Single Column Sequential Extraction of Ra,Nd, Th,Pa and U from a Natural Sample     

Catherine Jeandel  Celia Venchiarutti  Michael Bourquin  Catherine Pradoux  François Lacan  Pieter van Beek  Jean Riotte 《Geostandards and Geoanalytical Research》2011,35(4):449-459

A new procedure allowing the sequential extraction of Ra, Nd, Th, Pa and U from the same initial natural sample (sea or river waters, particles, sediments, rocks) is proposed. Extraction recoveries were better than 90%. Procedural blanks ranged from 80 pg (for Nd) to below 1 fg, the detection limit of the MC‐ICP‐MS used (for Pa); all were negligible compared with the amounts of elements currently determined. Based on classical anionic resins attached to a peristaltic pump allowing precise flow rate control, this procedure allowed a consequent reduction of the sample size, which improved the sampling resolution and reduced the sampling cost. It also ensured a better consistency of the samples for the five tracers.  相似文献   

Embryonic exposure to environmentally relevant concentrations of PCB126 affect prey capture ability of Fundulus heteroclitus larvae     

Couillard CM  Légaré B  Bernier A  Dionne Z 《Marine environmental research》2011,71(4):257-265

Early life stages from a marine fish species, Fundulus heteroclitus, were exposed to sublethal doses of 3,3',4,4',5 pentachlorobiphenyl (PCB126) to evaluate its effects on ecologically relevant responses: growth and behavior. A few hours after fertilisation, eggs were treated topically with PCB126 (2.5-50 pg egg?1). Four days post-hatching (dph), morphological changes (body length and malformations), spontaneous locomotor activity (active swimming speed, rate of travel, % inactivity), prey capture ability (Artemia franciscana nauplii) and whole body EROD activity were evaluated in larvae. Untreated larvae collected at 0.5, 1, 2, 3, 4 dph were also examined. PCB126 did not increase the mortality or malformation rates. Body length and spontaneous locomotor activity were altered only in larvae treated with the highest dose. Treatment with PCB126 caused a dose-responsive reduction in prey capture ability (rate of decline in the number of Artemia) and induction of EROD activity. The lowest observed effective dose for both of these responses was 5.0 pg PCB126 egg?1 or 5.0 TCDD-toxic equivalents pg g?1 egg, using a TCDD-toxic equivalent factor of 0.005 and an egg mass of 5 mg. Prey capture efficiency (number of Artemia captured per feeding strike) was reduced at ≥ 10.0 pg egg?1. In untreated developing larvae, prey capture ability and efficiency increased as post-hatching development progressed and EROD activity remained low. The pattern of behavioral responses observed in PCB126-exposed Fundulus larvae differed from that observed in less-developed larvae indicating that other mechanisms than retarded development were involved. Behavioral dysfunction was a more sensitive response to PCB126 than morphological alterations and it occurred at environmentally relevant concentrations.  相似文献   

LMDZ5B: the atmospheric component of the IPSL climate model with revisited parameterizations for clouds and convection     

Frédéric Hourdin  Jean-Yves Grandpeix  Catherine Rio  Sandrine Bony  Arnaud Jam  Frédérique Cheruy  Nicolas Rochetin  Laurent Fairhead  Abderrahmane Idelkadi  Ionela Musat  Jean-Louis Dufresne  Alain Lahellec  Marie-Pierre Lefebvre  Romain Roehrig 《Climate Dynamics》2013,40(9-10):2193-2222

Based on a decade of research on cloud processes, a new version of the LMDZ atmospheric general circulation model has been developed that corresponds to a complete recasting of the parameterization of turbulence, convection and clouds. This LMDZ5B version includes a mass-flux representation of the thermal plumes or rolls of the convective boundary layer, coupled to a bi-Gaussian statistical cloud scheme, as well as a parameterization of the cold pools generated below cumulonimbus by re-evaporation of convective precipitation. The triggering and closure of deep convection are now controlled by lifting processes in the sub-cloud layer. An available lifting energy and lifting power are provided both by the thermal plumes and by the spread of cold pools. The individual parameterizations were carefully validated against the results of explicit high resolution simulations. Here we present the work done to go from those new concepts and developments to a full 3D atmospheric model, used in particular for climate change projections with the IPSL-CM5B coupled model. Based on a series of sensitivity experiments, we document the differences with the previous LMDZ5A version distinguishing the role of parameterization changes from that of model tuning. Improvements found previously in single-column simulations of case studies are confirmed in the 3D model: (1) the convective boundary layer and cumulus clouds are better represented and (2) the diurnal cycle of convective rainfall over continents is delayed by several hours, solving a longstanding problem in climate modeling. The variability of tropical rainfall is also larger in LMDZ5B at intraseasonal time-scales. Significant biases of the LMDZ5A model however remain, or are even sometimes amplified. The paper emphasizes the importance of parameterization improvements and model tuning in the frame of climate change studies as well as the new paradigm that represents the improvement of 3D climate models under the control of single-column case studies simulations.  相似文献   

Control of deep convection by sub-cloud lifting processes: the ALP closure in the LMDZ5B general circulation model     

Catherine Rio  Jean-Yves Grandpeix  Frédéric Hourdin  Francoise Guichard  Fleur Couvreux  Jean-Philippe Lafore  Ann Fridlind  Agnieszka Mrowiec  Romain Roehrig  Nicolas Rochetin  Marie-Pierre Lefebvre  Abderrahmane Idelkadi 《Climate Dynamics》2013,40(9-10):2271-2292

Recently, a new conceptual framework for deep convection scheme triggering and closure has been developed and implemented in the LMDZ5B general circulation model, based on the idea that deep convection is controlled by sub-cloud lifting processes. Such processes include boundary-layer thermals and evaporatively-driven cold pools (wakes), which provide an available lifting energy that is compared to the convective inhibition to trigger deep convection, and an available lifting power (ALP) at cloud base, which is used to compute the convective mass flux assuming the updraft vertical velocity at the level of free convection. While the ALP closure was shown to delay the local hour of maximum precipitation over land in better agreement with observations, it results in an underestimation of the convection intensity over the tropical ocean both in the 1D and 3D configurations of the model. The specification of the updraft vertical velocity at the level of free convection appears to be a key aspect of the closure formulation, as it is weaker over tropical ocean than over land and weaker in moist mid-latitudes than semi-arid regions. We propose a formulation making this velocity increase with the level of free convection, so that the ALP closure is adapted to various environments. Cloud-resolving model simulations of observed oceanic and continental case studies are used to evaluate the representation of lifting processes and test the assumptions at the basis of the ALP closure formulation. Results favor closures based on the lifting power of sub-grid sub-cloud processes rather than those involving quasi-equilibrium with the large-scale environment. The new version of the model including boundary-layer thermals and cold pools coupled together with the deep convection scheme via the ALP closure significantly improves the representation of various observed case studies in 1D mode. It also substantially modifies precipitation patterns in the full 3D version of the model, including seasonal means, diurnal cycle and intraseasonal variability.  相似文献   

Investigating contemporary and historical sediment inputs to Slapton Higher Ley: an analysis of the robustness of source ascription methods when applied to lake sediment data     

N. Jenns  C. M. Heppell  T. P. Burt  J. Walden  I. D. L. Foster 《水文研究》2002,16(17):3467-3486

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Results from the Eso Large Program on Transneptunian Objects and Centaurs     

Boehnhardt  Hermann  Barucci  Antonella  Delsanti  Audrey  De Bergh  Catherine  Doressoundiram  Alain  Romon  Jennifer  Dotto  Elisabetta  Tozzi  Gianpaolo  Lazzarin  Monica  Fornasier  Sonia  Peixinho  Nuno  Hainaut  Olivier  Davies  John  Rousselot  Philippe  Barrera  Luis  Birkle  Kurt  Meech  Karen  Ortiz  JoseLuis  Sekiguchi  Tomohiko  Watanabe  Jun-ichi  Thomas  Nick  West  Richard 《Earth, Moon, and Planets》2003,92(1-4):145-156

BVRI photometry of 107 TNOs and Centaurs establishes the range of spectral gradients to be between –5 to 55%/100 nm (with one exception). A cluster of very red Cubewanos is firmly identified in orbits of low inclination and eccentricity beyond 40 AU from the Sun. Further correlations between surface colours and dynamical parameters (inclination and perihelion distance) are suggested for Cubewanos and scattered disk objects, but lack complete confidence for their reality. Plutinos and Centaurs do not show any clear correlation between surface colours and orbital parameters. We present in this paper 12 spectra obtained in the visible region and nine of them for which we obtained also near infrared spectra up to 2.4 microns. A few other objects have been observed, but the data are still under reduction and analysis. The principal reported results obtained are: (i) a wide range of visible slopes; (ii) evidence for surface variations on 2001 PT₁₃; and (iii) possible detection of few percent of water ice (1999 TC_36}, 2000 EB₁₇₃, 1999 DE₉, 2001 PT₁₃, 2000 QC₂₄₃, 1998 SG₃₅).  相似文献   

Wind signatures in the X-ray emission-line profiles of the late-O supergiant ζ Orionis     

David H. Cohen  Maurice A. Leutenegger  Kevin T. Grizzard  Catherine L. Reed  Roban H. Kramer  Stanley P. Owocki 《Monthly notices of the Royal Astronomical Society》2006,368(4):1905-1916

X-ray line-profile analysis has proved to be the most direct diagnostic of the kinematics and spatial distribution of the very hot plasma around O stars. The Doppler-broadened line profiles provide information about the velocity distribution of the hot plasma, while the wavelength-dependent attenuation across a line profile provides information about the absorption to the hot plasma, thus providing a strong constraint on its physical location. In this paper, we apply several analysis techniques to the emission lines in the Chandra High Energy Transmission Grating Spectrometer (HETGS) spectrum of the late-O supergiant ζ Ori (O9.7 Ib), including the fitting of a simple line-profile model. We show that there is distinct evidence for blueshifts and profile asymmetry, as well as broadening in the X-ray emission lines of ζ Ori. These are the observational hallmarks of a wind-shock X-ray source, and the results for ζ Ori are very similar to those for the earlier O star, ζ Pup, which we have previously shown to be well fit by the same wind-shock line-profile model. The more subtle effects on the line-profile morphologies in ζ Ori, as compared to ζ Pup, are consistent with the somewhat lower density wind in this later O supergiant. In both stars, the wind optical depths required to explain the mildly asymmetric X-ray line profiles imply reductions in the effective opacity of nearly an order of magnitude, which may be explained by some combination of mass-loss rate reduction and large-scale clumping, with its associated porosity-based effects on radiation transfer. In the context of the recent reanalysis of the helium-like line intensity ratios in both ζ Ori and ζ Pup, and also in light of recent work questioning the published mass-loss rates in OB stars, these new results indicate that the X-ray emission from ζ Ori can be understood within the framework of the standard wind-shock scenario for hot stars.  相似文献   

Potential sources of contamination to weak lensing measurements: constraints from N-body simulations     

Catherine Heymans  Martin White  Alan Heavens  Chris Vale  Ludovic Van Waerbeke 《Monthly notices of the Royal Astronomical Society》2006,371(2):750-760

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Manganese cycling in central Ontario forests: Response to soil acidification     

Shaun A. Watmough  M. Catherine Eimers  Peter J. Dillon 《Applied Geochemistry》2007

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North American Earth Science Megaproject Continuum, Part 3: New Canadian EON-ROSE Program     

Katherine Boggs  David Eaton  Thomas James  Roy Hyndman  Malaika Ulmi  Pascal Audet  Ed Johnston  Michael Sideris  Ron Clowes  Julie Elliott  Jeff Freymueller  Paul Kushner  Kristin Morell  Derek Schutt  Rick Aster  Frank Vernon  Michael Hedlin  Catherine de Groot-Hedlin  Eric Donovan  Roland Stull 《《地质学报》英文版》2018,92(Z1):12-13

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