An Investigation on Erodibility and Geotechnical Characteristics of Fine Grained Fluvial Soils from Lower Michigan     

Matthew A. McClerren  Hiroshan Hettiarachchi  Donald D. Carpenter 《Geotechnical and Geological Engineering》2012,30(4):881-892

Scour and erosion potential of a soil are closely related to each other. Similarities or differences between them have not been defined fully and the terms are often used interchangeably or in association with one another. Erodibility is a property of soil that describes erosion potential. Therefore, a proper understanding of erodibility should help predict scour more accurately. In the past, researchers have looked into erosion of soils with the ultimate objective of understanding the erodibility with respect to the standard geotechnical properties. Most research has shown the difficulties associated with correlating erodibility to any one or more soil properties. The research described in this paper is mainly focused on the relationship between erodibility and dry unit weight of soil with varying fractions of fines. Soils tested using laboratory Jet Erosion Test (JET) indicated that the logarithm of erodibility makes a linear inverse relationship with the dry unit weight. In situ JETs confirmed the range of erodibilities established by the laboratory JETs. The best correlations between erodibility and dry unit weight appeared within a single category of soil as classified by the Unified Soil Classification System. In addition, it was also determined that the logarithm of erodibility is inversely related to the angle of internal friction of the fluvial soils tested during this investigation.  相似文献   

Spectra of radioactivity induced in caesium iodide scintillator crystals by 155 MeV protons     

G. Carpenter  C. S. Dyer 《Astrophysics and Space Science》1973,24(1):95-104

Previous work has shown the importance of induced radioactivity as a source of background counts in X- and -ray astronomy experiments which use scintillation detectors. Comprehensive data on the decay spectra observed in Caesium Iodide crystals following irradiation by 155 MeV protons has been obtained by the Imperial College group and is presented here. The spectra cover the energy loss range from 20 keV to 3.4 MeV and were collected at times after irradiation ranging from 1 min until 200 d. A sufficient selection of spectra is given to enable calculations to be made of the time variations in radioactivity which would be observed in similar space-borne detectors subjected to irradiation by inner belt and cosmic ray protons. Examples of such calculations are given.  相似文献   

Spatial and temporal mapping of water in soil by magnetic resonance imaging     

M. H. G. Amin  R. J. Chorley  K. S. Richards  B. W. Bache  L. D. Hall  T. A. Carpenter 《水文研究》1993,7(3):279-286

Experiments on model and real soil blocks designed to assess the feasibility of using magnetic resonance imaging for three-dimensional mapping of the time-varying spatial distribution of water in structured soils are reported. The results show that, notwithstanding inherent problems in imaging natural soils with a significant iron content, experimental parameters can be identified which allow satisfactory images to be obtained. Magnetic resonance imaging may therefore provide important information on soil structure and water movement in dual porosity soils, with attendant benefits for the calibration of models of non-Darcian flow in such soils.  相似文献   

Coincident sediment slump/clathrate complexes on the U.S. Atlantic continental slope   总被引：1，自引：0，他引：1  

George Carpenter 《Geo-Marine Letters》1981,1(1):29-32

High-resolution seismic reflection data recorded on the continental slope off the east coast of the United States have revealed instances of sediment mass movement (slumps) which appear to occur above clathrate accumulations. The slumping is believed to be related to the liberation of free gas by clathrate decomposition and consequent weakening of unconsolidated sediments above the clathrate. Pleistocene sea-level lowering and/or post-Pleistocene bottom water temperature increases may have had a significant role in this process.  相似文献   

Local structural heterogeneity,mixing behaviour and saturation effects in the grossular–spessartine solid solution     

U.?RodehorstEmail author  M. A.?Carpenter  T. Boffa?Ballaran  C. A.?Geiger 《Physics and Chemistry of Minerals》2004,31(7):387-404

Local structural heterogeneities in crystals of the binary grossular–spessartine solid solution have been analyzed using powder IR absorption spectroscopy. Wavenumber shifts of the highest energy Si–O stretching mode in spectra collected at room temperature are consistent with variations in Si–O bond length from structural data. They show a smaller positive deviation from linearity across the join than is seen for the grossular–pyrope and grossular–almandine binaries. The effective line widths, corr, of three selected wavenumber regions all deviate positively from linear behaviour. An empirical calibration of this excess spectroscopic property, obtained by comparison with calorimetric enthalpy of mixing data, gives an estimate for the symmetric Margules parameter of W^H_spec = 14.4(7) kJ mol^–1 in H^mix = W^H_specX_GrX_Sp. W^H_spec values derived on the same basis for four aluminosilicate garnet solid solutions analyzed by IR spectroscopy vary with V², where V represents the difference in molar volume between the end members of each binary system. Measurements of lattice parameters and IR spectra were made over a range of temperatures for seven samples with different compositions. Positive excess molar volumes of mixing at low temperature (30 K) may be larger than the excess molar volumes at room temperature. The saturation temperatures of the molar volumes show no correlation with composition, however, in contrast with what had been expected on the basis of data for the grossular–pyrope binary. Saturation temperatures for spectroscopic parameters and lattice parameters of samples with compositions Gr15Sp85 and Gr60Sp40 seem to be outliers in all experiments. It is concluded that the data hint at systematic changes in saturation temperatures across the solid solution, with implications for both the excess entropy of mixing and the excess volume of mixing, but more precise data or further sample characterization are needed to prove that this composition dependence is real in garnet solid solutions.  相似文献   

Case Histories of Resistivity and Seismic Ground-Water Studies     

G. C. Carpenter  D. R. Bassarab 《Ground water》1964,2(1):21-25

  相似文献   

Microbial and hydrothermal aspects of ferric oxyhydroxides and ferrosic hydroxides: the example of Franklin Seamount, Western Woodlark Basin, Papua New Guinea   总被引：1，自引：0，他引：1  

TD Boyd  SD Scott 《Geochemical transactions》2001,2(1):45-12

Deposits of Fe-Si-Mn oxyhydroxides are commonly found on the seafloor on seamounts and mid-ocean spreading centers. At Franklin Seamount located near the western extremity of Woodlark Basin, Papua New Guinea, Fe-Si-Mn oxyhydroxides are being precipitated as chimneys and mounds upon a substrate of mafic lava. Previous studies have shown that the vent fluids have a low temperature (20–30°C) and are characterized by a total dissolved iron concentration of 0.038 mM kg^-1, neutral pH (6.26) and no measurable H₂S. The chimneys have a yellowish appearance with mottled red–orange patches when observed in situ from a submersible, but collected samples become redder within a few hours of being removed from the sea. The amorphous iron oxyhydroxides, obtained from active and inactive vents, commonly possess filamentous textures similar in appearance to sheaths and stalks excreted by the iron-oxidizing bacteria Leptothrix and Gallionella; however, formless agglomerates are also common. Textural relationships between apparent bacterial and non-bacterial iron suggest that the filaments are coeval with and/or growing outwards from the agglomerates. The amorphous iron oxyhydroxides are suggested to precipitate hydrothermally as ferrosic hydroxide, a mixed-valence (Fe²⁺-Fe³⁺) green–yellow iron hydroxide compound. Consideration of the thermodynamics and kinetics of iron in the vent fluid, suggest that the precipitation is largely pH controlled and that large amounts of amorphous iron oxyhydroxides are capable of being precipitated by a combination of abiotic hydrothermal processes. Some biologically induced precipitation of primary ferric oxyhydroxides (two-XRD-line ferrihydrite) may have occurred directly from the fluid, but most of the filamentous iron micro-textures in the samples appear to have a diagenetic origin. They may have formed as a result of the interaction between the iron-oxidizing bacteria and the initially precipitated ferrosic hydroxide that provided a source of ferrous iron needed for their growth. The processes described at Franklin Seamount provide insight into the formation of other seafloor oxyhydroxide deposits and ancient oxide-facies iron formation.  相似文献   

Phase transition and mixing behaviour of the cummingtonite–grunerite solid solution     

T. Boffa Ballaran  M. A. Carpenter  M. C. Domeneghetti 《Physics and Chemistry of Minerals》2001,28(2):87-101

 Natural amphiboles with composition close to the binary join cummingtonite–grunerite and crystals of the same samples annealed at 700 °C for 55.5 h, in order to obtain different degrees of non-convergent cation order, have been characterised by means of X-ray single-crystal diffraction and IR spectroscopy. Long-range order parameters describing the non-convergent order of Mg/Fe among the different octahedral sites have been calculated from the site occupancies of the investigated samples. Values of the O6-O5-O6 angles and of the 〈M4-O〉 mean bond distances depend on the C2/m → P2₁/m phase transition for a given degree of order. In the IR spectra, only two phonon lines dominated by the bending of the tetrahedral chains are sensitive to the displacive phase transition and to the different degree of cation order; all the other wavenumber shifts are correlated with compositional changes only. The local strains arising from the cation substitution, ordering and phase transition have been quantified by means of the autocorrelation function. Very small local heterogeneities are associated with the Mg/Fe substitution and disordering in samples at intermediate composition. The displacive phase transition seems to occur in order to reduce local distortions and the P2₁/m samples are as homogeneous as orthorhombic anthophyllites. The orthorhombic structure, however, appears less flexible than the monoclinic in accommodating cations larger than Mg at the octahedral sites. Received: 9 February 2000 / Accepted: 30 September 2000  相似文献   

A nocturnal atmospheric loss of CH<Subscript>2</Subscript>I<Subscript>2</Subscript> in the remote marine boundary layer     

Lucy J. Carpenter  Stephen J. Andrews  Richard T. Lidster  Alfonso Saiz-Lopez  Miguel Fernandez-Sanchez  William J. Bloss  Bin Ouyang  Roderic L. Jones 《Journal of Atmospheric Chemistry》2017,74(2):145-156

Ocean emissions of inorganic and organic iodine compounds drive the biogeochemical cycle of iodine and produce reactive ozone-destroying iodine radicals that influence the oxidizing capacity of the atmosphere. Di-iodomethane (CH₂I₂) and chloro-iodomethane (CH₂ICl) are the two most important organic iodine precursors in the marine boundary layer. Ship-borne measurements made during the TORERO (Tropical Ocean tRoposphere Exchange of Reactive halogens and Oxygenated VOC) field campaign in the east tropical Pacific Ocean in January/February 2012 revealed strong diurnal cycles of CH₂I₂ and CH₂ICl in air and of CH₂I₂ in seawater. Both compounds are known to undergo rapid photolysis during the day, but models assume no night-time atmospheric losses. Surprisingly, the diurnal cycle of CH₂I₂ was lower in amplitude than that of CH₂ICl, despite its faster photolysis rate. We speculate that night-time loss of CH₂I₂ occurs due to reaction with NO₃ radicals. Indirect results from a laboratory study under ambient atmospheric boundary layer conditions indicate a k _CH2I2+NO3 of ≤4 × 10^?13 cm³ molecule^?1 s^?1; a previous kinetic study carried out at ≤100 Torr found k _CH2I2+NO3 of 4 × 10^?13 cm³ molecule^?1 s^?1. Using the 1-dimensional atmospheric THAMO model driven by sea-air fluxes calculated from the seawater and air measurements (averaging 1.8 +/? 0.8 nmol m^?2 d^?1 for CH₂I₂ and 3.7 +/? 0.8 nmol m^?2 d^?1 for CH₂ICl), we show that the model overestimates night-time CH₂I₂ by >60 % but reaches good agreement with the measurements when the CH₂I₂ + NO₃ reaction is included at 2–4 × 10^?13 cm³ molecule^?1 s^?1. We conclude that the reaction has a significant effect on CH₂I₂ and helps reconcile observed and modeled concentrations. We recommend further direct measurements of this reaction under atmospheric conditions, including of product branching ratios.  相似文献   

Biogeochemical processes affecting total arsenic and arsenic species distributions in an intermittently anoxic fjord     

M. L. Peterson  R. Carpenter 《Marine Chemistry》1983,12(4)

Total arsenic, arsenate and arsenite concentration profiles for the water column of Saanich Inlet, an intermittently anoxic fjord located on Vancouver Island, B.C., Canada, were measured using independent analytical techniques for total arsenic and arsenic speciation to evaluate the accuracy of the speciation technique in both oxic and anoxic marine environments. Total arsenic profiles indicate a mid-depth minimum of about 1.0 ppb above the oxic—anoxic interface and an enrichment in the anoxic zone to about 2.0 ppb. This minimum may be due to either advection of arsenic-poor water into Saanich Inlet at mid-depth or arsenic incorporation onto solid phases within a bacteria- and manganese-rich particulate layer located immediately above the oxic—anoxic interface and subsequent removal via sinking particulate material. Ratios of total arsenic to phosphorus in the deep, anoxic waters of the basin are similar to those reported for marine algae, suggesting that the enrichment of total arsenic within the anoxic bottom layer may be due to its release upon organic matter decomposition.Arsenate and arsenite concentration versus depth profiles indicate a rapid (but incomplete in a thermodynamic sense) response to the oxic—anoxic interface. The arsenate/ arsenite concentration ratio is 15/1 in the oxic region of the water column and 1/12 in the anoxic zone. Arsenate—arsenite interconversion occurs at a depth shallower than ferric-ferrous but deeper than MnO₂ —Mn²⁺ interconversions.Measurements of arsenite oxidation rates at near-ambient arsenite concentrations and temperatures using an ⁷⁴As³⁺ radioactive tracer technique indicate that arsenite oxidation is initially ten times faster in seawater taken from the manganese-rich particulate layer at 165 m depth than in seawater collected near the surface at 50 m depth. Addition of antibiotics to seawater from 165 m depth initially suppressed the rate of arsenite oxidation, indicating that it may be partially microbially mediated.  相似文献