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151.
The concentrations of two greenhouse gases, nitrous oxide (N2O) and methane (CH4), and the bacterial processes involved in their production (nitrification and denitrification for N2O, and methanogenesis for CH4), were determined in surface waters of two coastal areas under the influence of freshwater inputs, on one part in the Gulf of Lions and the Rhone River plume, in northwestern Mediterranean Sea, and on the other part in the inner Thermaikos Gulf, in Aegean Sea, eastern Mediterranean Sea. High concentrations of dissolved CH4 and N2O were recorded in the surface waters of Gulf of Lions and Gulf of Thermaikos, up to 1300 nM for CH4, and 40 nM for N2O. No direct relationship could be found between the concentration and production of the biogases, as they may also be produced in deep water or bottom sediment in shallow areas, or derived from anthropogenic activity or ship contamination in polluted areas. Irrespective of the origin of CH4 and N2O, the presence of extremely high concentrations of these two gases in superficial seawater implies that they can easily escape to the atmosphere; consequently, these nearshore waters enriched in greenhouse gases may play an important role in the increase in atmospheric concentration of both CH4 and N2O.  相似文献   
152.
    
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153.
Summary The magnetosphere depends on the astronomical orientation of the geomagnetic field with respect to the solar wind. The statistical distribution of polar auroras must therefore depend on the orientation of the geomagnetic field with respect to the ecliptic plane. We have investigated this peculiar feature of auroras that we call auroral astronomical geometry. We give here some preliminary results concerning a limited set of pre-IGY auroras. The criteria that we have chosen to prepare the auroral collection are also briefly summarized. The results conform to the hypothesis of the auroral origin from the magnetospheric neutral sheet. Auroral particles are found to impinge over the earth with low angles with respect to the ecliptic plane (40°). Only in a 4-hours interval around midnight they are found to impinge with angles up to 70°. Definite evidence of these facts requires further investigation with a larger amount of data. — We have also prepared a complex code for recording the morphological features of each aurora, namely: standard information, movement. intensity, color, sunlight illumination, period of pulsation, location in the sky among stars and planets, time evolution, duration and general features of the auroral display. It is well known in fact that the auroral morphology affects auroral heights and latitudes, etc.; presumably it should also affect its astronomical geometry, which we will investigate later.Presented at the Inter-Union Symposium on Solar-Terrestrial Physics — Belgrade 1966.  相似文献   
154.
Two geomagnetic reversals(R→N followed by N→R) have been recorded in a sequence of Miocene marine clays of Tortonian-Messinian age in western Crete (Greece). The time span of each transition is found to be of the order of 5000–10,000 years. The transitional VGP paths are largely constrained in longitude either near the site longitude(R→N) or opposite to it(N→R). A normalized magnetization intensity record has also been obtained and its variations during reversals are found to be in excellent agreement with the predictions of Hoffman's phenomenological model.  相似文献   
155.
Riassunto Il campo magnetico terrestre in Albania è stato studiato (per la prima volta) dall'Istituto Geografico Militare attraverso l'esecuzione di una rete del 10 crdine (65 stazioni assolute nei tre elementiD, H edI a circa 20 Km l'una dall'altra). I risultati sono compendiati in una carta magnetica della regione, scala 1750.000, isolinee al 1942.0. Oltre a due zone molto estese di anomalie dovute a rocce eruttive del periodo eocenico nell' Albania settentrionale e sud-orientale, sono messe in evidenza altre tre importanti anomalie regionali nella regione a NE di Scutari, a SO di Kruja, a NE di Korcia ed una locale a SE di Valona. L'esame geofisico indica come probabile causa per la prima e la terza la presenza di rocce basiche a profondità non molto rilevanti (dell' ordine di qualche Km).
Zusammenfassung Das erdmagnetische Feld in Albanien ist (zum ersten Mal) von Ital. Mil. Geogr. Institut studiert worden. Ein magnetisches Netz erster Ordnung von 65 Stationen (ungefähr 20 Km Punktabstand) inD, H undI wurde gemessen. Die Ergebnisse sind in einer Karte dargestellt, Massstab 1750.000, Isolinien am 1942,0. Ausser zwei ausgedehnten Störgebieten von Eruptivgesteinen (Eozän) in Nord-und Süd-Ost-Albanien, sind drei andere Regionalstörungen im Gebiet NO von Scutari, SW von Kruja und NW Koriza, und eine Lokalstörung SO von Valona zu erkennen. Die erste und die dritte sind wahrscheinlich den Ergussgesteinen zuzuschreiben.


con una tavola f. t.

Dott.Carlo Morelli, Capo della Sezione Geomagnetica dell'Istituto Geografico Militare.  相似文献   
156.
New chemical and modal analyses are presented of magmatic rocks and pyroxenes nodules from the Somma-Vesuvius volcano and of trachytes from the surrounding area. Geochemical evidence is employed in checking the generally accepted suggestion that magma composition develops from that of trachyte into phonolitic tephrite and finally into tephritic leucitite (vesuvite) by assimilation of dolomite. At the Somma stage of the volcano, phonolitic tephrites (tephritic phonolites) alone have been produced. Vesuvius lavas (tephritic leucitites) are comparatively high in K2O, CaO, F, Cl, Mn, Cu, Sr and Ba and low in SiO2 and Nb. The formation of vesuvites by assimilation of dolomitic sedimentary rocks, combined with gravity-separation of early-formed pyroxenes from a trachytic or tephritic magma, is improbable as shown by chemical balances between the respective igneous and sedimentary rocks.  相似文献   
157.
Accurate OH and HO2 (collectively called HOx) measurements by laser-induced fluorescence (LIF) may be contaminated by spurious signals from interfering atmospheric chemicals or from the instrument itself. Interference tests must be conducted to ensure that observed OH signal originates solely from ambient OH and is not due to instrument artifacts. Several tests were performed on the Penn State LIF HOx instrument, both in the laboratory and in the field. Theseincluded measurements of the instrument's zero signal by using either zero air or perfluoropropylene to remove OH, examination of spectral interferences from naphthalene, sulfur dioxide, and formaldehyde, and tests of interferences by addition of suspected interfering atmospheric chemicals, including ozone, hydrogen peroxide, nitrous acid, formaldehyde, nitric acid, acetone, and organic peroxy radicals (RO2). All tests lacked evidence ofsignificant interferences for measurements in the atmosphere, including highly polluted urban environments.  相似文献   
158.
Here we report on the temporal changes in the composition of dissolved organic carbon (DOC) collected in the tidal freshwater region of the lower Mississippi River. Lignin-phenols, bulk stable carbon isotopes, compound-specific isotope analyses (CSIA) and 13C nuclear magnetic resonance (NMR) spectrometry were used to examine the composition of high molecular weight dissolved organic matter (HMW DOM) at one station in the lower river over 6 different flow regimes in 1998 and 1999. It was estimated that the annual input of DOC delivered to the Gulf of Mexico from the Mississippi River was of 3.1 × 10−3 Pg, which represents 1.2% of the total global input of DOC from rivers to the ocean. Average DOC and HMW DOC were 489 ±163 and 115 ± 47 μM, respectively. 13C-NMR spectra revealed considerably more aliphatic structures than aromatic carbons in HMW DOC. Lignin phenols were significantly 13C-depleted with respect to bulk HMW DOM indicating that C4 grass inputs to the HMW DOM were not significant. It is speculated that C4 organic matter in the river is not being converted (via microbial decay) to HMW DOM as readily as C3 organic matter is, because of the association of C4 organic matter with finer sediments. The predominantly aliphatic 13C NMR signature of HMW DOM suggests that autochthonous production in the river may be more important as a source of DOC than previously thought. Increases in nutrient loading and decreases in the suspended load (because of dams) in the Mississippi River, as well as other large rivers around the world, has resulted in significant changes in the sources and overall cycling of riverine DOC.  相似文献   
159.
Data are presented for trace element concentrations determined in the <63 μm fraction of streambed sediment samples collected at 24 sites on the island of O‘ahu, Hawai‘i. Sampling sites were classified as urban, agricultural, mixed (urban/agricultural), or forested based on their dominant land use, although the mixed land use at selected sampling sites consisted of either urban and agricultural or forested and agricultural land uses. Forest dominated sites were used as reference sites for calculating enrichment factors.Trace element concentrations were compared to concentrations from studies conducted in the conterminous United States using identical methods and to aquatic-life guidelines provided by the Canadian Council of Ministers of the Environment. A variety of elements including Pb, Cr, Cu and Zn exceeded the aquatic-life guidelines in selected samples. All of the Cr and Zn values and 16 of 24 Cu values exceeded their respective guidelines. The potential toxicity of elements exceeding guidelines, however, should be considered in the context of strong enrichments of selected trace elements attributable to source rocks in Hawai‘i, as well as in the context of the abundance of fine-grained sediment in the streambed of O‘ahu streams.Statistical methods including cluster analysis, Kruskal–Wallis non-parametric test, correlation analysis, and principal component analysis (PCA) were used to evaluate differences and elucidate relationships between trace elements and sites. Overall, trace element distributions and abundances can be correlated to three principal sources of elements. These include basaltic rocks of the volcanic edifice (Fe, Al, Ni, Co, Cr, V and Cu), carbonate/seawater derived elements (Mg, Ca, Na and Sr), and elements enriched owing to anthropogenic activity (P, Sn, Cd, Sn, Ba and Pb). Anthropogenic enrichment gradients were observed for Ba, Cd, Pb, Sn and Zn in the four streams in which sediments were collected upstream and downstream.The findings of this study are generally similar to but differ slightly from previous work on sediments and suspended particulate matter in streams, from two urban watersheds of O‘ahu, Hawai‘i. Inter-element associations in the latter were often stronger and indicated a mixture of anthropogenic, agricultural and basaltic sources of trace elements. Some elements fell into different statistical categories in the two studies, owing in part to differences in study design and the hydrogeological constraints on the respective study areas.  相似文献   
160.
Meteoric smoke particles (MSPs) form through the vaporization of meteoroids and the subsequent re-condensation of metallic species in the mesosphere. Recently, iridium and platinum enrichments have been identified in Greenland ice layers and attributed to the fallout of MSPs supplying polar latitudes with cosmic matter during the Holocene. However, the MSP fallout to Antarctica during the Earth's climatic history remains essentially unknown.

We have determined iridium and platinum in deep Antarctic ice from Dome C and Vostok dated back to 240 kyrs BP. We find high super-chondritic fluxes during warm periods and low meteoric accretion during glacial times, a pattern that is opposite to any known climatic variation in dust fallout to polar regions. The proposed explanation of this accretion regime is a weaker polar vortex during warm periods, allowing peripheral air masses enriched in volcanic iridium and platinum to penetrate inland to Antarctica. The MSP signal emerges only during cold phases and is four times lower than in the Greenland ice cap where more snow accumulates. This suggests that wet deposition is an important route of cosmic material to the Earth's surface.  相似文献   

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