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121.
Limaverde AM Wagener Ade L Fernandez MA Scofield Ade L Coutinho R 《Marine environmental research》2007,64(3):384-398
Stramonita haemastoma was investigated as a suitable bioindicator of TBT and TPhT contamination in the tropical Atlantic Ocean by: 1. Imposex induction in healthy females after inoculation with TBT and TPhT in the laboratory; and 2. Determining incidence of imposex in S. haemastoma collected from areas with various levels of tributyltin (TBT) and triphenyltin (TPhT) and determining the concentrations of these chemical in its tissues and that of its prey, the mussell Perna pernas. Imposex intensities and organotin concentrations in tissues showed good correlation, indicating S. haemastoma as a reliable bioindicator of TBT and TPhT contamination in coastal waters. Body burden threshold of TBT and TPhT for imposex induction was estimated to be 10-20 ng g(-1). 相似文献
122.
Claudio Marchesi William L. Griffin Carlos J. Garrido Jean-Louis Bodinier Suzanne Y. O’Reilly Norman J. Pearson 《Contributions to Mineralogy and Petrology》2010,159(3):315-330
The western part of the Ronda peridotite massif (Southern Spain) consists mainly of highly foliated spinel-peridotite tectonites
and undeformed granular peridotites that are separated by a recrystallization front. The spinel tectonites are interpreted
as volumes of ancient subcontinental lithospheric mantle and the granular peridotites as a portion of subcontinental lithospheric
mantle that underwent partial melting and pervasive percolation of basaltic melts induced by Cenozoic asthenospheric upwelling.
The Re–Os isotopic signature of sulfides from the granular domain and the recrystallization front mostly coincides with that
of grains in the spinel tectonites. This indicates that the Re–Os radiometric system in sulfides was highly resistant to partial
melting and percolation of melts induced by Cenozoic lithospheric thermal erosion. The Re–Os isotopic systematics of sulfides
in the Ronda peridotites thus mostly conserve the geochemical memory of ancient magmatic events in the subcontinental lithospheric
mantle. Os model ages record two Proterozoic melting episodes at ~1.6 to 1.8 and 1.2–1.4 Ga, respectively. The emplacement
of the massif into the subcontinental lithospheric mantle probably coincided with one of these depletion events. A later metasomatic
episode caused the precipitation of a new generation of sulfides at ~0.7 to 0.9 Ga. These Proterozoic Os model ages are consistent
with results obtained for several mantle suites in Central/Western Europe and Northern Africa as well as with the Nd model
ages of the continental crust of these regions. This suggests that the events recorded in mantle sulfides of the Ronda peridotites
reflect different stages of generation of the continental crust in the ancient Gondwana supercontinent. 相似文献
123.
Analytical and empirical methods used in current engineering practice for estimating inflow rate into a tunnel do not adequately account for the effect of groundwater level drawdown which triggers changes of the flow pattern as well as reductions of the hydraulic head. When there is no reservoir or a large body of water near the tunnel alignment, the groundwater recharge above the tunnel might not be fast enough to avoid a significant excavation-induced water level drawdown. This paper provides analytical methods for estimating groundwater inflow rate taking into account the groundwater table drawdown. The proposed analytical solutions presented here compare well with field observations as well as with results from numerical analysis using distinct element method which can adequately simulate the hydro-mechanically coupled behavior of joints in a rock mass. 相似文献
124.
Carlos Salazar-Camacho 《Geochimica et cosmochimica acta》2010,74(8):2257-568
We developed a model that describes quantitatively the arsenate adsorption behavior for any goethite preparation as a function of pH and ionic strength, by using one basic surface arsenate stoichiometry, with two affinity constants. The model combines a face distribution-crystallographic site density model for goethite with tenets of the Triple Layer and CD-MUSIC surface complexation models, and is self-consistent with its adsorption behavior towards protons, electrolytes, and other ions investigated previously. Five different systems of published arsenate adsorption data were used to calibrate the model spanning a wide range of chemical conditions, which included adsorption isotherms at different pH values, and adsorption pH-edges at different As(V) loadings, both at different ionic strengths and background electrolytes. Four additional goethite-arsenate systems reported with limited characterization and adsorption data were accurately described by the model developed. The adsorption reaction proposed is:
125.
时间延迟对劈裂试验条件下岩石凯塞效应的影响 总被引:1,自引:0,他引:1
验证了粗晶花岗岩在劈裂试验条件下凯塞效应的存在性。进行了循环加卸载时间间隔分别为2、15d和45d时岩石的声发射试验,讨论了时间延迟对花岗岩凯塞效应的影响。研究结果表明,前期荷载越接近极限强度,岩石的凯塞效应越不明显;凯塞效应随再次加载时间延迟的增加而削弱,在对花岗岩的声发射试验中观察到15d以后岩石的凯塞效应仍然很显著,45d后凯塞效应基本消失。文中同时对试件与加载设备之间的接触状态对声发射试验结果的影响作了初步的定性分析。 相似文献
126.
Ordovician igneous rocks in the western Acatlán Complex (Olinalá area) of southern Mexico include a bimodal igneous suite that intrudes quartzites and gneisses of the Zacango Unit, and all these rocks were polydeformed and metamorphosed in the amphibolite facies during the Devono-Carboniferous. The Ordovician igneous rocks consist of the penecontemporaneous amphibolites, megacrystic granitoids and leucogranite, the latter dated at ca. 464 Ma. Geochemical and Sm–Nd data indicate that the amphibolites have a differentiated tholeiitic signature, and that its mafic protoliths formed in an extensional setting transitional between within-plate and ocean floor. The amphibolites are variably contaminated by a Mesoproterozoic crustal source, inferred to be the Oaxacan basement exposed in the adjacent terrane. The most primitive samples have εNdt (t = 465 Ma) values significantly below that of the contemporary depleted mantle and were probably derived from the sub-continental lithospheric mantle. The megacrystic granites were most probably derived by partial melting of an arc crustal source (similar to the Oaxacan Complex) and triggered by the ascent of mafic magma from the lithospheric mantle. Sm–Nd isotopic signatures suggest that metasedimentary rocks from Zacango Unit were derived from adjacent Oaxacan Complex. Trace elements relationships (e.g. La/Th vs. Hf) and REE patterns suggest provenance in felsic-intermediate igneous rocks with a calc-alkaline signature. The Ordovician bimodal magmatism is inferred to have resulted from rifting on the southern flank of the Rheic Ocean and is an expression of a major rifting event that occurred along much of the northern Gondwanan margin in the Ordovician. 相似文献
127.
João Magalhães Neto Heliana Teixeira Joana Patrício Alexandra Baeta Helena Veríssimo Rute Pinto João Carlos Marques 《Estuaries and Coasts》2010,33(6):1327-1339
Anthropogenic activities are a disturbance factor of coastal systems and can be widely recognized as a major threat to the
health of coastal systems. However, natural events cannot be disregarded from management issues because of their significant
influence on the communities living in these areas. Based on long-term subtidal data from the Mondego Estuary (Portugal),
the effects of natural events (e.g., floods and droughts) on macrobenthic communities were compared with the anthropogenic
events. Sampling stations were grouped into characteristic zones (mouth, north arm, south arm) so the community dynamics of
each of these estuarine areas could be followed over time. Environmental assessment was performed for stations using the Benthic
Assessment Tool (BAT), and compared with the existing pressures. Human impacts persist over a number of years and gradually
reduce ecosystem health, as discussed in the European Water Framework Directive. Paradoxically, natural events cause stronger
impacts but are of a shorter duration, which allows for a faster recovery of macrobenthic communities. The study showed that
caution should be taken when developing and implementing water policies so as not to disregard the importance of the different
events (natural and human-caused) on the ecosystem health (e.g., community degradation and water quality and ecological quality
status assessment). 相似文献
128.
Arias-Molinares Daniela García-Palomares Juan Carlos Romanillos Gustavo Gutiérrez Javier 《Journal of Geographical Systems》2023,25(3):403-427
Journal of Geographical Systems - In the past ten years, cities have experienced a burst of micromobility services as they offer a flexible transport option that allows users to cover short trips... 相似文献
129.
Given the coarse resolution of global climate models, downscaling techniques are often needed to generate finer scale projections of variables affected by local-scale processes such as precipitation. However, classical statistical downscaling experiments for future climate rely on the time-invariance assumption as one cannot know the true change in the variable of interest, nor validate the models with data not yet observed. Our experimental setup involves using the Canadian regional climate model (CRCM) outputs as pseudo-observations to estimate model performance in the context of future climate projections by replacing historical and future observations with model simulations from the CRCM, nested within the domain of the Canadian global climate model (CGCM). In particular, we evaluated statistically downscaled daily precipitation time series in terms of the Peirce skill score, mean absolute errors, and climate indices. Specifically, we used a variety of linear and nonlinear methods such as artificial neural networks (ANN), decision trees and ensembles, multiple linear regression, and k-nearest neighbors to generate present and future daily precipitation occurrences and amounts. We obtained the predictors from the CGCM 3.1 20C3M (1971–2000) and A2 (2041–2070) simulations, and precipitation outputs from the CRCM 4.2 (forced with the CGCM 3.1 boundary conditions) as predictands. Overall, ANN models and tree ensembles outscored the linear models and simple nonlinear models in terms of precipitation occurrences, without performance deteriorating in future climate. In contrast, for the precipitation amounts and related climate indices, the performance of downscaling models deteriorated in future climate. 相似文献
130.
Vegetation is a natural source of Volatile Organic Compounds (VOC) that plays an important role in atmospheric chemistry. The main objective of the current study is to implement a model to quantify process-based VOC emissions from plants that focuses on the relationship between the sensitivity of VOC emission estimates to spatial resolution data, based on scientific knowledge and vegetation dynamics derived from satellite observations. The Normalized Difference Vegetation Index (NDVI) and Leaf Area Index (LAI) were elected to examine this issue using different resolutions of satellite-derived products: 22m from the DEIMOS-1 satellite, and 250m and 1000m provided by MODIS. The study is focused on an area of 80×80km2 in Portugal for 2011. Detailed land cover and meteorological data are also included in the emission quantification algorithm. The primary outcomes were determined using a multi-scale analysis showing spatial and temporal variations in the vegetation parameters and modeling results. The results confirm that the emissions model is highly sensitive to the spatial resolution of the satellite-derived data, resulting in about a 30% difference in total isoprene emissions for the study area. 相似文献