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161.
The Fengjia barite–fluorite deposit in southeast Sichuan is a stratabound ore deposit which occurs mainly in Lower Ordovician carbonate rocks. Here we present results from fluid inclusion and oxygen and hydrogen isotope studies to determine the nature and origin of the hydrothermal fluids that generated the deposit. The temperature of the ore‐forming fluid shows a range of 86 to 302 °C. Our detailed microthermometric data show that the temperature during mineralization of the fluorite and barite in the early ore‐forming stage was higher than that during the formation of the calcite in the late ore‐forming stage. The salinity varied substantially from 0.18% to 21.19% NaCl eqv., whereas the density was around 1.00 g/cm3. The fluid composition was mainly H2O (>91.33%), followed by CO2, CH4 and traces of C2H6, CO, Ar, and H2S. The dominant cation was Na+ and the dominant anion Cl, followed by Ca2+, SO42‐, K+, and Mg2+, indicating a mid–low‐temperature, mid‐low‐salinity, low‐density NaCl–H2O system. Our results demonstrate that the temperature decreased during the ore‐forming process and the fluid system changed from a closed reducing environment to an open oxidizing environment. The hydrogen and oxygen isotope data demonstrate that the hydrothermal fluids in the study area had multiple sources, primarily formation water, as well as meteoric water and metamorphic water. Combined with the geological setting and mineralization features we infer that the stratabound barite–fluorite deposits originated from mid–low‐temperature hydrothermal fluids and formed vein filling in the fault zone.  相似文献   
162.
The double‐spike method with multi‐collector inductively coupled plasma‐mass spectrometry was used to measure the Mo mass fractions and isotopic compositions of a set of geological reference materials including the mineral molybdenite, seawater, coral, as well as igneous and sedimentary rocks. The long‐term reproducibility of the Mo isotopic measurements, based on two‐year analyses of NIST SRM 3134 reference solutions and seawater samples, was ≤ 0.07‰ (two standard deviations, 2s, n = 167) for δ98/95Mo. Accuracy was evaluated by analyses of Atlantic seawater, which yielded a mean δ98/95Mo of 2.03 ± 0.06‰ (2s, n = 30, relative to NIST SRM 3134 = 0‰) and mass fraction of 0.0104 ± 0.0006 μg g?1 (2s, n = 30), which is indistinguishable from seawater samples taken world‐wide and measured in other laboratories. The comprehensive data set presented in this study serves as a reference for quality assurance and interlaboratory comparison of high‐precision Mo mass fractions and isotopic compositions.  相似文献   
163.
Stress mobilisation and deformation of a slope are important for engineers to carry out reliable design of retaining systems. However, most case histories reported mainly on the response of pore water pressure (PWP), whereas knowledge about the stress deformation characteristics of slope is limited. In this study, a saprolitic soil slope was instrumented to monitor not only the responses of PWP but also horizontal stress and horizontal displacement. To assist in the interpretation of field data, a series of laboratory tests was conducted to characterise volume change behaviour of the soil taken from the site, under the effects of both net stress and suction. During a rainstorm event when positive PWP built up, a remarkably large displacement of 20 mm was recorded between 5.5- and 6-m depths, and the top 5 m of the slope exhibited translational downslope movement. This caused an increase in Bishop’s effective horizontal stress by 350 %, which reached a peak value close to 40 % of a Bishop’s effective passive stress. During the subsequent dry season when suction was recovered, an upslope rebound of 10 mm was recorded. Comparison of field and laboratory data reveals that the rebound was attributed to suction-induced soil shrinkage. This rebound led to a decrease in the Bishop’s effective horizontal stress previously built up during the storm event.  相似文献   
164.
Dolines are the most typical landform in karst landscapes. They play an important role in karst hydrogeology; they are effective sediment traps that provide information about past climates and karst evolution, and can also be indicators of tectonic activity. The morphometic analysis of those depressions can help in their study and interpretation. However, detailed identification and delineation of dolines becomes increasingly difficult when the study area is very large, of limited access or covered by vegetation. Here, we have used a method developed by the authors for automatic identification and delineation of karst depressions based on the use of a pit removal algorithm. Next a complete morphometric analysis of the karst depressions has been carried out. The main advantage of the methodology is that by delineating and identifying the depth of each doline from its rim, many morphometric statistics can be obtained, including the relation of doline depth and area with respect to altitude, the main doline orientations, doline density, the fractal dimension of doline area and frequency, and point field analysis, among others. The results are interpreted from a geomorphological point of view and the mapped dolines can be easily integrated into geomorphological mapping. A case study is presented from the large Sierra Gorda karst massif in southern Spain, where 3100 depressions have been identified. A strong structural control of doline shape and orientation is demonstrated; the main areas of doline density are highlighted and doline size is shown to follow a fractal law.  相似文献   
165.
166.
In this article, we document a detailed analytical characterisation of zircon M127, a homogeneous 12.7 carat gemstone from Ratnapura, Sri Lanka. Zircon M127 has TIMS‐determined mean U–Pb radiogenic isotopic ratios of 0.084743 ± 0.000027 for 206Pb/238U and 0.67676 ± 0.00023 for 207Pb/235U (weighted means, 2s uncertainties). Its 206Pb/238U age of 524.36 ± 0.16 Ma (95% confidence uncertainty) is concordant within the uncertainties of decay constants. The δ18O value (determined by laser fluorination) is 8.26 ± 0.06‰ VSMOW (2s), and the mean 176Hf/177Hf ratio (determined by solution ICP‐MS) is 0.282396 ± 0.000004 (2s). The SIMS‐determined δ7Li value is ?0.6 ± 0.9‰ (2s), with a mean mass fraction of 1.0 ± 0.1 μg g?1 Li (2s). Zircon M127 contains ~ 923 μg g?1 U. The moderate degree of radiation damage corresponds well with the time‐integrated self‐irradiation dose of 1.82 × 1018 alpha events per gram. This observation, and the (U–Th)/He age of 426 ± 7 Ma (2s), which is typical of unheated Sri Lankan zircon, enable us to exclude any thermal treatment. Zircon M127 is proposed as a reference material for the determination of zircon U–Pb ages by means of SIMS in combination with hafnium and stable isotope (oxygen and potentially also lithium) determination.  相似文献   
167.
168.
For decades, various well-known empirical correlations have been established and commonly used to estimate the undrained shear strength of normally consolidated clays in geotechnical practice. However, there are still many contradictory cases regarding the validity of these correlations, so their applicability and reliability are questionable. In this study, an extensive geotechnical database for normally consolidated clays has been compiled. Next, a Bayesian nonparametric method is exploited to identify the most critical soil index properties in inferring the undrained shear strength and a new predictive model is proposed. Finally, the performance of the proposed predictive model is assessed and compared with two well-known correlations using an independent testing database. It confirms that the proposed model not only possesses high predictability, but also provides superior performance over other existing empirical correlations.  相似文献   
169.
Some studies suggest that creep parameters should be determined using a greater quantity of creep test data to provide more reliable prediction regarding the deformation of soft soils. This study aims to investigate the effect of loading duration on model updating. One‐dimensional consolidation data of intact Vanttila clay under different loading durations collected from the literature is used for demonstration. The Bayesian probabilistic method is used to identify all unknown parameters based on the consolidation data during the entire consolidation process, and their uncertainty can be quantified through the obtained posterior probability density functions. Additionally, the optimal models are also determined from among 9 model candidates. The analyses indicate that the optimal models can describe the creep behavior of intact soft soils under different loading durations, and the adopted method can evaluate the effect of loading duration on uncertainty in the creep analysis. The uncertainty of a specific model and its model parameters decreases as more creep data are involved in the updating process, and the updated models that use more creep data can better capture the deformation behavior of an intact sample. The proposed method can provide quantified uncertainty in the process of model updating and assist engineers to decide whether the creep test data are sufficient for the creep analysis.  相似文献   
170.
The representation of place is a key theoretical advancement that geographic information science can offer to improve the understanding of environmental determinants of health, but developing robust computational representations of place requires a substantial departure from conventional notions of geographic representation in GIS. Unlike conventional GIS representations based on either objects or locations, we suggest that place representation should incorporate dynamic subjective, experiential, and relational aspects of place, as the influence of place on health behavior concerns not only the features that can be objectively observed at a particular location but also the environmental perceptions of the individual, as molded by biological, social, and experiential characteristics. In addition, assessments of environmental exposures on health outcomes should focus on individuals' time–activity patterns and microenvironment profiles, which form a potentially unique personalized exposure environment for each individual. Addressing these representational challenges via collaborative research has the potential to advance both geographic information science and health research.  相似文献   
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