Thermal Convection in Finite Prandtl Number Fluids at High Rayleigh Number     

Catherine A. Hier  Stephen Y. Bergeron  David A. Yuen  Erik O. Sevre  John M. Boggs 《Visual Geosciences》2001,6(3):1-4

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Metasomatic hydrous fluids in amphibole peridotites from Zabargad Island (Red Sea)     

Pierre Agrinier  Catherine Mvel  Delphine Bosch  Marc Javoy 《Earth and Planetary Science Letters》1993,120(3-4):187-205

Combining textural, petrological, chemical and isotopic (Sr, H and O) data for amphiboles and whole rocks from the Zabargad peridotite diapir allows three different events to be distinguished. During each event, which can be related to a specific tectonic process of the rifting of the Red Sea, hydrous fluids produced amphiboles.

The first and the second generations of amphiboles have characteristics consistent with the involvement of mantle-derived hydrous fluids. The first generation consists of scarce Ti-pargasites which crystallized from small amounts of fluid at temperatures of around 900–1000°C. Their growth was linked to magma percolation in the peridotites before their deformation during diapiric uplift. The second generation consists of Cr-pargasites which crystallized locally (and abundantly) during reaction between the peridotites and a sodium/potassium-bearing hydrous fluid at temperatures of around 700–800°C. These amphiboles grew synchronously with the diapiric uplift. The hydrous fluids probably originated in the sub-continental mantle and were released during the diapiric uplift of the peridotites.

The third generation consists of amphiboles (pargasitic hornblende, hornblende sensu lato and tremolite) which are localized in shear zones and veins. They crystallized at temperatures estimated between 700°C and 450°C, again from a sodium/potassium-bearing hydrous fluid. However, this fluid is extraneous to the peridotites, as shown by the Sr, H and O isotope compositions which suggest seawater penetration either during or after the final emplacement of the peridotite diapir.

Although the peridotite diapir was emplaced in granulitic gneisses of the pan-African deep continental crust, no evidence was found for a contribution of hydrous continental fluids in the production of the amphiboles present in the peridotite bodies of Zabargad Island.  相似文献   

Les eaux thermales des granites de Galice (Espagne): des eaux carbogazeuses aux eaux alcalines (Thermal waters from granites of Galicia (Spain): from CO₂-rich to high-pH waters)     

Gil Michard  Catherine Beaucaire 《Chemical Geology》1993,110(4):345-360

Thermal waters from Galicia, Spain, range from CO₂-rich, low-pH to high-pH, sulfide-rich waters, going through intermediate waters. In order to explain the variations of their chemical composition, we present a discussion of the major factors governing the water composition. We eiscuss especially the isochemical recrystallization of a granite. It is shown that the equilibrium mineral association of the water-alkali granite system is unique. For chalco-alkaline granites, two different associations are possible, depending on the chemical composition of the granite. The effect of an addition of CO₂ is also discussed.

Some criteria allowing a distinction between fully equilibrated and non-equilibrated waters are presented.

Finally, the composition of Galician waters is explained by different initial CO₂ contents and by different values of the degree of the granite-water reaction progress (ξ).

Résumé

Les eaux thermales de Galice (Espagne) vont des eaux riches en CO₂ aux eaux typiquement alcalines en passant par différents intermédiaires. Pour comprendre l'évolution de la composition chimique de ces eaux, nous avons été conduits à discuter, de façon plus générale, des facteurs majeurs qui fixent la composition minéralogique résultant d'une recristallisation isochimique du granite. Nous avons pu montrer que les granites alcalins se transformaient toujours en la même association minérale, tandis que les granites calcoalcalins pouvaient donner naissance à deux associations d'équilibre différentes. L'apport de CO₂ au système eau-roche peut faire passer d'une association minérale à l'autre, et, si le CO₂ est en grande quantité, à une association contenant un minéral de moins et du CO₂ en excès. On propose également, pour les solutions géothermales, des critères d'équilibre ou de non équilibre, basés sur la composition en éléments majeurs. La variation de composition des eaux de Galice peut alors s'interpréter par des teneurs variables en CO₂ et des degrés d'avancement différents de la réaction d'interaction eau-granite.  相似文献   

The solubility of fluorite in hydrothermal solutions,an experimental study     

Catherine K. Richardson  H.D. Holland 《Geochimica et cosmochimica acta》1979,43(8):1313-1325

The solubility of fluorite in NaCl solutions increases with increasing temperature at all ionic strengths up to about 100°C. Above this temperature, the solubility passes through a maximum and possibly a minimum with increasing temperature at NaCl concentrations of 1.0M or less, and increases continuously with increasing temperature at NaCl concentrations above 1.0M. At any given temperature, the solubility of fluorite increases with increasing salt concentration in NaCl, KCl and CaCl₂ solutions. The solubility follows Debye-Hückel theory for KCl solutions. In NaCl and CaCl₂ solutions, the solubility of fluorite increases more rapidly than predicted by Debye-Hückel theory: the excess solubility is due to the presence of NaF^c, CaF⁺, and possibly of Na₂F⁺. The solubility of fluorite in NaCl-CaCl₂ and in NaCl-CaCl₂-MgCl₂ solutions is controlled by the common ion effect and by the presence of NaF^c, CaF⁺, and MgF⁺. The solubility of fluorite in NaCl-HCl solutions increases rapidly with increasing initial HCl concentration; the large solubility increase is due to the presence of HF^c. It seems likely that complexes other than those identified in this study rarely play a major role in fluoride transport and fluorite deposition at temperatures below 300°C.  相似文献   

Fluorite deposition in hydrothermal systems   总被引：1，自引：0，他引：1  

Catherine K. Richardson  H.D. Holland 《Geochimica et cosmochimica acta》1979,43(8):1327-1335

During the formation of fluorite deposits fluorite is precipitated either as a consequence of changes in temperature and pressure along the flow path of hydrothermal solutions or due to fluid mixing, or as the result of the interaction of hydrothermal solutions with wall rocks.A decrease in temperature in the flow direction is the most appealing, though still unproven, mechanism of fluorite deposition in Mississippi Valley fluorite deposits.Mixing can produce solutions which are either undersaturated or supersaturated with respect to fluorite. The most important parameters are the temperature, the salinity, and the calcium and fluoride concentration of the fluids prior to mixing.A variety of wall rock reactions can lead to fluorite precipitation. Among these reactions which increase the pH of initially rather acid (pH ≤ 3) hydrothermal solutions are apt to be particularly important.  相似文献   

Mineral-chemistry and stable-isotope constraints on the magmatism, hydrothermal alteration, and related PGE–(base-metal sulphide) mineralisation of the Mesoarchaean Baula-Nuasahi Complex, India     

Thierry Augé  Catherine Lerouge 《Mineralium Deposita》2004,39(5-6):583-607

The Baula-Nuasahi Complex, on the southern flank of the Singhbhum Archaean nucleus in north-eastern India, exposes a series of Mesoarchaean igneous suites. These are (1) a gabbro–anorthosite unit, which is petrographically homogeneous, although mineral-chemistry data hint at a subtle eastward differentiation; (2) a peridotite unit (with three chromitite layers) together with (3) a pyroxenite unit which display cumulate textures, modal layering, and (for the peridotite unit) differentiation trends in both mineralogy and mineral chemistry; and (4) the Bangur gabbro (~3.1 Ga), which defines an oblong intrusion, crosscutting the older igneous suites in the southern part of the complex, with a curvilinear NW-trending apophysis, 2 km long and up to 40 m wide. Magmatic breccia comprising ultramafic and chromitite wall-rock clasts in a gabbro matrix is exposed at the contact of the main Bangur gabbro body and also forms the entire Bangur gabbro apophysis. Concentrations of platinum-group minerals (PGMs) are found where the breccia contains abundant chromitite clasts, and two types of platinum-group-element (PGE) mineralisation are recognised. Type 1 (Pt 1.1–14.2, Pd 0.1–2.1 ppm, with an average Pt/Pd=8–9) is a contact-type mineralisation which occurs in the breccia at the contact between the Bangur intrusion and its ultramafic host. The PGMs—Pt alloys (isoferroplatinum) and sulphides (braggite, malanite)—are enclosed by pyroxene and plagioclase, reflecting a magmatic origin. Significant wall-rock assimilation by the magma (giving rise to the Bangur gabbro) is indicated by changes in pyroxene composition and by the presence of relicts of chromite (from the host) now altered to secondary ferritchromite in the contact zone. Type 2 PGE mineralisation (Pt 0.3–1.6, Pd 1.8–6.0 ppm, with Pt/Pd~0.5–3.0) is restricted to the breccia apophysis of the Bangur gabbro where it occurs in the breccia matrix, associated with an intense hydrothermal alteration which does not exist in the contact zone. PGMs (PGE arsenides, tellurides, bismuthides and antimonides) and, where present, base-metal sulphides (BMSs) form intergrowths with hydrous silicates, reflecting a hydrothermal origin. Oxygen isotope geothermometry documents the main stages of hydrothermal alteration within a decreasing temperature range between 700–1,000 and 500–600 °C, and oxygen, hydrogen and sulphur isotopes show that the hydrothermal fluids were derived from the magma rather than an external source. Pervasive hydrothermal alteration in the breccia apophysis likely represents upward channelling of late-magmatic fluids along a narrow, near-vertical, subplanar conduit which led away from the main magma chamber. We suggest that Type 2 mineralisation was produced by late-magmatic hydrothermal remobilisation and reconcentration of Type 1 PGE mineralisation, and that the composition of the hydrothermal fluids controlled whether BMSs were enriched along with the PGMs.Editorial handling: P. Lightfoot  相似文献   

Mössbauer spectroscopic determination of Fe<Superscript>3+</Superscript>/Fe<Superscript>2+</Superscript> in synthetic basaltic glass: a test of empirical<Emphasis Type="Italic"> f</Emphasis>O<Subscript>2</Subscript> equations under superliquidus and subliquidus conditions     

Georg?M.?PartzschEmail author  Dominique?Lattard  Catherine?McCammon 《Contributions to Mineralogy and Petrology》2004,147(5):565-580

One of the most widely used methods to estimate magmatic oxygen fugacity involves the use of empirical equations relating fO₂ to the iron redox state in quenched silicate liquids; however none of the equations have been calibrated experimentally under subliquidus conditions at temperatures and oxygen fugacities that are relevant to natural magmas. To address this problem, we tested two empirical relationships [Eq. (1) in Kress and Carmichael 1991; Eq. (6) in Nikolaev et al. 1996] on synthetic glasses synthesized from a ferrobasaltic and a transitional alkali-basaltic composition at sub- to superliquidus temperatures (1,132–1,222°C) and controlled oxygen fugacities (FMQ=–2 to +1.4). Fe³⁺/Fe was determined using conventional and milliprobe Mössbauer spectroscopy, and verified using wet chemical analysis on selected samples. For the ferrobasaltic bulk composition SC1-P, both empirical models reproduce the Fe³⁺/Fe ratio of the quenched liquids generally within 0.03 for sub- as well as superliquidus temperatures, although agreement is worse at higher oxygen fugacities (FMQ>+1) at subliquidus temperatures. For the transitional alkali-basaltic composition 7159V-P, both models reproduce the Fe³⁺/Fe ratio of the quenched liquids generally within 0.04, although agreement is worse for both models at high oxygen fugacities (FMQ>+1). Such behaviour may be related to a change in melt structure, where a progressive change in Fe³⁺ coordination is inferred to occur as a function of Fe³⁺/Fe based on Mössbauer center shifts. Recasting the data in terms of oxygen fugacity shows that calculated oxygen fugacities deviate from those actually maintained during the equilibration of the sample material by generally no more than 0.5 log-bar unit, with maximum deviations that only rarely exceed one log-bar unit.Editorial responsibility: J. Hoefs  相似文献   

Subtidal variability of transverse flow off a cape     

Arnoldo?Valle–LevinsonEmail author  Mary Catherine?Brown 《Ocean Dynamics》2003,53(3):166-175

Time series of velocity profiles at two Chesapeake Bay entrance sites were used to characterize the subtidal variability of transverse flows off a cape. A shallow sampling site was located near Cape Henry over 6 m of water and separated from a deep site, 20 m deep, by a distance of 4 km. The velocity profiles showed that wind-induced subtidal variations in general masked curvature effects (centrifugal accelerations) that may produce secondary circulation associated with tidal flow around a cape. Such secondary circulation, consisting of flow away from the cape at surface and toward the cape at depth, was observed only during periods of weak winds. Most of the time, transverse flows were unidirectional throughout the water column and moved in opposite directions at the two sites examined. This caused convergence of transverse flow between the two sites under the influence of northerly winds and divergence of transverse flow with southwesterly winds. In addition to unidirectional and curvature-induced secondary flows, other modes of subtidal variability consisted of (1) two-layered responses with surface flow toward the cape, and (2) three-layered responses. These two- and three-layered structures were observed more frequently at the deep site, where greater stratification is expected, than at the shallow site.Responsible Editor: Iris Grabemann  相似文献   

Undressing the researcher: feminism, embodiment and sexuality at a queer bathhouse event   总被引：2，自引：0，他引：2  

Alison L Bain  Catherine J Nash 《Area》2006,38(1):99-106

In this paper we examine how the researcher's body can be used as a tool for data collection in the process of ethnographic fieldwork. We focus in particular on the tensions inherent in undertaking embodied ethnographic research in the sexualized setting of a queer women's bathhouse event in Toronto, Canada. Our discussion addresses three moments within the research process: preparing our bodies to attend the bathhouse; positioning our bodies within the spaces of the bathhouse; and interacting with our bodies during the event. Through this discussion we argue that the body of the researcher is a contested site of knowledge production.  相似文献   

Estimating rupture scenario likelihood based on dynamic rupture simulations: the example of the segmented Middle Durance fault, southeastern France   总被引：1，自引：0，他引：1  

Hideo Aochi  Marc Cushing  Oona Scotti  Catherine Berge-Thierry 《Geophysical Journal International》2006,165(2):436-446

The Middle Durance fault system, southeastern France, is a slow active fault that produced moderate-size historical seismic events and shows evidence of at least one   M _w ≳ 6.5  event in the last 29 000 yr. Based on dynamic rupture simulation, we propose earthquake scenarios that are constrained by knowledge of both the tectonic stress field and of the 3-D geometry of the Durance fault system. We simulate dynamic rupture interaction among several fault segmentations of different strikes, dips and rakes, using a 3-D boundary integral equation method. 50 combinations of reasonable stress field orientations, stress field amplitudes and hypocentre locations are tested. The probability of different rupture evolutions is then computed. Each segment ruptures mainly as a single event (44 per cent of the 50 simulations test in this paper). However, the probability that an event triggers simultaneously along three segments is high (26 per cent), leading to a potential rupture length of 45 km. Finally, 2 per cent of the simulations occur along four adjacent segments, producing the greatest total rupture length of 55 km. The simulation results show that the southernmost segment is most easily ruptured (40 per cent), because of its favourable orientation with respect to the tectonic stress and of its favourable location for interaction with the other segments. South-bound unilateral propagation is slightly preferable (41 per cent), compared to north-bound unilateral and bilateral propagation modes. Although, these rupture scenarios cannot be directly translated into probabilities of occurrence, they do provide a better insight as to which rupture scenarios are more likely, an important element to better estimate near-field strong ground motion and seismic hazard.  相似文献