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121.
Low-angle normal faults accommodate a large part of continental post-orogenic extension. Besides the intrinsic rheological characteristics of the continental crust that may lead to the formation of shallow-dipping shear zones at the brittle–ductile transition, the role of pre-existing low-angle structures such as large thrusts has been proposed by several authors. We explore this question with the example of the North Cycladic Detachment System (NCDS) that is composed of a series of distinct detachments cropping out on the islands of Andros, Tinos and Mykonos, separating the Cycladic Blueschists in the footwall from the Upper Cycladic Nappe in the hanging wall. We show that these extensional structures are part of a single large-scale structure (more than 200 km along strike) that reactivates the Vardar suture zone. It extends eastward on Ikaria and westward offshore Evia and Thessalia where it probably connects to recent shallow-dipping normal faults evidenced on published seismic reflection profiles. The NCDS started its activity in the Oligocene concommitantly with the Aegean extension, and was still active in the Late Miocene. It has exhumed a series of metamorphic domes from southern Evia to Mykonos below low-angle detachment systems, made of low-angle normal faults and low-angle ductile shear zones. The ductile shear zones and the faults were created with a low dip and they kept the same attitude throughout their exhumation. We identify three main detachments that are part of a continuum of extension on the NCDS : Tinos detachment, Livada detachment and Mykonos detachment. A fourth detachment (Vari detachment) is the reactivation of an Eocene exhumation-related structure. Deformation in the footwall is characterized by intense stretching and flattening. Using the spatial evolution observed along strike from Andros to Mykonos we construct a history of formation of the NCDS starting with the reactivation of former thrusts leading to the exhumation of high-temperature metamorphic domes. The Aegean example shows that reactivation of earlier shallow-dipping discontinuities can play a fundamental role in continental post-orogenic extension.  相似文献   
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123.
We investigated the phosphorus (P) and iron (Fe) fractionation in four cores with anoxic sediments, deposited during the mid-Cretaceous oceanic anoxic event 2 (∼94 Ma) and the Paleocene-Eocene thermal maximum (∼55 Ma), that were exposed to oxygen after core recovery. Surprisingly, P associated with iron oxyhydroxides (Fe-bound P) was a major P phase in these laminated sediments deposited under euxinic conditions. A significant fraction of total Fe was present as (poorly) crystalline ferric Fe. This fraction increased with increasing storage time of the investigated cores. In carbonate-poor samples, Fe-bound P accounted for up to 99% of total P and its abundance correlated with pyrite contents. In samples with higher CaCO3 contents (>5 wt% in the investigated samples), P was mostly present in authigenic Ca-P minerals, irrespective of pyrite contents. We conclude that the P fractionation in anoxic, carbonate-poor, sediments is strongly affected by pyrite oxidation that occurs when these sediments are exposed to oxygen. Pyrite oxidation produces sulfuric acid and iron oxyhydroxides. The abundance of poorly crystalline Fe oxyhydroxides provides further evidence that these were indeed formed through recent (post-recovery) oxidation rather than in situ tens of millions of years ago. The acid dissolves apatite and the released phosphate is subsequently bound in the freshly formed iron oxyhydroxides. Pyrite oxidation thus leads to a conversion of authigenic Ca-P to Fe-bound P. In more calcareous samples, CaCO3 can act as an effective buffer against acidic dissolution of Ca-P minerals. The results indicate that shielding of sediments from atmospheric oxygen is vital to preserve the in situ P fractionation and to enable a valid reconstruction of marine phosphorus cycling based on sediment records.  相似文献   
124.
Sorption of Ni to birnessite is a fundamental control on the concentration of Ni in natural waters and associated sediments. Recent XAS work suggests the crystal-chemistry of Ni in birnessite is dependent on both structural and physiochemical factors. This work investigates the physiochemical controls on Ni crystal-chemistry in hexagonal birnessite with EXAFS of time series and pH series Ni-birnessite sorption experiments. At circumneutral pH Ni surface adsorbed above/below Mn octahedral vacancy sites in the phyllomanganate layers is progressively structurally incorporated into the vacancy sites with time (30% Ni incorporation after 408 h contact time). Ni structural incorporation into hexagonal birnessite occurs via rearrangement of surface adsorbed Ni with time rather than direct Ni incorporation from solution. At low pH (pH 4) Ni surface adsorbed at the vacancies is structurally incorporated into the vacancies upon increasing solution pH to circumneutral (∼20% Ni incorporation after 24 h contact time at circumneutral pH); newly incorporated Ni is stable with increasing contact time at pH circumneutral. However, upon decreasing solution pH from circumneutral back to pH 4, EXAFS shows a significant decrease in the proportion of Ni structurally incorporated; preliminary results indicate structural incorporation of Ni in hexagonal birnessite is reversible with decreasing pH. Time series results at circumneutral pH help explain the significant enrichment of Ni in marine ferromanganese precipitates; work here is combined with previous studies to provide a model correct at the molecular-level for Ni uptake by marine vernadite-rich ferromanganese precipitates. With Ni migrating from surface adsorbed to structurally incorporated, results suggest formation of a solid solution between an end-member vernadite and an end-member Ni-vernadite phase, with surface adsorption acting as a mechanism of transition from one composition to the other. pH series results call into question the viability of Ni crystal-chemistry in natural vernadite as a paleo-proxy for paleo-pH conditions in freshwater systems and challenge the traditional view that structurally incorporated trace-metals are stable within the Eh-pH field of the host mineral phase. Natural birnessite may not be as permanent a sink for Ni as first suggested by Ni crystal-chemistry.  相似文献   
125.
International Journal of Earth Sciences - New U–Pb dating on zircon yielded ca. 470 Ma ages for the granitoids from the Lévézou massif in the southern French Massif...  相似文献   
126.
Experiments to measure natural rates of sedimentation and to assess the tolerance of coral species to increased sedimentation were conducted at San Cristobal Reef, Puerto Rico. Sedimentation rates were measured over an 18 month period. Calcareous sediments were applied to colonies of Montastraea annularis, Diploria strigosa, D. clivosa, Acropora palmata and A. cervicornis in different frequencies and in different doses.Mean sedimentation rates from sediment traps were 9.6±2.4 (S.E.) mg cm?2 · day?1 at 10 cm above the bottom and 2.5±0.9 (S.E.) and 2.6±1.2 (S.E.) mg cm?2 · day?1 for two sets of traps at 50 cm above the bottom. Sediment application experiments indicated A. palmata was the least tolerant of the species tested. Although A. cervicornis and D. strigosa colonies were not significantly affected, single applications of 800 mg cm?2 to M. annularis colonies and of 200 mg cm?2 to A. palmata colonies caused death of underlying coral tissue. Algae colonized the smothered portions of these corals.  相似文献   
127.
We describe amphibolite-facies shear zones affecting an orthogneiss from the Armorican Hercynian belt (Ile d’Yeu, western France). The deformation pattern is consistent with top-to-the-South thrusting followed by E–W extension, as documented elsewhere in the region. Shearing was accompanied by channelled fluid flow that transformed the orthogneiss into a peraluminous micaschist. Structural and mineralogical data indicate rather early strain localization. Then, temperature increase associated with crustal thickening favoured more distributed deformations marked by shear zone stretching and the development of a HT regional foliation. Chemical analyses made across five shear zones show mass transfers that mainly implied losses in Ca and Na, and gains in H2O, Mg, and K. Most results indicate constant volume transformation, but some suggest records of either gains or losses of volume (between +20% and −30%). This might reflect variable records of fluid-rock interactions according to the timing of initiation and subsequent evolution of individual shear zones, early thrusting stages being marked by up-temperature flow, and late thrusting stages by down-temperature flow. δ18O analyses suggest that fluids experienced significant isotopic exchange with orthogneisses.  相似文献   
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129.
We study the ratio between the gravity variation and vertical displacement on the surface of a self-gravitating earth model when a surface load is applied. We adopt a theoretical and numerical point of view, excluding any observations. First, we investigate the spectral behavior of the ratio of the harmonic components of the gravity variation and vertical displacement. Then, we model the gravity-to-height ratio for different surface loads (continental hydrology, atmospheric pressure, ocean tides) using outputs of global numerical models in order to relate the predicted spatial values to theoretical mean values deduced from the spectral domain. For locations inside loaded areas, the ratio is highly variable because of the Newtonian attraction of the local masses and depends on the size of the load. For the hydrological loading (soil moisture and snow), the mean ratio over the continents is  ?0.87 μGal mm?1, but increases with decreasing size of the river basins. For the atmospheric loading, assuming an inverted-barometer response of the ocean, the ratio is positive, with larger values for high latitudes (0.49 μGal mm?1)—particularly on the coasts—than for lower latitudes (0.30 μGal mm?1). The ratio, however, is much less variable outside the loaded areas: in desert areas such as the Sahara and Arabia, its mean value is  ?0.28 μGal mm?1. For the ocean tidal loading, we find a mean ratio of  ?0.26 μGal mm?1 over the continents for the diurnal tidal waves. Both results are close to the theoretical mean value of  ?0.26 μGal mm?1 combining elastic and remote attraction contributions.  相似文献   
130.
While it is well recognized that vegetation can affect erosion, sediment yield and, over longer timescales, landform evolution, the nature of this interaction and how it should be modeled is not obvious and may depend on the study site. In order to develop quantitative insight into the magnitude and nature of the influence of vegetation on catchment erosion, we build a landscape evolution model to simulate erosion in badlands, then calibrate and evaluate it against sediment yield data for two catchments with contrasting vegetation cover. The model couples hillslope gravitational transport and stream alluvium transport. Results indicate that hillslope transport processes depend strongly on the vegetation cover, whereas stream transport processes do not seem to be affected by the presence of vegetation. The model performance in prediction is found to be higher for the denuded catchment than for the reforested one. Moreover, we find that vegetation acts on erosion mostly by reducing soil erodibility rather than by reducing surface runoff. Finally, the methodology we propose can be a useful tool to evaluate the efficiency of previous revegetation operations and to provide guidance for future restoration work. © 2019 John Wiley & Sons, Ltd.  相似文献   
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