Comparison of a Homemade Bacuri Shell Activated Carbon With Carbon Nanotubes for Food Dye Removal          下载免费PDF全文

Caroline Saucier  Matthew A. Adebayo  Eder C. Lima  Lizie D. T. Prola  Pascal S. Thue  Cibele S. Umpierres  Mayerly J. Puchana‐Rosero  Fernando M. Machado 《洁净——土壤、空气、水》2015,43(10):1389-1400

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On the use of long-term observation of water level and temperature along the shore for a better understanding of the dynamics: example of Toulon area,France     

Rey  Vincent  Dufresne  Christiane  Fuda  Jean-Luc  Mallarino  Didier  Missamou  Tathy  Paugam  Caroline  Rougier  Gilles  Taupier-Letage  Isabelle 《Ocean Dynamics》2020,70(7):913-933

Ocean Dynamics - A dense network of instruments has been deployed within harbors along the Mediterranean coast, in the Toulon Metropole area, between the Hyères islands and the Sanary Bay in...  相似文献   

First interactions with the hydrologic cycle determine pyrogenic carbon's fate in the Earth system     

Caroline Ann Masiello  Asmeret Asefaw Berhe 《地球表面变化过程与地形》2020,45(10):2394-2398

Fires produce an aromatic particulate residue commonly referred to as pyrogenic carbon (PyC). Particulate PyC is low density, high porosity, and is predominantly deposited on the soil surface in post-fire landscapes. These characteristics create a material that is prone to mobility, both vertically down the soil profile and laterally across the landscape even in low-relief landforms. Because of its tendency for lateral mobilization, we argue here that PyC's first interaction with water determines its environmental fate and persistence, not its interactions with soil minerals or microbes. PyC's first interactions with water determine: the amount of PyC that will enter the soil profile and experience microbial and geochemical alterations, whether it will be buried in depositional environments and stored on the landscape, or if it will be transported to streams and eventually to the ocean. Here we posit that this crucial first interaction with the hydrologic cycle occurs on the timescale of days to weeks, and therefore supersedes microbial decomposition as the primary control on PyC's environmental persistence. © 2020 John Wiley & Sons, Ltd.  相似文献   

Timing,magnitude and geochemistry of major Southeast Asian volcanic eruptions: identifying tephrochronologic markers     

Caroline Bouvet De Maisonneuve  Olga Bergal-Kuvikas 《第四纪科学杂志》2020,35(1-2):272-287

We review the current knowledge about Southeast Asian volcanoes and their eruption histories, and focus on identifying tephrochronologic markers representing major explosive eruptions in order to further future palaeoclimate and volcanological studies. Forty-one volcanic edifices in Southeast Asia have been classified as large calderas by Whelley et al. (2015) and thus have, or are likely to have, produced large explosive eruptions with a Volcanic Explosivity Index (VEI) of 6–8. Unfortunately, only 20 such eruptions have known ages, spanning from 1.2 Ma to 1991 ad , and fewer have geochemical data that can be used for tephrostratigraphic correlations. Volcanic products from different geodynamic regions and different sources can generally be distinguished on major element plots (e.g. K₂O versus CaO) of matrix glass composition. However, the distinction of multiple eruptions from the same source often requires additional data such as trace element compositions of matrix glass and/or mineral compositions. Biotite, but also magnetite compositions (MgO and TiO₂ content in particular) appear to be very discriminating. Up to nine tuffs in addition to the three to four Toba tuffs can be utilised as widespread tephrochronologic markers and span a range from 1.2 to 1.6 Ma to recent. As only a few Holocene major eruptions have been well characterised and dated, many large calderas are still unstudied, and many distal tephra layers are still lacking a source, more tephrochronologic markers can certainly be defined in the future.  相似文献   

A continuous plate-tectonic model using geophysical data to estimate plate-margin widths, with a seismicity-based example     

Caroline Dumoulin  David Bercovici  & Pål Wessel 《Geophysical Journal International》1998,133(2):379-389

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The Bothnian Sea ice stream: early Holocene retreat dynamics of the south‐central Fennoscandian Ice Sheet     

Sarah L. Greenwood  Caroline C. Clason  Johan Nyberg  Martin Jakobsson  Per Holmlund 《Boreas: An International Journal of Quaternary Research》2017,46(2):346-362

The Gulf of Bothnia hosted a variety of palaeo‐glaciodynamic environments throughout the growth and decay of the last Fennoscandian Ice Sheet, from the main ice‐sheet divide to a major corridor of marine‐ and lacustrine‐based deglaciation. Ice streaming through the Bothnian and Baltic basins has been widely assumed, and the damming and drainage of the huge proglacial Baltic Ice Lake has been implicated in major regional and hemispheric climate changes. However, the dynamics of palaeo‐ice flow and retreat in this large marine sector have until now been inferred only indirectly, from terrestrial, peripheral evidence. Recent acquisition of high‐resolution multibeam bathymetry opens these basins up, for the first time, to direct investigation of their glacial footprint and palaeo‐ice sheet behaviour. Here we report on a rich glacial landform record: in particular, a palaeo‐ice stream pathway, abundant traces of high subglacial meltwater volumes, and widespread basal crevasse squeeze ridges. The Bothnian Sea ice stream is a narrow flow corridor that was directed southward through the basin to a terminal zone in the south‐central Bothnian Sea. It was activated after initial margin retreat across the Åland sill and into the Bothnian basin, and the exclusive association of the ice‐stream pathway with crevasse squeeze ridges leads us to interpret a short‐lived stream event, under high extension, followed by rapid crevasse‐triggered break‐up. We link this event with a c. 150‐year ice‐rafted debris signal in peripheral varved records, at c. 10.67 cal. ka BP. Furthermore, the extensive glacifluvial system throughout the Bothnian Sea calls for considerable input of surface meltwater. We interpret strongly atmospherically driven retreat of this marine‐based ice‐sheet sector.  相似文献   

The loess sequence of Dolní Věstonice,Czech Republic: A new OSL‐based chronology of the Last Climatic Cycle     

Markus Fuchs  Sebastian Kreutzer  Denis‐Didier Rousseau  Pierre Antoine  Christine Hatté  France Lagroix  Olivier Moine  Caroline Gauthier  Jiri Svoboda  Lenka Lisá 《Boreas: An International Journal of Quaternary Research》2013,42(3):664-677

The Dolní Věstonice loess section in the Czech Republic is well known for its high‐resolution loess–palaeosol sequence of the last interglacial–glacial climatic cycle (Upper Pleistocene). The loess section is situated in a climatic transition zone between oceanic and continental climates and is therefore of great value in reconstructing past regional climate conditions and their interaction with climate systems, in particular that of the North Atlantic. Based on a combination of optically stimulated luminescence (OSL) ages, stratigraphic field observations and magnetic susceptibility measurements, a chrono‐climatic interpretation of the Dolní Věstonice loess section is presented. To establish a reliable Upper Pleistocene chronology, a quartz OSL approach was applied for equivalent dose (D_e) determination. Monomineralic quartz extracts of three distinct grain sizes, fine (4–11 μm), middle (38–63 μm) and coarse (90–200 μm), were used and compared. Within error limits, the calculated OSL ages are the same for the different grain sizes, and the OSL ages are in stratigraphic order. The established OSL chronology is in agreement with a Weichselian litho‐ and pedostratigraphy. The Dolní Věstonice loess section is characterized by four pedosedimentary subsequences. At the base of the profile, subsequence I is characterized by a distinct Early Glacial soil complex, OSL‐dated to c. 110 to 70 ka, representing one of the most complete records of environmental change in the European loess belt. Subsequence II is allocated to the Lower Pleniglacial and is characterized by laminated sandy loess. Middle Pleniglacial subsequence III is represented by a brown soil complex, and is followed by the uppermost subsequence IV, characterized by a thick body of laminated sandy loess, indicating strong wind activity and a high sedimentation rate of more than ～1 mm a^?1 during the Upper Pleniglacial. According to the OSL chronology, as well as to the sedimentological and palaeopedological investigations, it is likely that the sequence at Dolní Věstonice has recorded most of the climatic events expressed in the NGRIP δ¹⁸O reference record between 110 and 70 ka.  相似文献   

Living off the land: Nature and nomadism in Mongolia     

Caroline Upton 《Geoforum》2010,41(6):865-874

The demise of the Soviet Union precipitated profound changes in formerly collectivised rural spaces across Eastern Europe and Central Asia. However, it is only recently that attention to the post-Soviet ‘land question’ has begun to move beyond predominant, practical concerns with land restitution and fragmentation and towards engagement with diverse discourses of rurality, nature and modernity. In particular, longitudinal accounts of the narratives and practices of Soviet modernisation and post-Soviet “development” in specific rural places and societies are lacking. This paper is concerned with the complex linkages between environmental policies, practice and concepts of nature in such spaces and over recent history. Through examination of the management and representation of nature amongst pastoralist communities in Mongolia and in the collective and post-collective eras this paper seeks to understand local-level enactments, reworking and assimilation of externally-derived discursive and policy formulations. In doing so it acts as a corrective to state-centred and homogenising visions of Soviet and post-Soviet rurality. It highlights how local herders’ ‘room for manoeuvre’ in expression and enactment of diverse ideas of nature and its management resides primarily in informal spaces, facilitated by recent trends of devolution in natural resource management. Finally, the paper demonstrates how nomadism has been constructed and reconstructed as a component of, rather than inimical to, modernity, albeit with as yet unproven implications for livelihoods and for nature in rural Mongolia.  相似文献   

Surface complexation of Cu on birnessite (δ-MnO₂): Controls on Cu in the deep ocean     

David M. Sherman  Caroline L. Peacock 《Geochimica et cosmochimica acta》2010,74(23):6721-6730

Hexagonal birnessite (δ-MnO₂) is a close analogue to the dominant phase in hydrogenetic marine ferromanganese crusts and nodules. These deposits contain ∼0.25 wt.% Cu which is believed to be scavenged from the overlying water column where Cu concentrations are near 0.1 μg/L. Here, we measured the sorption of Cu on δ-MnO₂ as a function of pH and surface loading. We characterized the nature of the Cu sorption complex at pH 4 and 8 using EXAFS spectroscopy and find that, at pH 4, Cu sorbs to birnessite by inner-sphere complexation on the {0 0 1} surface at sites above Mn vacancies to give a three to fourfold coordinated complex with 6 Mn neighbors at ∼3.4 Å. At pH 8, however, we find that some Cu has become structurally incorporated into the MnO₂ layer by occupying the vacancy sites to give 6 Mn neighbors at ∼2.91 Å. Density functional calculations on and clusters predict a threefold coordinated surface complex and show that the change from surface complexation to structural incorporation is a response to protonation of oxygens surrounding the vacancy site. Consequently, we propose that the transformation between sorption via surface complex and vacancy site occupancy should be reversible. By fitting the Cu sorption as a function of surface loading and pH to the formation of the observed and predicted surface complex, we developed a surface complexation model (in the basic Stern approximation) for the sorption of Cu onto birnessite. Using this model, we demonstrate that the concentration of inorganic Cu in the deep ocean should be several orders of magnitude lower than the observed total dissolved Cu. We propose that the observed total dissolved Cu concentration in the oceans reflects solubilization of Cu by microbially generated ligands.  相似文献   

A global approach to reactive transport: application to the MoMas benchmark     

Caroline de Dieuleveult  Jocelyne Erhel 《Computational Geosciences》2010,14(3):451-464

Water resource management involves numerical simulations in order to study contamination of groundwater by chemical species. Not only do the aqueous components move due to physical advection and dispersion processes, but they also react together and with fixed components. Therefore, the mass balance couples transport and chemistry, and reactive transport models are partial differential equations coupled with nonlinear algebraic equations. In this paper, we present a global method based on the method of lines and differential algebraic system (DAE) solvers. At each time step, nonlinear systems are solved by a Newton-LU method. We use this method to carry out numerical simulations for the reactive transport benchmark proposed by the MoMas research group. Although we study only 1D computations with a specific geochemical system, several difficulties arise. Numerical experiments show that our method can solve quite difficult problems, get accurate results and capture sharp fronts.  相似文献