Biodegradation and environmental behavior of biodiesel mixtures in the sea: An initial study     

DeMello JA  Carmichael CA  Peacock EE  Nelson RK  Samuel Arey J  Reddy CM 《Marine pollution bulletin》2007,54(7):894-904

Biodiesel, a mixture of fatty acid methyl esters (FAMEs) derived from animal fats or vegetable oils, is rapidly moving towards the mainstream as an alternative source of energy. However, the behavior of biodiesel, or blends of biodiesel with fossil diesel, in the marine environment have yet to be fully understood. Hence, we performed a series of initial laboratory experiments and simple calculations to evaluate the microbial and environmental fate of FAMEs. Aerobic seawater microcosms spiked with biodiesel or mixtures of biodiesel and fossil diesel revealed that the FAMEs were degraded at roughly the same rate as n-alkanes, and more rapidly than other hydrocarbon components. The residues extracted from these different microcosms became indistinguishable within weeks. Preliminary results from physical-chemical calculations suggest that FAMEs in biodiesel mixtures will not affect the evaporation rates of spilled petroleum hydrocarbons but may stabilize oil droplets in the water column and thereby facilitate transport.  相似文献   

Assessing the response of watersheds to catastrophic (logging) and possible secular (global temperature change) perturbations using sediment-chemical chronologies     

David T. Long  Matthew J. Parsons  Catherine H. Yansa  Sharon S. Yohn  Colleen E. McLean  Ryan G. Vannier 《Applied Geochemistry》2010

Geochemical profiles of sediment cores from two oligotrophic lakes (Elk and Mullett) in northern Lower Michigan were studied to examine the response and recovery of watersheds to large-scale logging that occurred between 1850 and 1920. Specific questions addressed were: can the impact of extensive clear-cutting of forests be recognized in the sediment-chemical chronologies, can states of system stability be identified prior to the logging, and are there indications that the systems are recovering and possibly returning to a stable state? To answer these questions, elements were put into four groups as proxies for watershed runoff or export (e.g., Al, Mg), pollution (e.g., Pb, Cu), redox (e.g., Fe, As), and productivity (e.g., Ca, P). It was observed that vertical patterns of all proxies were influenced by logging and the early increases in concentration of pollution proxies were due to increased watershed export, not pollution. System stability might be recognized by relatively symmetrical vertical patterns among all of the proxies or secular changes of slowly increasing or decreasing vertical concentration trajectories. Some pre-logging trajectories were punctuated by episodes of slightly elevated concentrations that appear to be related to comparatively warmer periods during the Little Ice Age. Iron and Mn enrichments caused by increased watershed runoff might be misinterpreted as paleo-redox horizons. Results are interpreted to indicate that (1) reference conditions may be better defined as the temporal trends among proxy groups and not individual concentrations, (2) simply assuming pre-1800 conditions as a reference may not be appropriate, (3) inter-proxy group comparisons are needed to help for interpretations of intra-proxy group patterns, (4) the possible regime shift identified here might be expected for other ecosystems because of the intensity of human disturbances and secular changes, and (5) without consideration of a possible regime shift, recovery from logging is estimated to be on the order of 75–130 a, but shorter if regime shifts are considered.  相似文献   

Deep reflection seismic imaging of the internal zone of the South Armorican Hercynian belt (western France) (ARMOR 2/Géofrance 3D Program)     

Adnand Bitri  Jean-Pierre Brun  Denis Gapais  Florence Cagnard  Charles Gumiaux  Jean Chantraine  Guillaume Martelet  Catherine Truffert 《Comptes Rendus Geoscience》2010,342(6):448-452

We present results and interpretation of a 72 km long deep seismic reflection profile acquired across the internal zone of the Hercynian belt of South Brittany. The profile is of excellent quality, most of the crust being highly reflective. The “ARMOR 2 South” profile, is correlated with the “ARMOR 2 North” profile that was published in 2003. Correlation of the main subsurface reflections with surface geological and structural data provides important information about the crustal structure that resulted from thickening during Late Devonian and regional-scale extension during Late Carboniferous. In particular, seismics image shows a very high reflectivity zone, lying flat over more than 40 km at about 10–12 km depth. This zone is interpreted as a major zone of ductile crustal thinning.  相似文献   

Authigenic carbonates related to active seepage of methane-rich hot brines at the Cheops mud volcano,Menes caldera (Nile deep-sea fan,eastern Mediterranean Sea)   总被引：1，自引：0，他引：1  

Catherine Pierre  Germain Bayon  Marie-Madeleine Blanc-Valleron  Jean Mascle  Stéphanie Dupré 《Geo-Marine Letters》2014,34(2-3):253-267

On the passive margin of the Nile deep-sea fan, the active Cheops mud volcano (MV; ca. 1,500 m diameter, ~20–30 m above seafloor, 3,010–3,020 m water depth) comprises a crater lake with hot (up to ca. 42 °C) methane-rich muddy brines in places overflowing down the MV flanks. During the Medeco2 cruise in fall 2007, ROV dives enabled detailed sampling of the brine fluid, bottom lake sediments at ca. 450 m lake depth, sub-surface sediments from the MV flanks, and carbonate crusts at the MV foot. Based on mineralogical, elemental and stable isotope analyses, this study aims at exploring the origin of the brine fluid and the key biogeochemical processes controlling the formation of these deep-sea authigenic carbonates. In addition to their patchy occurrence in crusts outcropping at the seafloor, authigenic carbonates occur as small concretions disseminated within sub-seafloor sediments, as well as in the bottom sediments and muddy brine of the crater lake. Aragonite and Mg-calcite dominate in the carbonate crusts and in sub-seafloor concretions at the MV foot, whereas Mg-calcite, dolomite and ankerite dominate in the muddy brine lake and in sub-seafloor concretions near the crater rim. The carbonate crusts and sub-seafloor concretions at the MV foot precipitated in isotopic equilibrium with bottom seawater temperature; their low δ¹³C values (–42.6 to –24.5‰) indicate that anaerobic oxidation of methane was the main driver of carbonate precipitation. By contrast, carbonates from the muddy lake brine, bottom lake concretions and crater rim concretions display much higher δ¹³C (up to –5.2‰) and low δ¹⁸O values (down to –2.8‰); this is consistent with their formation in warm fluids of deep origin characterized by ¹³C-rich CO₂ and, as confirmed by independent evidence, slightly higher heavy rare earth element signatures, the main driver of carbonate precipitation being methanogenesis. Moreover, the benthic activity within the seafloor sediment enhances aerobic oxidation of methane and of sulphide that promotes carbonate dissolution and gypsum precipitation. These findings imply that the coupling of carbon and sulphur microbial reactions represents the major link for the transfer of elements and for carbon isotope fractionation between fluids and authigenic minerals. A new challenge awaiting future studies in cold seep environments is to expand this work to oxidized and reduced sulphur authigenic minerals.  相似文献   

Integration of optical and Synthetic Aperture Radar (SAR) imagery for delivering operational annual crop inventories     

Heather McNairn  Catherine Champagne  Jiali Shang  Delmar Holmstrom  Gordon Reichert 《ISPRS Journal of Photogrammetry and Remote Sensing》2009,64(5):434-449

Agriculture plays a critical role within Canada’s economy and, as such, sustainability of this sector is of high importance. Targeting and monitoring programs designed to promote economic and environmental sustainability are a vital component within Canada’s agricultural policy. A hierarchy of land information, including up to date information on cropping practices, is needed to measure the impacts of programs on land use decision-making and to gauge the environmental and economic benefits of these investments. A multi-year, multi-site research activity was completed to develop a robust methodology to inventory crops across Canada’s large and diverse agricultural landscapes. To move towards operational implementation the methodology must deliver accurate crop inventories, with consistency and reliability. In order to meet these operational requirements and to mitigate risk associated with reliance on a single data source, the methodology integrated both optical and Synthetic Aperture Radar (SAR) imagery. The results clearly demonstrated that multi-temporal satellite data can successfully classify crops for a variety of cropping systems present across Canada. Overall accuracies of at least 85% were achieved, and most major crops were also classified to this level of accuracy. Although multi-temporal optical data would be the preferred data source for crop classification, a SAR-optical dataset (two Envisat ASAR images and one optical image) provided acceptable accuracies and will mitigate risk associated with operational implementation. The preferred dual-polarization mode would be VV–VH. Not only were these promising classification results repeated year after year, but the target accuracies were met consistently for multiple sites across Canada, all with varying cropping systems.  相似文献   

Influence of a hedge surrounding bottomland on seasonal soil‐water movement     

Virginie Caubel  Catherine Grimaldi  Philippe Merot  Michel Grimaldi 《水文研究》2003,17(9):1811-1821

The influence of a hedge surrounding bottomland on soil‐water movement along the hillslope was studied on a plot scale for 28 months. The study was based on the comparison of two transects, one with a hedge, the other without, using mainly a dense grid of tensiometers. The influence of the bottomland hedge was located in the area where tree roots were developed, several metres upslope from the hedge, and could be observed both in the saturated and non‐saturated zone, from May to December. The hedge induced a high rate of soil drying, because of the high evaporative capacity of the trees. We evaluated that water uptake by the hedge during the growing season was at least 100 mm higher than without a hedge. This increased drying rate led to a delayed rewetting of the soils upslope from the hedge in autumn, of about 1 month compared with the situation without a hedge. Several consequences of this delayed rewetting are expected: a delay in the return of subsurface transfer from the hillslope to the riparian zone, a buffering effect of hedges on floods, already observed at the catchment scale, and an increased residence time of pollutants. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

Fe and O isotope composition of meteorite fusion crusts: Possible natural analogues to chondrule formation?          下载免费PDF全文

Dominik C. Hezel  Graeme M. Poole  Jack Hoyes  Barry J. Coles  Catherine Unsworth  Nina Albrecht  Caroline Smith  Mark Rehkämper  Andreas Pack  Matthew Genge  Sara S. Russell 《Meteoritics & planetary science》2015,50(2):229-242

Meteorite fusion crust formation is a brief event in a high‐temperature (2000–12,000 K) and high‐pressure (2–5 MPa) regime. We studied fusion crusts and bulk samples of 10 ordinary chondrite falls and 10 ordinary chondrite finds. The fusion crusts show a typical layering and most contain vesicles. All fusion crusts are enriched in heavy Fe isotopes, with δ⁵⁶Fe values up to +0.35‰ relative to the solar system mean. On average, the δ⁵⁶Fe of fusion crusts from finds is +0.23‰, which is 0.08‰ higher than the average from falls (+0.15‰). Higher δ⁵⁶Fe in fusion crusts of finds correlate with bulk chondrite enrichments in mobile elements such as Ba and Sr. The δ⁵⁶Fe signature of meteorite fusion crusts was produced by two processes (1) evaporation during atmospheric entry and (2) terrestrial weathering. Fusion crusts have either the same or higher δ¹⁸O (0.9–1.5‰) than their host chondrites, and the same is true for Δ¹⁷O. The differences in bulk chondrite and fusion crust oxygen isotope composition are explained by exchange of oxygen between the molten surface of the meteorites with the atmosphere and weathering. Meteorite fusion crust formation is qualitatively similar to conditions of chondrule formation. Therefore, fusion crusts may, at least to some extent, serve as a natural analogue to chondrule formation processes. Meteorite fusion crust and chondrules exhibit a similar extent of Fe isotope fractionation, supporting the idea that the Fe isotope signature of chondrules was established in a high‐pressure environment that prevented large isotope fractionations. The exchange of O between a chondrule melt and an ¹⁶O‐poor nebula as the cause for the observed nonmass dependent O isotope compositions in chondrules is supported by the same process, although to a much lower extent, in meteorite fusion crusts.  相似文献   

The Oxford Principles     

Steve Rayner  Clare Heyward  Tim Kruger  Nick Pidgeon  Catherine Redgwell  Julian Savulescu 《Climatic change》2013,121(3):499-512

Scientific momentum is increasing behind efforts to develop geoengineering options, but it is widely acknowledged that the challenges of geoengineering are as much political and social as they are technical. Legislators are looking for guidance on the governance of geoengineering research and possible deployment. The Oxford Principles are five high-level principles for geoengineering governance. This article explains their intended function and the core societal values which they attempt to capture. Finally, it proposes a framework for their implementation in a flexible governance architecture through the formulation of technology-specific research protocols.  相似文献   

The Shear Testing Programme – I. Weak lensing analysis of simulated ground-based observations     

Catherine Heymans  Ludovic Van Waerbeke  David Bacon  Joel Berge  Gary Bernstein  Emmanuel Bertin  Sarah Bridle  Michael L. Brown  Douglas Clowe  Håkon Dahle  Thomas Erben  Meghan Gray  Marco Hetterscheidt  Henk Hoekstra  Patrick Hudelot  Mike Jarvis  Konrad Kuijken  Vera Margoniner  Richard Massey  Yannick Mellier  Reiko Nakajima  Alexandre Refregier  Jason Rhodes  Tim Schrabback  David Wittman 《Monthly notices of the Royal Astronomical Society》2006,368(3):1323-1339

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Weak gravitational lensing: reducing the contamination by intrinsic alignments     

Catherine Heymans  Alan Heavens 《Monthly notices of the Royal Astronomical Society》2003,339(3):711-720

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