Effect of anorthite on granite phase relations: Experimental data and models   总被引：1，自引：1，他引：0  

Michel Pichavant  Catherine Weber  Arnaud Villaros 《Comptes Rendus Geoscience》2019,351(8):540-550

New experimental data on the effect of anorthite (An) on liquidus phase equilibria in the system Qz–Ab–Or are presented. The data were obtained for 5 wt% An added to variable Qz/Ab/Or compositions at 300 MPa and under H₂O-saturated conditions. Crystal–liquid equilibria were determined for 13 synthetic glass compositions made from gels in experiments performed between 660 and 750 °C in cold-seal pressure vessels. Forward and reversal experiments were systematically conducted on each composition to demonstrate equilibrium. A total of 51 charges was examined. Three crystalline phases, quartz, alkali feldspar and plagioclase appear on the H₂O-saturated liquidus surface. The determined minimum liquidus 5 wt% An “piercing” point (39% Qz, 33% Ab, 28% Or) is shifted away from the Ab apex toward the Qz–Or sideline when compared with the An-free 300 MPa H₂O-saturated minimum. This shift is of the same type as that observed at 100 MPa in the same system and at 200 MPa in a rhyolitic system. The new experimental results are used to test both empirical and thermodynamic models for silicic magmas. Empirical models reproduce reasonably well the new experimental data, although more sophisticated calculations schemes appear to be required to improve their accuracy. The new experimental results in the haplogranodiorite system are not well reproduced with the model of Holland and Powell (2001), mainly because plagioclase stability appears greatly enhanced in the model. Rhyolite-MELTS satisfactorily reproduces the Qz-, Pl- and Af-liquid phase equilibria, but model H₂O solubilities are significantly lower and crystallization temperatures higher than in experiments.  相似文献   

Variability in the annual cycle of vertical particulate organic carbon export on Arctic shelves: Contrasting the Laptev Sea,Northern Baffin Bay and the Beaufort Sea     

Catherine Lalande  Alexandre Forest  David G. Barber  Yves Gratton  Louis Fortier 《Continental Shelf Research》2009

The ongoing regression of sea ice cover is expected to significantly affect the fate of organic carbon over the Arctic continental shelves. Long-term moored sediment traps were deployed in 2005–2006 in the Beaufort Sea, Northern Baffin Bay and the Laptev Sea to compare the annual variability of POC fluxes and to evaluate the factors regulating the annual cycle of carbon export over these continental shelves. Annual POC fluxes at 200 m ranged from 1.6 to 5.9 g C m⁻² yr⁻¹ with the highest export in Northern Baffin Bay and the lowest export over the Mackenzie Shelf in the Beaufort Sea. Each annual cycle exhibited an increase in POC export a few weeks before, during, or immediately following sea ice melt, but showed different patterns over the remainder of the cycle. Enhanced primary production, discharge of the Lena River, and resuspension events contributed to periods of elevated POC export over the Laptev Sea slope. High POC fluxes in Northern Baffin Bay reflected periods of elevated primary production in the North Water polynya. In the Beaufort Sea sediment resuspension contributed to most of the large export events. Our results suggest that the outer shelf of the Laptev Sea will likely sustain the largest increase in POC export in the next few years due to the large reduction in ice cover and the possible increase in the Lena River discharge. The large differences in forcing among the regions investigated reinforce the importance of monitoring POC fluxes in the different oceanographic regimes that characterize the Arctic shelves to assess the response of the Arctic Ocean carbon cycle to interannual variability and climate change.  相似文献   

Large and growing environmental reservoirs of Deca-BDE present an emerging health risk for fish and marine mammals   总被引：2，自引：0，他引：2  

Ross PS  Couillard CM  Ikonomou MG  Johannessen SC  Lebeuf M  Macdonald RW  Tomy GT 《Marine pollution bulletin》2009,58(1):7-10

Polybrominated diphenyl ethers (PBDEs) have been the subject of intense scientific and regulatory scrutiny during recent years. Of the three commercial forms (Penta, Octa and Deca) of PBDEs that have been widely used as flame retardants in textiles, furniture upholstery, plastics, and electronics, only Deca-BDE remains on the general market in North America, while a recent ruling of the European Court spells an impending end to its use in Europe. We review here highlights of aquatic research documenting the rapid emergence of PBDEs as a high priority environmental concern in Canada. PBDEs are being introduced in large quantities to the aquatic environment through sewage discharge and atmospheric deposition. In certain environmental compartments, the single congener BDE-209, the main ingredient in the Deca-BDE formulation, has surpassed the legacy PCBs and DDT as the top contaminant by concentration. Limited biomagnification of BDE-209 in aquatic food webs reflects its high log K_ow and preferential partitioning into the particle phase. As a result, large environmental reservoirs of BDE-209 are being created in sediments, and these may present a long-term threat to biota: BDE-209 breaks down into more persistent, more bioaccumulative, more toxic, and more mobile PBDE congeners in the environment.  相似文献   

Diel cycles of hydrogen peroxide in marine bathing waters in Southern California, USA: In situ surf zone measurements     

Catherine D. Clark  Warren J. De Bruyn  Charlotte M. Hirsch  Paige Aiona 《Marine pollution bulletin》2010,60(12):2284-2288

Hydrogen peroxide is photochemically produced in natural waters. It has been implicated in the oxidative-induced mortality of fecal indicator bacteria (FIB), a microbial water quality measure. To assess levels and cycling of peroxide in beach waters monitored for FIB, diel studies were carried out in surf zone waters in July 2009 at Crystal Cove State Beach, Southern California, USA. Maximum concentrations of 160–200 nM were obtained within 1 h of solar noon. Levels dropped at night to 20–40 nM, consistent with photochemical production from sunlight. Day-time production and night-time dark loss rates averaged 16 ± 3 nM h⁻¹ and 12 ± 4 nM h⁻¹ respectively. Apparent quantum yields averaged 0.07 ± 0.02. Production was largely dominated by sunlight, with some dependence on chromophoric dissolved organic matter (CDOM) levels in waters with high absorption coefficients. Peroxide levels measured here are sufficient to cause oxidative-stress-induced mortality of bacteria, affect FIB diel cycling and impact microbial water quality in marine bathing waters.  相似文献   

Yam Cultivation on the East Coast of New Caledonia: adaptation of agriculture to social and economic changes     

Catherine Gaillard  Harley I. Manner 《The Australian geographer》2010,41(4):485-505

Agriculture represents less than 2 per cent of the GDP of New Caledonia where the economy (and wage-earning activities) is dominated by the service sector and the nickel industry. However, family farming remains strong, especially for the Indigenous Melanesian tribes of the east coast of New Caledonia. Yams (Dioscorea spp.) are still one of the pillars of traditional Kanak society despite the social and economic changes that followed colonisation by France. This study of Kanak yam cultivation on the north-eastern coast of New Caledonia underscores the fact that yam cultivation systems have greatly changed since the 1950s, when they were last described. In addition to customary gift exchanges and subsistence consumption, yams are increasingly being grown for market sales. Five cropping systems, three yam production systems, and three Kanak social activity systems are described and their linkages to each other are explained. There are three levels of Kanak market participation: none, transitional, and fully engaged, and the extent of market participation and associated technical choices defines farmers’ levels of cultural activity and the nature and characteristics of yam cultivation.  相似文献   

Stabilization of Fe/Cu nanoparticles by starch and efficiency of arsenic adsorption from aqueous solutions     

Yassaman Babaee  Catherine N. Mulligan  Md. Saifur Rahaman 《Environmental Earth Sciences》2017,76(19):650

Due to the severity of arsenic contamination of soil and water resources around the world, finding new adsorbents for arsenic removal from the water is of high importance. The present study investigates the possible use and effectiveness of starch-stabilized Fe/Cu nanoparticles for adsorption of arsenic from aqueous solutions. First, Fe/Cu nanoparticles at various starch concentrations of 0, 0.02, 0.04 and 0.06 wt% were synthesized and characterized by X-ray diffraction, transmission electron microscopy and zeta potential/particle size analyzer. Then 0.04 wt% stabilized Fe/Cu nanoparticles were tested for the sorption of As(III) and As(V) from synthetic arsenic-contaminated water. To have an understanding about the arsenic adsorption mechanism of nanoparticles, X-ray photoelectron spectroscopy (XPS) was performed before and after adsorption. The results showed that starch provides nanoparticles with a neutral surface and stabilization of nanoparticles is possible with 0.04 wt% or higher concentrations of starch. For 0.04 wt% starch-stabilized Fe/Cu nanoparticles, the adsorption isotherms fit well within the Langmuir equation, with maximum sorption capacities of 90.1 mg/g for As(III) and 126.58 mg/g for As(V) at a pH of 7.0 from the aqueous arsenic solutions. Examining the XPS spectra of nanoparticles before and after adsorption showed that arsenic adsorption by this nanoparticle can be due to the formation of inner-sphere arsenic complexes on the particle surface, and the surface oxygen-containing functional groups involved in adsorption. The high sorption capacity suggests the potential for applying starch-stabilized Fe/Cu nanoparticles to the contaminated waters for removal of arsenic.  相似文献   

Observations of Centaur 8405 Asbolus: Searching for Water Ice     

Jennifer Romon-MartinMaria A. Barucci  Catherine de BerghAlain Doressoundiram  Nuno Peixinho  François Poulet 《Icarus》2002,160(1):59-65

Near-infrared spectra of Centaur 8405 Asbolus have been obtained, covering the whole rotational period. Complementary photometry and visible spectroscopy have also been performed. The aim of this project was to confirm or refute the water ice detection on one side of Asbolus reported by Kern et al. (2000 Astrophys. J.542, L155-L159). We found no absorption feature at any rotational phase of Asbolus. Our study is the first in-depth investigation of a centaur over a complete rotational period. Our results seem also to indicate that a change in the slope from 0.8 to 1.0 μm may occur in Asbolus spectrum.  相似文献   

The magnesiowüstite: iron equilibrium and its implications for the activity-composition relations of (Mg,Fe)<Subscript>2</Subscript>SiO<Subscript>4</Subscript> olivine solid solutions     

Hugh?St. C.?O'NeillEmail author  Mark?I.?Pownceby  Catherine?A.?McCammon 《Contributions to Mineralogy and Petrology》2003,146(3):308-325

The chemical potential of oxygen (µO₂) in equilibrium with magnesiowüstite solid solution (Mg, Fe)O and metallic Fe has been determined by gas-mixing experiments at 1,473 K supplemented by solid-cell EMF experiments at lower temperatures. The results give:where IW refers to the Fe-"FeO" equilibrium. The previous work of Srecec et al. (1987) and Wiser and Wood (1991) agree well with this equation, as does that of Hahn and Muan (1962) when their reported compositions are corrected to a new calibration curve for lattice parameter vs. composition. The amount of Fe³⁺ in the magnesiowüstite solid solution in equilibrium with Fe metal was determined by Mössbauer spectroscopy on selected samples. These data were combined with literature data from gravimetric studies and fitted to a semi-empirical equation:These results were then used to reassess the activity-composition relations in (Mg, Fe)₂SiO₄ olivine solid solutions at 1,400 K, from the partitioning of Mg and Fe²⁺ between olivine and magnesiowüstite in equilibrium with metallic Fe experimentally determined by Wiser and Wood (1991). The olivine solid solution is constrained to be nearly symmetric with , with a probable uncertainty of less than ±0.5 kJ/mol (one standard deviation). The results also provide a useful constraint on the free energy of formation of Mg₂SiO₄.Editorial responsibility: B. Collins  相似文献   

The porosity and permeability of chondritic meteorites and interplanetary dust particles     

Catherine M. CORRIGAN  Michael E. ZOLENSKY  Jason DAHL  Michael LONG  Joseph WEIR  Clyde SAPP  Patti Jo BURKETT 《Meteoritics & planetary science》1997,32(4):509-515

Abstract— We have investigated the porosity of a large number of chondritic interplanetary dust particles (IDPs) and meteorites by three techniques: standard liquid/gas flow techniques, a new, noninvasive ultrasonic technique, and image processing of backscattered images. The latter technique is obviously best-suited to sub-kilogram sized samples. We have also measured the gas and liquid permeabilities of some chondrites by two techniques: standard liquid/gas flow techniques, and a new, nondestructive pressure release technique. We find that chondritic IDPs have a somewhat bimodal porosity distribution. Peaks are present at 0 and 4% porosity; a tail then extends to 53%. Type 1–3 chondrite matrix porosities range up to 30%, with a peak at 2%. The bulk porosities for type 1–3 chondrites have the same approximate range as exhibited by the matrix, which indicates that other components of the bulk meteorites (including chondrules and aggregates) have the same average porosity as the matrix. These results reveal that the porosities of primitive materials at scales ranging from nanogram to kilogram are similar, which implies that similar accretion dynamics operated through 12 orders of size magnitude. Permeabilities of the investigated chondrites vary by several orders of magnitude, and there appears to be no simple dependence of permeability with degree of aqueous alteration, chondrite type or porosity.  相似文献   

Observation of sections of oceanic crust and mantle cropping out on the southern wall of Kane FZ (N. Atlantic)     

Jean-Marie Auzende  Mathilde Cannat  Pascal Gente  Jean-Pierre Henriet  Thierry Juteau  Jeffrey Karson  Yves Lagabrielle  Catherine Mével  Maurice Tivey 《地学学报》1994,6(2):143-148

The objective of the 20 Nautile dives of the recent Kanaut cruise was to study the southern wall of the Kane Fracture Zone from its eastern intersection with the Mid-Atlantic Ridge (MAR) to 5 Myr in age. The geological mapping shows four successive massifs, wrench faulted and slightly tilted. The transform-facing walls of these massifs exhibit outcrops of fresh and serpentinized peridotites, gabbros and basalts. The entire crustal exposure is cataclased and metamorphosed to greenschist facies.  相似文献