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11.

Phosphorus (P) is an essential nutrient required for plant growth and at the same time a costly pollutant, which can cause eutrophication of water bodies. Modern agriculture relies heavily on mineral fertilisers, which contain phosphorus derived from phosphate rock, because, without regular applications, crop yields would be limited. Since phosphate rock is a non-renewable resource, there are growing concerns regarding future phosphorus scarcity and the sustainability of modern agriculture. For many farmers, animal manure was once a means of maintaining soil fertility, but now it presents a major operational problem. This study evaluated the possibility of recycling phosphorus on a national and regional scale in Italy, using major sources of manure and wastewater. These results were successively compared with an estimate of the agricultural demand for phosphorus. Considering the quantity of phosphorus fertilizer that was applied to the soil–plant system, for the years 2001–2010, the annual phosphorus requirement of Italian crops was about 101,000 t of P. Therefore, the phosphorus source comprising animal manure and civil/industrial waste (117,500 t of P and 40,000 t of P, respectively) could potentially satisfy the average annual agronomic phosphorus demand. Regarding the geographical distribution of phosphorus supply and demand on a regional scale, areas with a large deficit of phosphorus included Calabria, Puglia and Marche. However, when only livestock waste was considered, Sicily, Umbria and Friuli could also be considered to be regions experiencing a phosphorus deficit.

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The marine sector surrounding Panarea Island (Aeolian Islands, South Italy) is affected by widespread submarine emissions of CO2 -rich gases and thermal water discharges which have been known since the Roman Age. On November 3rd, 2002 an anomalous degassing event affected the area, probably in response to a submarine explosion. The concentrations of minor reactive gases (CO, CH4 and H2) of samples collected in November and December, 2002 show drastic compositional changes when compared to previous samples collected from the same area in the 1980s. In particular the samples collected after the November 3rd phenomenon display relative increases in H2 and CO and a strong decrease in the CH4 contents, while other gas species show no significant change. The interaction of the original gas with seawater explains the variable contents of CO2, H2S, N2, Ar and He which characterize the different samples, but cannot explain the large variations of CO, CH4 and H2 which are instead compatible with changes in the redox, temperature and pressure conditions of the system. Two models, both implying an increasing input of magmatic fluids are compatible with the observed variations of minor reactive species. In the first one, the input of magmatic fluids drives the hydrothermal system towards atypical (more oxidizing) redox conditions, slowly pressurizing the system up to a critical state. In the second one, the hydrothermal system is flashed by the rising high-T volcanic fluid, suddenly released by a magmatic body at depth. The two models have different implications for volcanic surveillance and risk assessment: In the first case, the November 3rd event may represent both the culmination of a relatively slow process which caused the overpressurization of the hydrothermal system and the beginning of a new phase of quiescence. The possible evolution of the second model is unforeseeable because it is mainly related to the thermal, baric and compositional state of the deep magmatic system that is poorly known.  相似文献   
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Stochastic ground motion models produce synthetic time‐histories by modulating a white noise sequence through functions that address spectral and temporal properties of the excitation. The resultant ground motions can be then used in simulation‐based seismic risk assessment applications. This is established by relating the parameters of the aforementioned functions to earthquake and site characteristics through predictive relationships. An important concern related to the use of these models is the fact that through current approaches in selecting these predictive relationships, compatibility to the seismic hazard is not guaranteed. This work offers a computationally efficient framework for the modification of stochastic ground motion models to match target intensity measures (IMs) for a specific site and structure of interest. This is set as an optimization problem with a dual objective. The first objective minimizes the discrepancy between the target IMs and the predictions established through the stochastic ground motion model for a chosen earthquake scenario. The second objective constraints the deviation from the model characteristics suggested by existing predictive relationships, guaranteeing that the resultant ground motions not only match the target IMs but are also compatible with regional trends. A framework leveraging kriging surrogate modeling is formulated for performing the resultant multi‐objective optimization, and different computational aspects related to this optimization are discussed in detail. The illustrative implementation shows that the proposed framework can provide ground motions with high compatibility to target IMs with small only deviation from existing predictive relationships and discusses approaches for selecting a final compromise between these two competing objectives.  相似文献   
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This work is aimed at investigating the weathering processes of the granodiorites cropping out in a small catchment of the Sila Massif. The mineral constituents in this granodiorite are plagioclase, often zoned with a Ca-rich core and a Na-rich rim, quartz, chlorite, K-feldspar, white mica and epidote. During this study, dolomite was discovered in local stream sediments, as separate monomineralic grains, probably resulting from erosion of veins cutting the crystalline rocks. Prevailing dissolution of foreign dolomite and a Ca-rich plagioclase is suggested by the Ca–Mg–HCO3 chemical composition of local groundwaters and stream waters, which is rather unexpected for waters interacting with granitoid rocks. These qualitative observations are quantitatively confirmed by reaction path modelling of the weathering processes occurring in the study area, which was carried out using the EQ3/6 software package, version 8.0, and the Double Solid Reactant Method. Indeed, it was possible to ascertain that the release of both major dissolved constituents and several trace elements (Ba, Co, Cr, Fe, Mn, Ni, Pb, Sr, V and Zn), from rocks to waters, is chiefly controlled by the dissolution of foreign dolomite and the Ca-rich core of zoned plagioclases.  相似文献   
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Damage observed in existing structures after recent earthquake events pointed out the key importance of beam-to-column joints in influencing the global response of reinforced concrete structures. In the last two decades several theoretical and empirical models have been proposed for evaluating shear strength of beam-to-column joints. The present paper reports an overview of the models currently available in the scientific literature for evaluating shear capacity of exterior beam-to-column joints. The present study is the first step of a wide analysis aimed at assessing such models and improving them. Moreover, the uncertainties deriving by applying the mentioned models will be also quantified therein, by means of well-established procedures for probabilistic seismic analysis of structures. The final results of that study are reported within a companion paper.  相似文献   
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Several theoretical models are currently available in the scientific literature for evaluating the shear capacity of both exterior and interior beam-to-column joints in reinforced concrete (RC) frames. A reasonably wide set of those models, based on either analytical or empirical formulations, has been summarised within a companion work. The present paper firstly presents a wide database which collects results obtained in about two-hundred experimental tests carried out on RC joints. Those results are employed for assessing the above mentioned capacity models by considering a set of experimental data much wider than those usually utilised in the original formulation of such models. Accuracy and reliability of the various models are measured by quantifying some statistical parameters actually describing the relationship between the experimental evidence and the prediction of the various capacity models under consideration. Three relevant classes of joints (namely unreinforced, under reinforced and code-compliant) are considered with the aim of emphasising that the various models perform in a rather different way when applied to those different classes. Finally, a possible recalibration of the various models is proposed with the objective of enhancing their predictive capacity with respect to both the database as a whole and the three classes of RC joints mentioned above.  相似文献   
19.
Major, trace element and Sr-isotope compositions are reported for a suite of lavas coming from the area of Commenda in the SE Vulsinian district. The analyzed samples have all low silica contents and variable but generally high CaO, MgO and FeOt. Based on K2O% and K2O/Na2O ratio, the rocks from Commenda can be classified as belonging to the Potassic Series (KS) and the High-potassium Series (HKS). The HKS rocks appear to have derived by cristal/liquid fractionation from the most mafic types with separation of olivine and clinopyroxene and then of clinopyroxene + leucite. The most primitive HKS rocks have aphyric texture and high Mg-values, Cr and Ni contents which are close or within the range of values of magmas formed by partial melting of periodititic mantle sources. The KS rocks have lower incompatible element contents as the HKS rocks with similar degree of evolution.The variations of Sr-isotopic ratios of the analyzed rocks and of other Vulsinian lavas, indicate that the basic HKS Vulsinian rocks did not interact significantly with the continental crust. Instead, the KS appears to have evolved by combined crystal fractionation and assimilation processes, starting from parental magmas which had87Sr/86Sr ratio not significantly lower than that found in the less evolved rocks of the suite.The most primitive HKS rocks from Commenda have hygromagmatophile element distribution pattern characterized by high ratio of LILE/HFSE with negative anomalies of Ta and Ti, resembling closely those of other Roman mafic volcanics. The primitive geochemical characteristics of the Commenda rocks exclude that these features are the products of interaction with the crust and provide a further support to the hypothesis of a genesis within a subduction-modified mantle source.  相似文献   
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Earthquake Engineering and Engineering Vibration - Self-centering earthquake-resistant structures have received increased attention due to their ability to reduce post-earthquake residual...  相似文献   
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