Geochemical comparison of waters and stream sediments close to abandoned Sb-Au and As-Au mining areas,northern Portugal     

Paula C.S. Carvalho  Ana M.R. Neiva  Maria M.V.G. Silva  Eduardo A. Ferreira da Silva 《Chemie der Erde / Geochemistry》2014

Waters from abandoned Sb-Au mining areas have higher Sb (up to 2138 μg L⁻¹), As (up to 1252 μg L⁻¹) and lower Al, Zn, Li, Ni and Co concentrations than those of waters from the As-Au mining area of Banjas, which only contain up to 64 μg L⁻¹ As. In general, Sb occurs mainly as SbO₃⁻ and As H₂AsO₄⁻. In general, waters from old Sb-Au mining areas are contaminated in Sb, As, Al, Fe, Cd, Mn, Ni and NO₂⁻, whereas those from the abandoned As-Au mining area are contaminated in Al, Fe, Mn, Ni, Cd and rarely in NO₂⁻. Waters from the latter area, immediately downstream of mine dumps are also contaminated in As. In stream sediments from Sb-Au and As-Au mining areas, Sb (up to 5488 mg kg⁻¹) and As (up to 235 mg kg⁻¹) show a similar behaviour and are mainly associated with the residual fraction. In most stream sediments, the As and Sb are not associated with the oxidizable fraction, while Fe is associated with organic matter, indicating that sulphides (mainly arsenopyrite and pyrite) and sulphosalts containing those metalloids and metal are weathered. Arsenic and Sb are mainly associated with clay minerals (chlorite and mica; vermiculite in stream sediments from old Sb-Au mining areas) and probably also with insoluble Sb phases of stream sediments. In the most contaminated stream sediments, metalloids are also associated with Fe phases (hematite and goethite, and also lepidocrocite in stream sediments from Banjas). Moreover, the most contaminated stream sediments correspond to the most contaminated waters, reflecting the limited capacity of stream sediments to retain metals and metalloids.  相似文献   

Carbon isotopes and geochemical processes in CO2-rich cold mineral water,N-Portugal     

P. M. Carreira  J. M. Marques  M. R. Carvalho  D. Nunes  M. Antunes da Silva 《Environmental Earth Sciences》2014,71(6):2941-2953

This paper summarizes a new outlook on the conceptual model of Melgaço–Messegães CO₂-rich cold (≈18 °C) mineral water systems, issuing in N of Portugal, based on their isotopic (²H, ³H, ¹³C, ¹⁴C and ¹⁸O) and geochemical features. Stable isotopes indicate the meteoric origin of these CO₂-rich mineral waters. Based on the isotopic fractionation with the altitude, a recharge altitude between 513 up to 740 m a.s.l. was estimated, corroborating the tritium results. The lowest ³H content (0 TU) is found in the groundwater samples with the highest mineralization. The mineral waters circulation are mainly related to a granitic and granodioritic environment inducing two different groundwater types (Ca/Na–HCO₃ and Na/Ca–HCO₃), indicating different underground flow paths. Calcium dissolution is controlled by hydrolysis of rock-matrix silicate minerals (e.g. Ca-plagioclases) and not associated to anthropogenic sources. The shallow dilute groundwaters exhibit signatures of anthropogenic origins (e.g. NO₃) and higher Na/Ca ratios. The stable isotopes together with the geochemistry provided no indication of mixing between the regional shallow cold dilute groundwater and mineral water systems. The heavy isotopic signatures identified in the δ¹³C data (δ¹³C = 4.7 ‰, performed on the total dissolved inorganic carbon (TDIC) of CO₂-rich mineral waters) could be derived from a deep-seated (upper mantle) source or associated to methanogenesis (CH₄ source). The negligible ¹⁴C content (≈2 pmC) determined in the TDIC of the mineral waters, corroborates the hypothesis of a mantle-derived carbon source to the mineral groundwater systems or dissolution of carbonate layers at depth.  相似文献   

Sea surface temperatures at tide gauges: Case study of San Francisco,California, from 1855 to 1993     

Alexandra Carvalho  George A. Maul 《Marine Geodesy》2013,36(4):317-324

Tide gauge observations usually include temperature and density measurements. As an example of such data, a time series of sea surface temperature (SST) from 1855 to 1877 and from 1921 to 1993 at Fort Point, San Francisco, California (the longest U.S. record), and mean air temperature at Mission Dolores (San Francisco), California, from 1936 to 1990, were analyzed. Annual mean Fort Point SST increased at a rate of 0.3°C per century, but the coefficient of determination (r²) was below 0.06; for air temperature the results were 1.6°C per century and r² = 0.16 respectively. Evidence of El Niño were found in the periodogram of the mean annual SST but not in the air temperature. The annual and semiannual peaks in the monthly time‐series analysis of SST and air temperature dominate their periodograms, and the cross‐correlation between them has r² = 0.47. Of the 1.3 mmlyr sea level rise over the same time period. 0.003°C/yr accounts for 0.04 mmlyr in thermal expansion if the upper 100 m of the water column were uniformly warmed.  相似文献   

Current constraints on the epoch of cosmic acceleration     

B. SantosJ.C. Carvalho  J.S. Alcaniz 《Astroparticle Physics》2011,35(1):17-20

The cosmographic expansion history of the universe is investigated by using the 557 type Ia supernovae from the Union2 Compilation set along with the current estimates involving the product of the CMB acoustic scale ?_A and the BAO peak at two different redshifts. Using a well-behaved parameterization for the deceleration parameter, q(z) = q₀ + q₁z/(1 + z), we estimate the accelerating redshift z_acc = −q₀/(q₀ + q₁) (at which the universe switches from deceleration to acceleration) and investigate the influence of a non-vanishing spatial curvature on these estimates. We also use the asymptotic value of q(z) at high-z to place more restrictive bounds on the model parameters q₀ and q₁, which results in a more precise determination of the epoch of cosmic acceleration.  相似文献   

Sulfur stable isotopes indicate the source of sinking materials in a coastal bay: Otsuchi Bay,Sanriku, Japan     

Matheus Carvalho de Carvalho  Ken-ichi Hayashizaki  Hisao Ogawa 《Journal of Oceanography》2008,64(5):705-712

Through 2004 and 2005, δ ³⁴S of sinking material from Otsuchi Bay was measured at the center and rocky shore of the bay. At the center of the bay δ ³⁴S was high (18∼21‰) in the material collected from April to November. However, δ ³⁴S was low (9∼14‰) in the material collected from December to March. The increase in δ ³⁴S in April was attributed to an increase in phytoplankton biomass because marine phytoplanktonic δ ³⁴S is high. When δ ³⁴S of sinking material was low, input of riverine material or bottom sediment resuspension were considered as the probable causes, because their δ ³⁴S is low. Marine sulfur was always high (more than 70%) at both stations. The difference between the δ ³⁴S of sinking material collected from the different sampling stations indicates that marine macroalgae contribute to sinking material near the shore when phytoplankton is scarce. In conclusion, the relative influence of different material sources to sinking materials could be successfully estimated using δ ³⁴S.  相似文献