts are older than the most published ⁴⁰Ar/³⁹Ar ages for L4 and H5 meteorites, respectively. The age for the EL6 clast is typical of older EL6 chondrites. These ages indicate times of argon closure ranging up to 50 Ma after the main constituents of the host breccia, that is, the ureilitic components of AhS, reached the >800°C blocking temperatures of pyroxene and olivine thermometers. We suggest that these ages record the times at which the clasts cooled to the Ar closure temperatures on their respective parent bodies. This interpretation is consistent with the recent proposal that the majority of xenolithic materials in polymict ureilites were implanted into regolith 40–60 Ma after calcium–aluminum-rich inclusion and is consistent with the interpretation that 2008 TC₃ was a polymict ureilite. With allowance for its 10-Ma uncertainty, the 4549-Ma ⁴⁰Ar/³⁹Ar age of ALM-A is consistent with closure within a few Ma of the time recorded by its Pb/Pb age either on the UPB or as part of a rapidly cooling fragment. Plots of age versus cumulative ³⁹Ar release for 10 of 15 samples with ≥5 heating steps indicate minor losses of ⁴⁰Ar over the last 4.5 Ga. The other five such samples lost some ⁴⁰Ar at estimated times no earlier than 3800–4500 Ma bp . Clustering of ages in the low-temperature data for these five samples suggests that an impact caused localized heating of the AhS progenitor ~2.7 Ga ago. In agreement with the published work, 10 estimates of cosmic-ray exposure ages based on ³⁸Ar concentrations average 17 ± 5 Ma but may include some early irradiation.  相似文献