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131.
Carsten Montzka Morton Canty Ralf Kunkel Gunter Menz Harry Vereecken Frank Wendland 《Journal of Hydrology》2008,353(3-4):322-334
Hydrological modelling of mesoscale catchments is often adversely affected by a lack of adequate information about specific site conditions. In particular, digital land cover data are available from data sets which were acquired on a European or a national scale. These data sets do not only exhibit a restricted spatial resolution but also a differentiation of crops and impervious areas which is not appropriate to the needs of mesoscale hydrological models. In this paper, the impact of remote sensing data on the reliability of a water balance model is investigated and compared to model results determined on the basis of CORINE (Coordination of Information on the Environment) Land Cover as a reference. The aim is to quantify the improved model performance achieved by an enhanced land cover representation and corresponding model modifications. Making use of medium resolution satellite imagery from SPOT, LANDSAT ETM+ and ASTER, detailed information on land cover, especially agricultural crops and impervious surfaces, was extracted over a 5-year period (2000–2004). Crop-specific evapotranspiration coefficients were derived by using remote sensing data to replace grass reference evapotranspiration necessitated by the use of CORINE land cover for rural areas. For regions classified as settlement or industrial areas, degrees of imperviousness were derived. The data were incorporated into the hydrological model GROWA (large-scale water balance model), which uses an empirical approach combining distributed meteorological data with distributed site parameters to calculate the annual runoff components. Using satellite imagery in combination with runoff data from gauging stations for the years 2000–2004, the actual evapotranspiration calculation in GROWA was methodologically extended by including empirical crop coefficients for actual evapotranspiration calculations. While GROWA originally treated agricultural areas as homogeneous, now a consideration and differentiation of the main crops is possible. The accuracy was determined by runoff measurements from gauging stations. Differences in water balances resulting from the use of remote sensing data as opposed to CORINE were analysed in this study using a representative subcatchment. Resulting Nash–Sutcliff model efficiencies improved from 0.372 to 0.775 and indicate that the enhanced model can produce thematically more accurate and spatially more detailed local water balances. However, the proposed model enhancements by satellite imagery have not exhausted the full potential of water balance modelling, for which a higher temporal resolution is required. 相似文献
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134.
Synthesis and Preliminary Characterisation of New Silicate, Phosphate and Titanite Reference Glasses 总被引:3,自引:0,他引:3
Stephan Klemme Stefan Prowatke Carsten Münker Charles W. Magee Yann Lahaye Thomas Zack Simone A. Kasemann E. Joan A. Cabato Benjamin Kaeser 《Geostandards and Geoanalytical Research》2008,32(1):39-54
Eleven synthetic silicate and phosphate glasses were prepared to serve as reference materials for in situ microanalysis of clinopyroxenes, apatite and titanite, and other phosphate and titanite phases. Analytical results using different micro-analytical techniques showed that the glass fragments were homogeneous in major and trace elements down to the micrometre scale. Trace element determinations using inductively coupled plasma-mass spectrometry (ICP-MS), multi-collector inductively coupled plasma-mass spectrometry (MC-ICP-MS), laser-ablation inductively coupled plasma-mass spectrometry (LA-ICP-MS) and secondary ionisation mass spectrometry (SIMS) showed good agreement for most elements (Li, Be, B, Cs, Rb, Ba, Sr, Ga, Pb, U, Th, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Er, Tm, Yb, Lu, Zr, Hf, Ta, Nb) studied and provide provisional recommended values. 相似文献
135.
Carsten Meyer-Jacob Hendrik Vogel Florian Boxberg Peter Rosén Michael E. Weber Richard Bindler 《Journal of Paleolimnology》2014,52(3):245-255
We present an independent calibration model for the determination of biogenic silica (BSi) in sediments, developed from analysis of synthetic sediment mixtures and application of Fourier transform infrared spectroscopy (FTIRS) and partial least squares regression (PLSR) modeling. In contrast to current FTIRS applications for quantifying BSi, this new calibration is independent from conventional wet-chemical techniques and their associated measurement uncertainties. This approach also removes the need for developing internal calibrations between the two methods for individual sediments records. For the independent calibration, we produced six series of different synthetic sediment mixtures using two purified diatom extracts, with one extract mixed with quartz sand, calcite, 60/40 quartz/calcite and two different natural sediments, and a second extract mixed with one of the natural sediments. A total of 306 samples—51 samples per series—yielded BSi contents ranging from 0 to 100 %. The resulting PLSR calibration model between the FTIR spectral information and the defined BSi concentration of the synthetic sediment mixtures exhibits a strong cross-validated correlation ( \( {\text{R}}^{ 2}_{\text{cv}} \) = 0.97) and a low root-mean square error of cross-validation (RMSECV = 4.7 %). Application of the independent calibration to natural lacustrine and marine sediments yields robust BSi reconstructions. At present, the synthetic mixtures do not include the variation in organic matter that occurs in natural samples, which may explain the somewhat lower prediction accuracy of the calibration model for organic-rich samples. 相似文献
136.
An assessment is made of the modes of interannual variability in the seasonal mean summer and winter Southern Hemisphere 500 hPa geopotential height in the twentieth century in models from the Coupled Model Intercomparison Project phase 3 (CMIP3) dataset. The analysis is done for both the intraseasonal and slow components of the geopotential height. When the CMIP3 models are assessed against reanalysis data, the spatial structure and variance of the leading modes in the intraseasonal component are generally well reproduced. There are systematic differences between the models in their reproduction of the leading modes in the slow component. An overall score using the leading modes in the slow component allows a categorisation of CMIP3 model performance. Using an ensemble from four models that suitably reproduce the twentieth century modes, modes of variability in the slow-internal and slow-external components are estimated. The leading mode of the slow-external component is shown to be related to observed changes in greenhouse gas concentrations. In this ensemble, there is little change in the leading modes in the intraseasonal component in the twenty-first century. Larger changes in variance, and subtle changes in regional-scale structure, are found for the leading modes in the slow-internal component. These are related to changes in the slowly varying dynamics of the Southern Annular Mode and the El Niño-Southern Oscillation. By far the biggest change is in the leading mode of the slow-external component. The spatial structure becomes uniform in the twenty-first century, and the variance increases with increasing greenhouse gas concentrations. 相似文献
137.
Sascha?SandmannEmail author Thorsten?J.?Nagel Daniel?Herwartz Raúl?O.?C.?Fonseca Robert?M.?Kurzawski Carsten?Münker Nikolaus?Froitzheim 《Contributions to Mineralogy and Petrology》2014,168(5):1075
The Adula Nappe in the Central Alps is a mixture of various pre-Mesozoic continental basement rocks, metabasics, ultrabasics, and Mesozoic cover rocks, which were pervasively deformed during Alpine orogeny. Metabasics, ultrabasics, and locally garnet–mica schists preserve eclogite-facies assemblages while the bulk of the nappe lacks such evidence. We provide garnet major-element data, Lu profiles, and Lu–Hf garnet geochronology from eclogites sampled along a north–south traverse. A southward increasing Alpine overprint over pre-Alpine garnets is observed throughout the nappe. Garnets in a sample from the northern Adula Nappe display a single growth cycle and yield a Variscan age of 323.8 ± 6.9 Ma. In contrast, a sample from Alpe Arami in the southernmost part contains unzoned garnets that fully equilibrated to Alpine high-pressure (HP) metamorphic conditions with temperatures exceeding 800 °C. We suggest that the respective Eocene Lu–Hf age of 34.1 ± 2.8 Ma is affected by partial re-equilibration after the Alpine pressure peak. A third sample from the central part of the nappe contains separable Alpine and Variscan garnet populations. The Alpine population yields a maximum age of 38.8 ± 4.3 Ma in line with a previously published garnet maximum age from the central nappe of 37.1 ± 0.9 Ma. The Adula Nappe represents a coherent basement unit, which preserves a continuous Alpine high-pressure metamorphic gradient. It was subducted as a whole in a single, short-lived event in the upper Eocene. Controversial HP ages and conditions in the Adula Nappe may result from partly preserved Variscan assemblages in Alpine metamorphic rocks. 相似文献